基于双指标多等级的土壤重金属生态风险评价

采用土壤中重金属的全量和有效态双重指标,建立基于多等级综合评估的土壤中重金属生态风险评价模型,将联合概率曲线法引入土壤评价模型,分析重金属暴露浓度与毒性数据的概率分布,考察重金属对土壤生物的毒害程度,从而确定土壤中重金属对于生态系统的风险。建立从简单到复杂的多等级综合评价方法,表征重金属的污染等级、浓度效应、多种重金属污染物的协同效应、不同重金属的毒性效应和土壤对不同重金属污染物的敏感性。选择典型地区采集有代表性的土壤样品,测定不同重金属的总量和有效态,验证评价模型的实用性和评价分级的合理性。旨在解决土壤重金属风险评价的方法学问题,为土壤环境质量管理提供支持。     

安全信息认知对心理安全感的作用机理研究

为揭示安全信息认知对员工心理安全感的影响，把握信息时代背景下心理安全感的研究趋势。基于安全信息认知的背景与特征，构建心理安全感的安全信息认知流程模型。通过描述安全信息对心理安全感的影响机理，从需要、动机、意识、期望剖析心理安全感的安全信息认知动力，归纳心理安全感的安全信息认知偏好，并从风险管控、安全氛围、安全管理落地、安全防护措施设计、员工安全生产积极性方面论述心理安全感在企业的应用对策。研究表明，员工安全信息认知对其心理安全感具有重要影响，是引起心理安全感波动的关键因素，也为心理安全感在企业的应用提供指导。     

基于BP神经网络的受限空间火灾联合探测方法

针对航空受限空间火灾探测高误报的问题，在现有技术成果基础上对多种火灾探测方式进行研讨，并提出1种基于BP神经网络技术的飞机机身内部受限空间火灾联合探测报警方法。该方法结合现有烟雾感应、气体传感器探测等常用火灾探测技术，以红外热成像探测为辅助手段，采用神经网络实现数据融合，对模拟实验舱火灾烟雾进行联合探测，在单一火灾探测方式基础上提高了探测准确率。     

化肥厂爆炸事故的不安全动作分析

为了分析化肥厂爆炸事故背后的不安全动作。本文选取了2009-2018年间国内外发生的52起典型化肥厂爆炸事故。从发生时间的角度分析事故特性,发现白昼期间的事故发生概率相对较高。同时文章分析了运输卸料、车间操作、特种作业和管理人员4种作业类型的不安全动作,从发生频率和风险等级两个方面评估了不安全动作的综合危险度。结果表明13项不安全动作的综合危险度较高,需要重点预控。     

联合执法机制在区域环境利益平衡中的应用

在追求环境效应与经济发展获得＂双赢＂的今天,跨行政区域联合执法已经成为平衡区域环境利益、妥善解决区域间环境纠纷,进而促进环境与经济协调发展的重要手段。本文提出了包括组建联合执法小组、主持联合执法会议、建立信息共享平台和实现联合监测的联合执法机制,并概括地阐述了确立长效性执法主体、先期处理制度、联合执法活动、活动监督、异议处理和惩罚制度的具体执行程序。试图利用联合执法的机制来解决区域间环境利益失衡的难题,以期为决策者提供相应的理论支持或政策参考。     

基于析因设计的多种重金属对发光菌联合毒性研究

文章采用析因设计的方法,研究沉积物水浸提液掺杂的多种重金属Cu、Cd、Zn、Pb和Ni对发光菌的联合毒性。通过对试验结果进行方差分析和多元线性回归,建立了重金属浓度和发光菌发光抑制率的关系模型:T=97.983Cu+41.111Cd-27.297Zn+129.869Pb+16.715Ni-5 803.639Cu*Cd+2 270.182Cd*Zn-6 411.870Cd*Pb-675.052Cd*Ni-3 108.544Pb*Ni+15 9552.434Cd*Pb*Ni+274 718.434Zn*Pb*Ni。模型分析结果表明:Zn对联合毒性产生负的影响,Cu、Cd、Pb、Ni对联合毒性具有正的贡献;Cd*Zn二元交互作用和Cd*Pb*Ni、Zn*Pb*Ni三元交互作用表现为协同作用,Cu*Cd、Cd*Pb、Cd*Ni、Pb*Ni二元交互作用表现为拮抗作用,而重金属四元和五元交互作用对联合毒性的贡献不显著。上述重金属联合毒性的作用可为沉积物中重金属复合污染控制提供参考。     

