A Satisficing Framework for Environmental Policy Under Model Uncertainty

We propose a novel framework for the economic assessment of environmental policy. Our main point of departure from existing work is the adoption of a satisficing, as opposed to optimizing, modeling approach. Along these lines, we place primary emphasis on the extent to which different policies meet a set of goals at a specific future date instead of their performance vis-a-vis some intertemporal objective function. Consistent to the nature of environmental policymaking, our model takes explicit account of model uncertainty. To this end, the decision criterion we propose is an analog of the well-known success-probability criterion adapted to settings characterized by model uncertainty. We apply our criterion to the climate-change context and the probability distributions constructed by Drouet et al. (2015) linking carbon budgets to future consumption. Insights from computational geometry facilitate computations considerably and allow for the efficient application of the model in high-dimensional settings.

     

BMP tests of source selected OFMSW to evaluate anaerobic codigestion with sewage sludge

The aim of this study is to characterize different types of source selected organic fraction of municipal solid waste (SS-OFMSW) in order to optimize the upgrade of a sewage sludge anaerobic digestion unit by codigestion. Various SS-OFMSW samples were collected from canteens, supermarkets, restaurants, households, fruit–vegetable markets and bakery shops. The substrates characterization was carried out getting traditional chemical–physical parameters, performing elemental analysis and measuring fundamental anaerobic digestion macromolecular compounds such as carbohydrates, proteins, lipids and volatile fatty acids. Biochemical methane potential (BMP) tests were conducted at mesophilic temperature both on single substrates and in codigestion regime with different substrates mixing ratios. The maximum methane yield was observed for restaurant (675 NmlCH₄/gVS) and canteens organic wastes (571 and 645 NmlCH₄/gVS). The best codigestion BMP test has highlighted an increase of 47% in methane production respect sewage sludge digestion.     

Electroassisted methods for waste destruction: silver(II) and peroxydisulfate reagents in the electrochemically mediated oxidation of polyaromatic sulfonates

The electrochemical oxidation is a promising process for organic pollutants which are recalcitrant to biological degradation. The anodic oxidation of 1,5-naphthalenedisulfonic acid, hereafter NDS, was evaluated at a Pt anode using in situ generated Ag(II) cation or peroxydisulfate [S2O(8)(2-)] anion as mediators. Kinetics of the direct chemical oxidation of NDS in the presence of Na2S2O8, and the identification of some oxidation intermediates are also reported. An analysis of the results shows that Ag(II) is characterized by a high-reaction rates, while [S2O(8)(2-)] performs the oxidation of NDS in a complete way.     

Water monitoring and treatment for drinking purposes in 2004 tsunami affected area—Ban Nam Khem, Phang Nga, Thailand

University of Brescia and Mahidol University of Bangkok developed a project in Phang Nga province (Thailand), the most damaged by 2004 tsunami. In particular, the study, performed between April and May 2006, dealt with the surface and ground water monitoring in Ban Nam Khem village and the experimental evaluation of possible drinking treatment alternatives. The monitoring highlighted that saline content in the tsunami affected area is decreasing but still very high (conductivity presented values up to 2,600 and 6,230 microS/cm in ground and surface water, respectively); hence, advanced and complicated processes such as reverse osmosis should be adopted to treat such water for drinking purposes. Waiting for ground water salinity to assume acceptable values, activities for the reduction of its organic and microbiological contamination will be started. However, it has to be underlined that the diffusion of drinking water to a greater part of population can be obtained only through the realization of new centralised treatment plants and the improvement of existing ones (serving at the moment about 20% of inhabitants).     

Concentration of trace metals in sediments and soils from protected lands in south Florida: background levels and risk evaluation

