Impact of overland traffic on heavy metal levels in highway dust and soils of Istanbul, Turkey

The purpose of this study was to investigate the impact of overland traffic on the spatial distribution of heavy metals in urban soils (Istanbul, Turkey). Road dust, surface, and subsurface soil samples were collected from a total of 41 locations along highways with dense traffic and secondary roads with lower traffic and analyzed for lead (Pb), zinc (Zn), and copper (Cu) concentrations. Statistical evaluation of the heavy metal concentrations observed along highways and along the secondary roads showed that the data were bimodally distributed. The maximum observed Pb, Zn, and Cu concentrations were 1,573, 522 and 136 mg/kg, respectively, in surface soils along highways and 99.3, 156, and 38.1 mg/kg along secondary roads. Correlation analysis of the metal concentrations in road dust, surface and 20-cm depth soils suggests the presence of a common pollution source. However, metal concentrations in the deeper soils were substantially lower than those observed at the surface, indicating low mobility of heavy metals, especially for Pb and Zn. A modified kriging approach that honors the bimodality of the data was used to estimate the spatial distribution of the surface concentrations of metals, and to identify hotspots. Results indicate that despite the presence of some industrial zones within the study area, traffic is the main heavy metal pollution source.     

Current and Future Strategies for Water and Wastewater Management of Istanbul City

Istanbul has experienced rapid increases in population to more than 12 million people, which has created infrastructure problems of water supply and wastewater treatment and disposal. In this article, the achievements and approaches of the Istanbul Water and Sewerage Administration (ISKI) to solve the water shortage problem and to improve services are summarized. Istanbul had a very severe water shortage problem in 1994 because of ignorance of the implementation of the needed projects. After reviewing the reasons and causes of the problem, new priority criteria adopted after 1994 are given. Following the implementation of the projects determined according to the aforementioned criteria, water supplied has exceeded the water demand. The added capacity is equal to one to three times of the capacity built up to 1994 for water treatment, service reservoirs, pumping stations, transmission lines, and the water distribution network; water quality has been improved the meet local and international potable water standards. Unaccounted for water has been reduced from 60% to 27%. The percentage of treated wastewater has been increased from 10% to 90% in 8 years, resulting in drastic improvements and rehabilitation of the Golden Horn and coastal water quality. Through improved customer services, complaints were reduced from 33% in 1994 to 0.3%. Some of the main criteria and the approaches behind this success are summarized. Published online     

The modeling and analysis of transesterification reaction conditions in the selection of optimal biodiesel yield and viscosity

Among alternative fuels, biodiesel has been emphasized as a substantial candidate for diesel engines because of many advantages. However, the main shortcomings preventing more widespread use of biodiesel are high production cost and viscosity. In order to simultaneously overcome both of these shortcomings, the reaction conditions for the transesterification of waste cooking oil (WCO) were optimized using Taguchi and the full factorial design approaches. The analyses of signal to noise ratio and variance were also performed to identify the dominance of reaction conditions on viscosity and biodiesel yield. As a result, the optimal reaction conditions giving the lowest kinematic viscosity (3.991 cSt) and the highest biodiesel yield (98.19%) were determined to be as follows: sodium methoxide amount of 1.00 wt%, reaction time of 60 min, reaction temperature of 55 °C, and methanol to oil molar ratio of 6:1. The catalyst amount and methanol to oil molar ratio were found to be the most significant conditions influencing on the viscosity (10.36% and 78.87% contributions) and the yield (58.48% and 20.17% contributions), respectively. Finally, all physicochemical properties of final waste cooking oil biodiesel (WCOB) produced under optimal reaction conditions were found to meet the EN 14214.     

Lung bioaccessibility of contaminants in particulate matter of geological origin

Human exposure to particulate matter (PM) has been associated with adverse health effects. While inhalation exposure to airborne PM is a prominent research subject, exposure to PM of geological origin (i.e., generated from soil/soil-like material) has received less attention. This review discusses the contaminants in PM of geological origin and their relevance for human exposure and then evaluates lung bioaccessibility assessment methods and their use. PM of geological origin can contain toxic elements as well as organic contaminants. Observed/predicted PM lung clearance times are long, which may lead to prolonged contact with lung environment. Thus, certain exposure scenarios warrant the use of in vitro bioaccessibility testing to predict lung bioavailability. Limited research is available on lung bioaccessibility test development and test application to PM of geological origin. For in vitro tests, test parameter variation between different studies and concerns about physiological relevance indicate a crucial need for test method standardization and comparison with relevant animal data. Research is recommended on (1) developing robust in vitro lung bioaccessibility methods, (2) assessing bioaccessibility of various contaminants (especially polycyclic aromatic hydrocarbons (PAHs)) in PM of diverse origin (surface soils, mine tailings, etc.), and (3) risk characterization to determine relative importance of exposure to PM of geological origin.     

Interrelationships among foreign direct investments,renewable energy,and CO2 emissions for different European country groups: a panel ARDL approach

Environmental Science and Pollution Research - This study estimated unbalanced panel data analysis to investigate the relationship among CO2 emissions, GDP, renewable and non-renewable energy...     

Energy and exergy analysis of a heat storage tank with a novel eutectic phase change material layer of a solar heater system

Solar energy is one of the most important renewable energy sources, but it is not available every time and every season. Thus, storing of solar energy is important. One of the popular methods of heat storage is use of phase change materials (PCMs) which have large thermal energy storage capacity. In this study, the heat storage tank in a domestic solar water heating system was chosen as control volume. The experiments were performed in the province of Elaz?g, Turkey, in November when solar radiation was weak due to cloudy sky. The heat storage tank of the system was modified to fill PCM between insulation and hot water part. A few PCMs which are Potassium Fluoride, Lithium Metaborate Dihydrate, Strontium Hydroxide Octahydrate, Barium Hydroxide Octahydrate, Aluminum Ammonium Sulfate, and Sodium Hydrogen Phosphate were analyzed to proper operating conditions using a Differential Scanning Calorimeter (DSC) and the best PCM was obtained with the Aluminum Ammonium Sulfate and Sodium Hydrogen Phosphate mixture. Thus, eutectic PCM was obtained and used in a heat storage tank of the solar water heating system. Energy and exergy analysis of heat storage tank was performed with and without the PCM. Energy and exergy analysis has shown that the heat storage tank with the PCM is more efficient than without the PCM and the maximum exergy efficiency was obtained as 22% with the heat storage tank with the PCM.     

Health risk assessment of soil trace elements using the Sequential Gaussian Simulation approach

Environmental Science and Pollution Research - In this study, the performance of the Sequential Gaussian Simulation (SGS) approach was studied with the aim of accurately determining local health...