SnAgCu焊料中Sn元素在模拟土壤溶液中的浸出行为

研究了Sn-3.5Ag-0.75Cu无铅焊料及其与Cu基板的钎焊接头在模拟土壤的NaCl,NaCl-Na2SO4和NaCl-Na2SO4-Na2CO3溶液中Sn元素的浸出行为.结果表明:焊料在NaCl-Na2SO4-Na2CO3溶液中Sn的浸出相对严重;而接头在NaCl溶液中Sn的浸出量最多.在Sn浸出量多的焊料和接头表面形成厚而疏松的腐蚀产物,XRD分析表明其产物主要由SnO,SnO2和Sn4(OH)6Cl2组成.动电位极化测试分析表明接头中Cu基板与焊料合金之间的电偶腐蚀是焊料合金与接头在同种溶液中Sn元素浸出差异的主要原因.     

区域大气污染联防联控的理论与方法分析

区域性、复合型大气污染是中国目前以及今后一段时期内所面临的主要大气污染问题,但我国现行"属地"特征的环境管理制度无法满足区域性、复合型大气污染所需要的合作解决问题的要求,因此亟需建立区域大气污染联防联控机制。本文探讨了区域大气污染联防联控的理论基础,并着重讨论了我国实施区域联防联控的技术与方法,包括联防联控区域划分方法、区域大气环境问题控制技术、区域总量控制目标确定与分配方法及区域大气污染联防联控保障体系等。     

Bolted flange joints equipped with FBG sensors in industrial piping systems subjected to seismic loads

The vulnerability of major-hazard industrial plants to natural hazards has been recognized as an emergent issue whose importance is underlined by the Sendai Framework, established immediately after the Tohoku earthquake of 2011, in Japan. Hence, seismic risk analysis is of paramount importance as testified by the intense research activity that characterized the last years. In this respect, structural health monitoring can represent a valuable tool able to strongly help the decision-making phase. Along this main vein, optical fibers (OFs) represent a class of sensors able to both monitor critical conditions, as leakage of hazardous material, and activate safety barriers, if any. More precisely, optical fibers represent an economic solution, whose characteristics appear particularly suitable for dangerous environments like major-hazard plants. However, investigations relevant to their use for seismic monitoring of chemical/petrochemical plants are rather limited, especially when subject to strong dynamic excitations. As a result, this paper deals with the analysis of optical fiber Bragg gratings (FBGs) applied to bolted flange joints (BFJ) under cyclic loadings. More precisely, two experimental programs, i.e., a cyclic test on a single BFJ and a series of shaking table tests on BFJs of a multicomponent system, demonstrated the effectiveness of the proposed monitoring systems in detecting hazardous conditions and, thus, their potential use in conjunction with safety barriers.     

Ecotoxicological effects of polycyclic musks and cadmium on seed germination and seedling growth of wheat (Triticum aestivum)

Single and joint toxic e ects of polycyclic musks including 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[g]-2- benzopyran (HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronapthalene (AHTN) and cadmium (Cd) on seed germination and seedling growth of wheat (Triticum aestivum) were investigated. The results showed that the toxicity sequence of HHCB toxic to wheat seed germination and seedling growth was similar to that of AHTN, that is, germination rate > shoot elongation > root elongation, while the toxicity of Cd was in the sequence of root elongation > shoot elongation > germination rate, according to the LC50 and EC50 values. It is suggested that polycyclic musks and Cd had di erent toxicological mechanisms. Root and shoot elongation of wheat might be good bioindicators for the contamination of polycyclic musks and Cd in soil. The mixture of polycyclic musks and Cd had synergistic e ects on T. aestivum according to the equi-toxic mixture approach when root elongation was selected as the toxicological endpoint. Thus, the joint toxicity of HHCB and Cd was significantly higher than the single toxicity of HHCB or Cd, which was also confirmed by the EC50 mix value of the mixture (EC50 mix = 0.530 TUmix). The EC50 mix value of the mixture of AHTN and Cd was 0.614 TUmix, which indicated that the mixture toxicity was strengthened when AHTN coexisted with Cd.