A comprehensive environmental evaluation was completed on 20 metals: two reference metals (Fe, Al) and several minor trace metals (As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn) for surface soils and sediments collected from 50 sites in Everglades National Park (ENP), the coastal fringes of Biscayne National Park (BNP), and Big Cypress National Preserve. Samples were prepared by acid digestion (EPA3050) and analyzed by ICP/MS detection (EPA6020). Although no widespread contamination was detected across the two parks and one preserve, there were some specific areas where metal concentrations exceeded Florida’s ecological thresholds, suggesting that some metals were of concern. A screening-level evaluation based on a proposed effect index grouped trace metals by their potential for causing negligible, possible, and probable effects on the biota. For example, Cu in BNP and Cr and Pb in ENP were considered of concern because their adverse effect likelihood to biota was assessed as probable; consequently, these trace metals were selected for further risk characterization. Also, stations were ranked based on a proposed overall contamination index that showed that: site BB10 in BNP and sites E3 and E5 in ENP had the highest scores. The first site was located in a marina in BNP, and the other two sites were along the eastern boundary of ENP adjacent to current or former agricultural lands. An assessment tool for south Florida protected lands was developed for evaluating impacts from on-going Everglades restoration projects and to assist State and Federal agencies with resource management. The tool consists of enrichment plots and statistically derived background concentrations based on soil/sediment data collected from the two national parks and one preserve. Finally, an equally accurate but much simplified approach is offered for developing enrichment plots for other environmental settings.     

Validation of a Lagrangian dispersion model implementing different kernel methods for density reconstruction

In this paper the inert version of a Lagrangian particle model named photochemical Lagrangian particle model (PLPM) is described and validated. PLPM implements four density reconstruction algorithms based on the kernel density estimator. All these methods are fully grid-free but they differ each other in considering local or global features of the particles distribution, in treating the Cartesian directions separately or together and in being based on receptors or particles positions in space. Each kernel has been shown to have both advantages and disadvantages, but the overall good performances of the model when compared with the well known Copenhagen and Kincaid data sets are very encouraging in view of its extension to fully chemically active simulations, currently under development.     

Sorption and desorption behavior of chloroanilines and chlorophenols on montmorillonite and kaolinite

The bioavailability of pollutants, pesticides and/or their degradation products in soil depends on the strength of their sorption by the different soil components, particularly by the clay minerals. This study reports the sorption-desorption behavior of the environmentally hazardous industrial pollutants and certain pesticides degradation products, 3-chloroaniline, 3,4-dichloroaniline, 2,4,6-trichloroaniline, 4-chlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol on the reference clays kaolinite KGa-1 and Na-montmorillonite SWy-l. In batch studies, 2.0 g of clay were equilibrated with 100.0 mL solutions of each chemical at concentrations ranging from 10.0 to 200.0 mg/L. The uptake of the compounds was deduced from the results of HPLC-UV-Vis analysis. The lipophilic species were best retained by both clay materials. The most lipophilic chemical used in the study, 2,4,6-trichloroaniline, was also the most strongly retained, with sorption of up to 8 mg/g. In desorption experiments, which also relied on HPLC-UV-Vis technique, 2,4,6-trichloroaniline was the least desorbed from montmorillonite. However, on kaolinite all of the compounds under study were irreversibly retained. The experimental data have been modelled according to the Langmuir and Freundlich isotherms. A hypothesis is proposed concerning the sorption mechanism and potential applications of the findings in remediation strategies have been suggested.     

Foliar response of an Ailanthus altissima clone in two sites with different levels of ozone-pollution

Potted plants of Ailanthus altissima, produced by root suckers coming from a single symptomatic mother tree, were placed in two sites in the vicinity of Florence (central Italy), with different levels of ozone pollution. These plants were kept in well watered conditions during the period May-September 1999. In the high pollution site (Settignano-SET) the level of ozone exposure (AOT40) reached at the end of the season a value of 31 ppm h, whereas in the "low pollution" site (Cascine-CAS) the exposure to ozone was 11 ppm h. A. altissima showed foliar symptoms in early July at SET and in the second half of July at CAS when exposure values reached 5 ppm h at both sites. However, at the end of August the conditions of the plantlets were rather similar in both sites. Microscopic and ultrastructural analysis were performed at the first onset of symptoms at SET (the CAS leaflets were asymptomatic). Observing the upper leaf surface where the brown stipples were visible, it was found that the cells of the palisade mesophyll displayed loss of chlorophyll and the organelles in the cytoplasm were damaged. Swelling of thylacoids was observed in the CAS leaflets, thus indicating the possible onset of a pre-visual damage. The injured cells were separated from the healthy ones by a layer of callose. We conclude that the sensitivity to ozone of A. altissima leaves is related to its leaf structure, with low leaf density and large intercellular spaces. Cell walls, as well as acting as mechanical barriers against the spread of ozone within the cell, also provide important detoxifying processes.