Ionic imbalance due to hydrogen carbonate from Asian dust

In an attempt to identify the ionic imbalance, hydrogen carbonate, HCO₃⁻ (bicarbonate), was determined together with the commonly determined nine major ions because the imbalance was frequently encountered in the chemical analysis of samples with high pHs. Titration method was applied for the determination of the samples with pH higher than 5.6. These samples amounted to 102 of the 1536 samples collected in Hokkaido, Northern Japan, from April 1998 to December 2002. Of the 102 samples, 74 (Group A) showed an acceptable ion balance without including HCO₃⁻. In the other 28 (Group B), however, inclusion of HCO₃⁻ successfully improved the ion balance. These results suggested that hydrogen carbonate was a potential candidate for explaining the imbalance. The hydrogen carbonate concentrations showed a strong correlation with the corresponding non-sea salt calcium (nss-Ca²⁺) concentrations, which implied that hydrogen carbonate was derived from calcium carbonate particles incorporated into falling raindrops or cloud droplets. For Group A, the relationship between hydrogen carbonate and the nss-calcium ion concentration was very similar to that for commonly suspended particles in Hokkaido. On the other hand, Group B exhibited a stronger but significantly different correlation. To the samples of Group B, a back-trajectory analysis was applied to demonstrate that the samples were associated with aerosol travelling from Northern China or Mongolia, which indicated that alkaline aerosol affected the chemistry. In consideration of these findings, the current standard of the ion balance should be critically reviewed for modification in regard to the contribution of hydrogen carbonate not only in source areas but also in receptor areas of alkaline aerosol.     

Effectiveness of resistivity monitoring for interpreting temporal changes in landfill properties

It is always possible for impermeable layers to exist in landfills. When they do, the properties of the solution at the exit of the leachate-collection system might not accurately reflect the overall properties of the landfill. This study examines whether resistivity monitoring is effective for determining the influence of impermeable layers on the leachate. The test cell used in this study was filled with waste made up mainly of incinerator ash and shredded incombustible material. Three lines of resistivity sensors were laid in the uppermost layer of the fill. A resistivity profile was recorded periodically from each of these lines. The water-table level and leachate properties were measured concurrently. Leachate conductivity was mainly controlled by concentrations of the main ions, and it correlated inversely to variations in resistivity. Temporal changes in the resistivity of the fills are an excellent means of assessing the leaching in fills. Monitoring the properties of leachate, combined with resistivity profiling, is extremely useful for interpreting the temporal changes of properties in landfills containing impermeable layers.     

Liquefaction process for a hydrothermally treated waste mixture containing plastics

Most landfilled plastic waste is a mixture or is in the form of composites with incombustible wastes such as glass, metals, and ceramics. After hydrothermal treatment, including a steam-explosion process, the separation of mixed waste (MW) into organic and inorganic substances becomes easy. However, the effect of hydrothermal pretreatment on the subsequent liquefaction of organic substances from MW is not obvious. In this study, the effects on the liquefaction of polystyrene and high-density polyethylene are discussed. Moreover, optimum conditions for the liquefaction of organic substances from hydrothermally treated MW are identified. By means of this hydrothermal pretreatment, including the steam-explosion process, polystyrene and high-density polyethylene can be significantly converted to oil by liquefaction at 300°–400°C. In comparison with liquefaction of hydrothermally pretreated mixed waste (HMW) at 300°–400°C with a batch type reactor, the yield of oil increases significantly on liquefaction using a semi-batch type reactor. It is considered that the radical chain and termination reactions among the radicals from HMW were inhibited in the semi-batch type reactor. On liquefaction of HMW in a semi-batch reactor, the conversion of HMW to oil was enhanced on increasing the liquefaction temperature to 350°C and the holding time to 60 min. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

Spatial distribution and loading amounts of particle sorbed and dissolved perfluorinated compounds in the basin of Tokyo Bay

