全文获取类型
收费全文 | 298篇 |
免费 | 36篇 |
国内免费 | 73篇 |
专业分类
安全科学 | 67篇 |
废物处理 | 15篇 |
环保管理 | 37篇 |
综合类 | 167篇 |
基础理论 | 56篇 |
污染及防治 | 42篇 |
评价与监测 | 19篇 |
社会与环境 | 1篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 9篇 |
2020年 | 10篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 10篇 |
2016年 | 9篇 |
2015年 | 14篇 |
2014年 | 9篇 |
2013年 | 35篇 |
2012年 | 28篇 |
2011年 | 30篇 |
2010年 | 22篇 |
2009年 | 19篇 |
2008年 | 15篇 |
2007年 | 23篇 |
2006年 | 21篇 |
2005年 | 20篇 |
2004年 | 14篇 |
2003年 | 9篇 |
2002年 | 13篇 |
2001年 | 12篇 |
2000年 | 14篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有407条查询结果,搜索用时 31 毫秒
1.
Influences of working pressure on properties for TiO2 films deposited by DC
pulse magnetron sputtering 总被引:1,自引:1,他引:0
TiO2 films were deposited at room temperature by DC pulse magnetron sputtering system.The crystalline structures,morphological features and photocatalytic activity of TiO2 films were systematically investigated by X-ray diffraction (XRD),atomic force microscopy and ultraviolet spectrophotometer,respectively.The results indicated that the working pressure was the key deposition parameters influencing the TiO2 film phase composition at room temperature,which directly affected its photocatalytic activity.With increasing the working pressure,the target self-bias decreases monotonously.Therefore,low temperature TiO2 phase (anatase) could be deposited with high working pressure.The anatase TiO2 films deposited with 1.4 Pa working pressure displayed the highest photocatalytic activity by decomposition of Methyl Orange solution,which the degradation rate reached the maximum (35%) after irradiation by ultraviolet light for 1 h. 相似文献
2.
Pd-Ni/GC电极电化学还原水中三氯甲烷的研究 总被引:2,自引:0,他引:2
通过电沉积法在玻碳板(GC)电极上负载钯镍双金属,并利用正交实验对其进行循环伏安(CV)研究. CV结果表明,钯镍双金属比钯、镍单金属具有更大的氢吸附峰值,可以在- 500 mV(以Hg/Hg2SO4 为参比电极)左右获得- 24.83 mA的氢吸附峰.扫描电镜分析(SEM)表明,镍的加入改变了钯颗粒在GC表面的分布形态,钯镍双金属颗粒形貌明显不同于钯、镍单金属颗粒,钯镍双金属颗粒粒径介于钯、镍单金属颗粒粒径之间.实验考察了脱氯电流、脱氯时间对三氯甲烷去除率的影响.三氯甲烷的去除率随脱氯电流的增大而增大,随脱氯时间的延长而提高.在优化条件下制备的Pd-Ni/GC电极在0.5 mA、180 min的脱氯条件下对三氯甲烷的去除率为42.53%.可以推测,随着脱氯时间的继续延长,三氯甲烷去除率可得到进一步提高. 相似文献
3.
Benzoyl peroxide (BPO) is a typical organic peroxide widely used in food processing, particularly flour bleaching. Due to the unstable nature of the oxygen-oxygen bond in BPO, it readily reacts under even mid-low-temperature conditions. Lower concentrations of BPO are also potentially explosive, even when combined with acid or alkaline additives. Given the history of both potential and documented industrial accidents, this study investigates the thermal stability of various BPO concentrations when mixed with acid or alkaline solutions. In addition, differential and integral kinetic models were applied to verify that the apparent activation energy data from the differential scanning calorimetry experiments were valid. The results of autocatalysis reactions and nth-order reaction simulations presented characteristics consistent with the experimental findings. The findings in this paper can be used as a reference for BPO products that are mediated with either an acid or an alkaline solution during production, storage, transportation, or use. 相似文献
4.
随着印染工艺不断更新,大量化学分子结构复杂的化工染料应用到印染行业,使得常规的水处理工艺难以降解印染废水中的染料。本文以活性黑(RB5)染料为研究对象,采用液相高压放电产生强氧化性自由基来降解染料废水,考察反应时间、初始浓度和气体流量对RB5降解的影响,研究结果表明:在外部功率相同的情况下,浓度高染料其降解率相对较低;通入氧气量增加,产生的活性自由基和活性物质数量也增加,RB5的降解率也增大,但气流量不宜过大;高压放电产生的各种活性物质容易破坏染料发色基团的分子链,使其脱色。 相似文献
5.
《Journal of Manufacturing Processes》2014,16(4):551-562
Electromagnetic pulse metal processing techniques (EPMPT) such as welding, forming and cutting have proven to be an effective solution to specific manufacturing problems. A high pulse magnetic field coil is a critical part of these technologies and its design is a challenging task. This paper describes a Bitter coil design using a newly developed methodology for a simplified analytical calculation of the coil and complementary finite element models (FE) of different complexity. Based on the methodology a Belgian Welding Institute (BWI) Bitter coil has been designed and tested by means of short circuit experiments, impedance and B-field measurements. A good agreement between the calculated and the experimental design parameters was found. 相似文献
6.
