排序方式: 共有31条查询结果,搜索用时 15 毫秒
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A simple approach to enhance the photocatalytic activity of red phosphorus(P) was developed.A mechanical ball milling method was applied to reduce the size of red P and to deposit graphene quantum dots onto red P. The product was characterized by scanning electron microscopy, transmission electron microscopy, contact angle measurements, zeta-potential measurements, X-ray diffraction and UV–vis absorption spectroscopy. The product exhibited high visible-light-driven photocatalytic performance in the photodegradation of rhodamine B. 相似文献
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李皓 《湖南环境生物职业技术学院学报》2006,12(4):408-411
在机械加工中采用近似法加工空间曲面,常常使加工过程变得简单可行,而且解决了部分机床力不能及的矛盾.在此介绍了在普通铣床上用椭圆曲线网络加工大半径浅圆弧的加工原理、加工方法及其误差分析. 相似文献
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Michele?ArestaEmail author Angela?Dibenedetto Carlo?Fragale Tiziano?Pastore 《Environmental Chemistry Letters》2004,2(1):1-4
Mechanical energy has been used so far for running chemical reactions and for preparing new materials in absence of solvents. Very recently, the technology has been applied to solve environmental problems. In this paper, we describe the application of high-energy milling (HEM) for the remediation of soils contaminated by chlorinated organic compounds such as polychlorobiphenyls (PCBs) and agrochemicals like atrazine. NaBH4 and LiAlH4 have been successfully used for the total dehydrohalogenation of both classes of compounds, leaving a residue lower than 2 ppmw of the starting compound in the treated soil. LiAlH4 was found to be more active than NaBH4. 相似文献
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以废弃液晶屏玻璃基板为原料,研究了球磨方式和球磨时间在球磨过程中对粉料粒径分布的影响。通过对废弃液晶屏玻璃基板的行星式球磨工艺的研究,探讨了球磨方式、球磨时间等因素对球磨效果的影响,以建立玻璃粉体细化的合理球磨方式和工艺参数。 相似文献
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The current homogeneous acid catalyst for biodiesel product however, would lead to formation of many undesirable by-products that make the post treatment of the biodiesel to be difficult and costly. Thus, sucrose-derived solid acid catalyst was developed in the present study which aims to improve the esterification process and reduce the generation of waste. The physicochemical properties of the synthesized catalysts were studied by various techniques such as, BET surface area, X-ray diffraction (XRD), temperature programmed desorption of NH3 (TPD-NH3), scanning electron microscopy (SEM). Response surface methodology (RSM) with central composite design (CCD) is used to determine the optimum parameters for the catalytic reaction. The experimental results showed that the catalyst exhibited good catalytic activity in the transesterification of PFAD, providing maximum biodiesel yield of 94% at optimum parameters. The better catalytic activity of the aforementioned catalyst in the biodiesel reaction could be attributed to the presence of optimal number of catalytically active acid site density on its surface. 相似文献
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Yao Xiao Honghong Lyu Chengliang Yang Beibei Zhao Lan Wang Jingchun Tang 《环境科学学报(英文版)》2021,33(5):93-107
In order to enhance the removal performance of graphitic carbon nitride (g-C3N4) on organic pollutant, a simultaneous process of adsorption and photocatalysis was achieved via the compounding of biochar and g-C3N4. In this study, g-C3N4 was obtained by a condensation reaction of melamine at 550°C. Then the g-C3N4/biochar composites were synthesized by ball milling biochar and g-C3N4 together, which was considered as a simple, economical, and green strategy. The characterization of resulting g-C3N4/biochar suggested that biochar and g-C3N4 achieved effective linkage. The adsorption and photocatalytic performance of the composites were evaluated with enrofloxacin (EFA) as a model pollutant. The result showed that all the g-C3N4/biochar composites displayed higher adsorption and photocatalytic performance to EFA than that of pure g-C3N4. The 50% g-C3N4/biochar performed best and removed 45.2% and 81.1% of EFA (10 mg/L) under darkness and light with a dosage of 1 mg/mL, while g-C3N4 were 19.0% and 27.3%, respectively. Besides, 50% g-C3N4/biochar showed the highest total organic carbon (TOC) removal efficiency (65.9%). Radical trapping experiments suggested that superoxide radical (?O2?) and hole (h+) were the main active species in the photocatalytic process. After 4 cycles, the composite still exhibited activity for catalytic removal of EFA. 相似文献
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研究了不同浓度下几种阴离子(NO3-、SO42-、H2PO4-、SiO32-)对球磨零价铁(BZVI)除砷规律的影响,探讨了上述阴离子对BZVI氧化As(Ⅲ)能力的影响,三价砷及五价砷的转化机制,及BZVI腐蚀产物.研究证实,不同浓度的NO3-和SO42-对砷去除效率影响不显著,但是随着H2PO4-和SiO32-浓度升高,溶液中As(V)分别由25.1%上升到83.6%和下降到3.8%;通过SEM和拉曼光谱分析发现,H2PO4-促进BZVI的腐蚀,导致As(Ⅲ)氧化能力增强;而铁表面形成二氧化硅聚合物或非晶固相则是SiO32-降低BZVI对砷氧化和吸附能力的主要机制. 相似文献
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欧版磨粉机在脱硫石灰石制粉中的应用 总被引:1,自引:0,他引:1
环保脱硫工艺中的脱硫剂大都为石灰石粉,石灰石粉的品质、细度及粒径分布是影响脱硫效果的关键性因素之一,而选择合适的石灰石粉制备的工艺和装备则对整个脱硫过程起着至关重要的作用;本文重点介绍了欧版磨粉机制备脱硫石灰石粉的技术特点及其在环保脱硫石灰石制粉中的应用。 相似文献