全文获取类型
收费全文 | 4009篇 |
免费 | 217篇 |
国内免费 | 1468篇 |
专业分类
安全科学 | 333篇 |
废物处理 | 209篇 |
环保管理 | 316篇 |
综合类 | 2466篇 |
基础理论 | 633篇 |
污染及防治 | 1191篇 |
评价与监测 | 190篇 |
社会与环境 | 182篇 |
灾害及防治 | 174篇 |
出版年
2024年 | 10篇 |
2023年 | 63篇 |
2022年 | 200篇 |
2021年 | 178篇 |
2020年 | 148篇 |
2019年 | 133篇 |
2018年 | 151篇 |
2017年 | 195篇 |
2016年 | 189篇 |
2015年 | 213篇 |
2014年 | 325篇 |
2013年 | 385篇 |
2012年 | 328篇 |
2011年 | 340篇 |
2010年 | 303篇 |
2009年 | 264篇 |
2008年 | 268篇 |
2007年 | 270篇 |
2006年 | 232篇 |
2005年 | 175篇 |
2004年 | 116篇 |
2003年 | 153篇 |
2002年 | 119篇 |
2001年 | 108篇 |
2000年 | 105篇 |
1999年 | 108篇 |
1998年 | 82篇 |
1997年 | 94篇 |
1996年 | 102篇 |
1995年 | 82篇 |
1994年 | 63篇 |
1993年 | 55篇 |
1992年 | 51篇 |
1991年 | 18篇 |
1990年 | 23篇 |
1989年 | 14篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有5694条查询结果,搜索用时 15 毫秒
1.
选取衡阳市区和衡山背景站臭氧自动监测数据,分析两地的臭氧污染特征。对空气质量的优良率情况、臭氧作为首要污染物的变化情况、臭氧浓度的日变化特征、典型时段的浓度变化特征、臭氧浓度的月际变化特征和臭氧与PM_(2.5)的关联情况等进行了分析。结果表明,多云及阴雨天气时,衡阳市区的臭氧浓度日变化幅度大于衡山背景站。夏季,衡阳市区和衡山背景站的臭氧浓度的日变化特征规律差异较大,臭氧浓度分布比较分散,前者为典型的单峰形,后者则波动平缓。冬季,日变化幅度不大,但衡阳市区的臭氧浓度明显低于衡山背景站。衡山背景站和衡阳市区的臭氧基本同步变化,但日均值高于衡阳市区。 相似文献
2.
Zhu Rong Wang Shixin Srinivasakannan C. Li Shiwei Yin Shaohua Zhang Libo Jiang Xiaobin Zhou Guoli Zhang Ning 《Environmental Chemistry Letters》2023,21(3):1611-1626
Environmental Chemistry Letters - The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet... 相似文献
3.
Huang Ying Jiang Qiongji Yu Xubiao Gan Huihui Zhu Xia Fan Siyi Su Yan Xu Zhirui He Cunrui 《Environmental science and pollution research international》2021,28(37):51251-51264
Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under... 相似文献
4.
Li Haoxin Huang Yuyan Yang Xiaojie Jiang Zhengwu Yang Zhenghong 《Journal of Material Cycles and Waste Management》2018,20(3):1701-1709
Journal of Material Cycles and Waste Management - This work aims to develop another approach to the management of magnesium slag (MS) via the production of Portland cement clinker. Thus, 0, 10, 20,... 相似文献
5.
Comparison of different sequential extraction procedures for mercury fractionation in polluted soils
Dong Haochen Feng Liu Qin Yu Luo Muxinjian 《Environmental science and pollution research international》2019,26(10):9955-9965
Environmental Science and Pollution Research - Three sequential extraction procedures (SEPs), modified Tessier, modified BCR, and CIEMAT, were compared for mercury fractionation in polluted soils.... 相似文献
6.
Yiming Chang Liangang Mao Lan Zhang Yanning Zhang Hongyun Jiang 《Environmental science and pollution research international》2020,27(10):10286-10295
Compound pollution refers to two or more kinds of pollutants with different properties, a pollutant from different sources, or the simultaneous existence of two or more different types of pollutants in the same environment. In this study, we aimed to investigate the individual and combined toxicity of the insecticide imidacloprid (IMI), the herbicide acetochlor (ACT), and the fungicide tebuconazole (TBZ) to zebrafish. The acute toxicity test results showed that the 96-h LC50 values of IMI, ACT, and TBZ were 276.84 (259.62–294.35) mg active ingredient (a.i.) L−1, 1.52 (1.34–1.74) mg a.i. L−1, and 8.16 (7.7–8.6) mg a.i. L−1, respectively. The combinations of IMI, ACT, and TBZ with toxicity ratios of 1:2:2, 1:4:4, 2:4:1, and 4:1:4 displayed synergistic toxic effects on zebrafish, while the toxicity ratios of 1:1:1, 1:1:2, 2:1:2, 2:2:1, and 4:2:1 of IMI, ACT, and TBZ, respectively, exhibited antagonistic toxic effects on zebrafish. The following experiments were performed with a toxicity ratio of 1:4:4 (IMI:ACT:TBZ). The activities of four enzyme biomarkers related to oxidative stress in the liver, catalase (CAT), superoxide dismutase (SOD), glutathione S-transferase (GST), and malondialdehyde (MDA) content were evaluated in each exposure group on days 7, 14, 21, and 28. Compared with those of the control group, the activities of CAT, SOD, and GST and the MDA content were significantly altered at different time points in the individual and combined exposure groups. Additionally, the activities of CAT, SOD, and GST and the MDA content were significantly altered in the combined group compared with those of the individual group after 14 days or 21 days of exposure. Therefore, it was confirmed that combined toxicity studies are indispensable in risk assessment. 相似文献
7.