In this study, we analyzed over 30 types of PFCs, including precursors in both the dissolved phase and particle solid phase, in 50 samples of river water collected from throughout the Tokyo Bay basin. PFCs were detected in suspended solids (SSs) at levels ranging from <0.003-4.4 ng L(-1) (0.11-2470 ng g(-1) dry weight). The concentrations of PFCs in the SS were one to two order(s) of magnitude lower than those of PFCs in the dissolved phase. Relatively high levels of PFCs (total of 35 PFCs) in SS were observed in urbanized areas. The concentration of PFCAs, including PFOA and PFNA, were significantly correlated with the geographic index as artificial area (R(2) of the linear regression curve in a double logarithmic plot: 0.09-0.55). Conversely, PFOS and FOSA were significantly correlated with the arterial traffic area (R(2) in a double logarithmic plot: 0.29-0.55). Those spatial trends were similar to the trends in dissolved PFCs. We estimated the loading amount of PFCs into Tokyo Bay from six main rivers and found that more than 90% of the total PFCs reached Tokyo Bay in the dissolved phase. However, 40.0-83.5% of the long chain PFCAs (C12-C15), were transported as particle sorbed PFCs. Rain runoff events might increase the loading amount of PFCs in SS. Overall, the results presented herein indicate that greater attention should be given to PFCs, especially for longer chain PFCs in SS in addition to dissolved PFCs.     

Initial design process of the sustainability science ontology for knowledge-sharing to support co-deliberation

Implementation of the sustainability science (SS) approach is often difficult because of poor communication between experts from different academic fields. We focused on ontology engineering as a method of knowledge structuring that supports the co-deliberation process. However, SS is too broad for a few experts to construct an ontology because SS targets and covers almost all existing research fields from the viewpoint of problem-solving. The N-iteration process is required for completing an SS ontology. In the present paper, we discuss the initial design process for constructing an ontology on SS from the aspect of a knowledge-sharing tool to support co-deliberation. First, we identified the SS ontology by referring to the existing literature. Second, we traced the structuring process of the SS ontology, which is independent of the existing research domain. Third, we compared the SS ontology with existing ontologies or concept structures on SS. Fourth, we assessed the SS ontology produced in the initial process in terms of relevance and coverage and addressed areas for improvement in order to facilitate co-deliberation among researchers from different domains. As a result of developing the SS ontology and applying it to the mapping tool that we developed based on the ontology, we found the following three points: the SS ontology enables us to define concepts relevant to SS without overlapping by distinguishing part-of and attribute-of relationships at the upper level of the ontology; the SS-based mapping tool successfully represents the potential countermeasures required by the targeted problem for all scientific fields except experimental engineering; however, the SS ontology requires further improvement in order to represent the conceptual linkage arising from compound and secondary problems and the fulfillment of classes at the lower hierarchy of Shortage problem, and requires slots for the entire hierarchy. In addition, based on the discussion of the areas for improvement, we found that missing slots and classes should be added in the process in which we use or improve tools corresponding to a variety of requirements for supporting co-deliberation. In this way, we are able to propose an incremental process for constructing the SS ontology from the aspect of a knowledge-sharing tool to support co-deliberation.     

Photodegradation of gaseous acetaldehyde and methylene blue in aqueous solution with titanium dioxide-loaded activated carbon fiber polymer materials and aquatic plant ecotoxicity tests

TiO₂-supported activated carbon felts (TiO₂–ACFTs) were prepared by dip coating of felts composed of activated carbon fibers (ACFs) with either polyester fibers (PS-A20) and/or a polyethylene pulp (PE-W15) in a TiO₂ aqueous suspension followed by calcination at 250 °C for 1 h. The as-prepared TiO₂–ACFTs with 29–35 wt.% TiO₂ were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and N₂ adsorption. The TiO₂–ACFT(PS-A20) samples with 0 and 29 wt.% TiO₂ were microporous with specific surface areas (S _BET) of 996 and 738 m²/g, respectively, whereas the TiO₂–ACFT(PE-W15) samples with 0 and 35 wt.% TiO₂ were mesoporous with S _BET of 826 and 586 m²/g, respectively. Adsorption and photocatalytic activity of the as-prepared samples were evaluated by measuring adsorption in the dark and photodegradation of gaseous acetaldehyde (AcH) and methylene blue (MB) in aqueous solution under UV light. The TiO₂ loading caused a considerable decrease in the S _BET and MB adsorption capacity along with an increase in MB photodegradation and AcH mineralization. Lemna minor was chosen as a representative aquatic plant for ecotoxicity tests measuring detoxification of water obtained from the MB photodegradation reaction with the TiO₂–ACFT samples under UV light.     