目的为了确定外界电磁能量究竟如何进入到引信电路内部,针对无线电引信的电磁能量耦合路径进行系统研究。方法通过对多种引信进行不同形式的连续波、强电磁脉冲电磁辐照效应试验,对比引信天线、孔缝、弹体、电源模块等部位的能量耦合可能性。分析连续波、强电磁脉冲电磁环境对无线电引信作用的耦合规律。结果确定了电磁信号类型和引信接地结构是影响电磁能量耦合通道的关键因素,揭示了前门耦合是连续波电磁辐射环境的最主要方式。结论弹体或引信前端与电路共地的金属部件是强电磁脉冲辐射环境的主要能量路径,从而为无线电引信抗电磁性能加固的实施提供了有益参考。 相似文献
7.
通过循环伏安测试、交流阻抗测试、电吸附实验等方法研究了单组分和多组分溶液中不同离子在活性炭纤维电极表面的选择性电吸附性能。结果表明,电吸附选择性能与离子的水合半径、离子价态、离子浓度有关;增大初始浓度可以提高电吸附容量;并且,由于强烈的选择吸附作用,Ca2+离子可以吸附取代其它已经被吸附的离子。 相似文献
8.
Chokri Belai Moncef Khadraoui Salma Mseddi Monem Kallel Boubaker Elleuch Jean Francois Fauvarque 《环境科学学报(英文版)》2013,25(1):220-230
Problems related with industrials effluents can be divided in two parts: (1) their toxicity associated to their chemical content which should be removed before discharging the wastewater into the receptor media; (2) and the second part is linked to the difficulties of pollution characterisation and monitoring caused by the complexity of these matrixes. This investigation deals with these two aspects, an electrochemical treatment method of an olive mill wastewater (OMW) under platinized expanded titanium electrodes using a modified Grignard reactor for toxicity removal as well as the exploration of the use of some specific analytical tools to monitor effluent phenolic compounds elimination. The results showed that electrochemical oxidation is able to remove/mitigate the OMW pollution. Indeed, 87% of OMW color was removed and all aromatic compounds were disappeared from the solution by anodic oxidation. Moreover, 55% of the chemical oxygen demand (COD) and the total organic carbon (TOC) were reduced. On the other hand, UV- Visible spectrophotometry, Gaz chromatography/mass spectrometry, cyclic voltammetry and 13 C Nuclear Magnetic Resonance (NMR) showed that the used treatment seems efficaciously to eliminate phenolic compounds from OMW. It was concluded that electrochemical oxidation in a modified Grignard reactor is a promising process for the destruction of all phenolic compounds present in OMW. Among the monitoring analytical tools applied, cyclic voltammetry and 13 C NMR are among the techniques that are introduced for the first time to control the advancement of the OMW treatment and gave a close insight on polyphenols disappearance. 相似文献
9.
Dariusz Guziejewski Mariola Brycht Agnieszka Nosal-Wiercińska Sylwia Smarzewska Witold Ciesielski Sławomira Skrzypek 《Journal of environmental science and health. Part. B》2013,48(8):550-556
The electrochemical behavior of new generation fungicide acibenzolar-s-methyl (S-methyl 1,2,3-benzothiadiazole-7-carbothioate, ASM) on the hanging mercury drop electrode (HMDE) was investigated using square wave adsorptive stripping voltammetry. This method of determination is based on the irreversible reduction of ASM at the HMDE. The well-defined ASM peak was observed at ?0.4 V (vs. Ag/AgCl) in BR buffer at pH 2.2. The reduction peak current was proportional to concentration of ASM from 1.0 × 10?8 to 6.0 × 10?8 mol L?1 with detection and quantification limit 3.0 × 10?9 and 1.0 × 10?8 mol L?1, respectively. The applicability of the developed method for analysis of spiked samples of tap water, river water, and soil is illustrated. The effect of adsorption on the mercury electrode was studied in detail using the AC impedance method. Possible interferences with other common pesticides and heavy metal ions were examined. Clarification of the electrode mechanism was made using cyclic voltammetry (CV) technique. 相似文献
10.
在声发射技术的应用中,传感器的工作频率和灵敏度对AE检测的结果具有决定性的作用,传感器的校准是AE定量研究的基础,也是声发射检测技术研究中的重要课题。根据二级校准的相关要求设计了三个不同声源的实验:落球、断铅和压断毛细玻璃管法。通过重复性实验,测量了不同大小的钢球从不同高度下落;不同粗细、硬度以及不同长度的铅芯的断裂;不同粗细的毛细玻璃管被压断产生的脉冲声源,分别比较以上三个实验在不同状态条件下产生的脉冲声源信号,分析其实时特征和频谱特征(峰值,上升时间),通过计算确定其不确定度和稳定度,总结优化操作方法,同时分析了实验误差。在此基础上得出最适合做声发射传感器灵敏度校准的脉冲声源,为声发射传感器校准中的参考声源提供性能评判的依据。 相似文献