Guochen Zhang Xin Zhao Danni Yang Xia Jiang Wenju Jiang 《Journal of the Air & Waste Management Association (1995)》2018,68(9):958-968
In this study, MnO2 and pyrolusite were used as the catalysts to prepare modified activated carbon, that is, AC-Mn and AC-P, respectively, from coals by blending method and steam activation. The Brunauer–Emmett–Teller (BET) results indicated that the AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The relative contents of basic functional groups (i.e., C = O, π-π*) on AC-P were slightly lower than those on AC-Mn, while both contained the same main metal species, namely, MnO. The desulfurization results showed that with 3 wt% of blending ratio, AC-Mn3 and AC-P3 had higher sulfur capacities at 220 and 205 mg/g, respectively, which were much higher than for the blank one (149.6 mg/g). Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn, which might be attributed to the existence of other metals in pyrolusite. After the desulfurization process, MnO were gradually transferred into MnSO4, and the relative contents of basic functional groups decreased evidently for both AC-Mn3 and AC-P3. The results demonstrated that pyrolusite could be one good alternative to MnO2 to prepare modified activated carbon for desulfurization.
Implications: MnO2 and pyrolusite were used as the additives to prepare modified activated carbon from coals by a blending method and by steam activation, that is, AC-Mn and AC-P, respectively. The AC-P had higher surface areas and micropore volumes than the AC-Mn with the same blending ratio. The AC-Mn and AC-P had higher sulfur capacities than a blank one. Moreover, the AC-P had relatively higher sulfur capacity than the AC-Mn with the same contents of Mn. The results demonstrated that pyrolusite could be one good alternative to MnO2 to prepare modified activated carbon for desulfurizatio. 相似文献
8.
This study investigated the levels, sources and ecological risks of 16 polycyclic aromatic hydrocarbons (PAHs) in two sediment cores that were collected along the Huaxi Reservoir. The spatial distributions and residue levels of the 16 priority PAHs in the sediments from the Huaxi Reservoir were analyzed for their potential ecological risk, source apportionment and contribution to the total PAH residue. The concentration level of the total PAHs (TPAHs) was in the range 1805 ng·g?1 to 20023 ng·g?1 based on dry weight, and the content of PAHs in the Huaxi Reservoir exhibited a gradual upward trend. The PAH congener ratios fluoranthene/(fluoranthene + pyrene) and indeno[1, 2, 3-cd]pyrene/(indeno[1, 2, 3-cd]pyrene + benzo[g, h, i]perylene) were used to identify the source. The main source of the low molecular weight PAHs was wood and coal combustion, whereas the high molecular weight PAHs were primarily from petroleum combustion sources. The results of an ecological risk assessment demonstrated that ACE poses a potential ecological risk, while FLU, NAP, ANT, BaP, DBA, PHEN and PYR can have serious ecological risks. 相似文献
9.
Luo Xiaofang Dessie Wubliker Wang Meifeng Duns Gregory J. Rong Nianhang Feng Luya Zeng Jianqing Qin Zuodong Tan Yimin 《Journal of Material Cycles and Waste Management》2021,23(2):548-556
Journal of Material Cycles and Waste Management - The traditional Chinese medicinal plant Magnolia officinalis has a wide range of applications; including more than 200 kinds of patented Chinese... 相似文献
10.
计算机模拟研究UO2+2在人体细胞液的形态分布 总被引:1,自引:0,他引:1
建立了由多种金属离子和小分子配体组成的多相细胞液热力学平衡模型.模拟研究了UO2 2在组织液和细胞液的形态分布及CO2-3、氨三乙酸(NTA)和乙二胺四乙酸(EDTA)浓度对细胞液中UO2 2形态分布的影响.在组织液中,正常生理pH下,当各形态UO2 2总摩尔浓度 [U]= 1.0×10-6 mol/L 或[U]=1.0×10-3 mol/L时,UO2 2均主要以[UO2(CO3)3]4-和[UO2(CO3)2]2-形态存在.在细胞液中,当[U]=1.0×10-6 mol/L时,UO2 2主要以[UO2(CO3)3]4-和[UO2(CO3)2]2-存在;当[U]=1.0×10-3 mol/L,pH为6.0~6.8时,细胞液中存在大量的固相(UO2)3(PO4)2·4H2O,当pH为6.8~7.4时,UO2 2主要以[UO2(CO3)3]4-、[UO2(CO3)2]2-和[(UO2)2CO3(OH)3]-存在.细胞液中(UO2)3(PO4)2·4H2O含量随[U]升高而增加.通过调节细胞液pH和增加细胞液CO2-3浓度均能降低其固相UO2 2配合物含量.在细胞液中增加NTA会增加(UO2)3(PO4)2·4H2O含量,当添加EDTA时会显著降低(UO2)3(PO4)2·4H2O含量. 相似文献