Validation studies of turbulence closure schemes for high resolutions in mesoscale meteorological models – A case of gas dispersion at the local scale

This work is a contribution to a large project, aimed at the development of an advanced environmental assessment modelling system to be used in Japan. The modelling system here considered consisted of the RAMS and HYPACT coupled models. The RAMS code was modified to properly simulate local scale phenomena using a fine mesh size of 250 m. In this direction, the main aim here was to investigate the effect of the choice of the turbulence closure scheme on the dispersion of pollutants. Our modified version of the RAMS/HYPACT model chain was validated using field experiments which were carried out by the Japan Atomic Energy Research Institute (JAERI) in the area of Mt. Tsukuba (Japan). The mean flow, turbulence and concentration fields obtained using two alternative turbulence closure schemes are compared. A discussion on the different performances of the turbulence closures is presented and the influence of the closure schemes over the plume dispersion is investigated.     

Bioaccumulation surveillance in Milford Haven Waterway

Biomonitoring of contaminants (metals, organotins, polyaromatic hydrocarbons (PAHs), PCBs) was undertaken in Milford Haven Waterway (MHW) and a reference site in the Tywi Estuary (St Ishmael/Ferryside) during 2007–2008. Bioindicator species encompassed various uptake routes—Fucus vesiculosus (dissolved contaminants); Littorina littorea (grazer); Mytilus edulis and Cerastoderma edule (suspension feeders); and Hediste (=Nereis) diversicolor (sediments). Differences in feeding and habitat preference have subtle implications for bioaccumulation trends though, with few exceptions, contaminant burdens in MHW were higher than the Tywi reference site, reflecting inputs. Elevated metal concentrations were observed at some MHW sites, whilst As and Se (molluscs and seaweed) were consistently at the higher end of the UK range. However, for most metals, distributions in MH biota were not exceptional. Several metal-species combinations indicated increases in bioavailability upstream, which may reflect the influence of geogenic/land-based sources—perhaps enhanced by lower salinity. TBT levels in MH mussels were below OSPAR toxicity thresholds and in the Tywi were close to zero. Phenyltins were not accumulated appreciably in M. edulis, whereas some H. diversicolor populations appear subjected to localized (historical) sources. PAHs in H. diversicolor were distributed evenly across most of MHW, although acenaphthene, fluoranthene, pyrene, benzo(a)anthracene and chrysene were highest at one site near the mouth; naphthalenes in H. diversicolor were enriched in the mid-upper Haven (a pattern seen in M. edulis for most PAHs). Whilst PAH (and PCB) concentrations in MH mussels were mostly above reference and OSPAR backgrounds, they are unlikely to exceed ecotoxicological thresholds. Bivalve Condition indices (CI) were highest at the Tywi reference site and at the seaward end of MH, decreasing upstream—giving rise to several significant (negative) relationships between CI and body burdens. Despite the possible influence of salinity gradient as a complicating factor, multivariate analysis indicated that a combination of contaminants could influence the pattern in condition (and the biomarkers metallothionein and TOSC). Integrating bioaccumulation data with biological and biochemical endpoints is seen as a useful way to discriminate environmental quality of moderately contaminated areas such as MHW and to prioritise cause and effect investigations.     

The effect of oxygen on chemical dechlorination of dieldrin using iron sulphides

The degradation of dieldrin by ferric sulphide (FeS₂) in aqueous solution was investigated when shielded against sunlight. An oxidative dechlorination process was observed under aerobic and anaerobic conditions; oxygen volume changed the degradation rate of dieldrin and the generation rate of reaction products. The dechlorination rate under microaerophilic conditions was fastest among the anaerobic to air oxygen concentrations. For this experiment, over 99% of the dieldrin was degraded, and 90% of the released chloride was detected after 30 d under 10 μmol oxygen. The major reaction products were different depending on the dose of oxygen. In the case of aerobic conditions, low molecular weight organic acids, such as formic acid, lactic acid, and oxalic acid, were generated as major reaction products. However, under anaerobic conditions, C₁₆H₂₂O₄ (dibutyl phthalate) and C₆H₁₃ClO (3-chloro-4-methyl-2-pentanol) were detected as reaction intermediates, and small amounts of succinic acid, malonic acid, and formic acid were also generated. These reactions proceed by FeS₂ interface reactions with H₂O under anaerobic condition, or O₂ under aerobic condition.