An evaluation of mass absorption cross-section for optical carbon analysis on Teflon filter media

Black carbon (BC) or elemental carbon (EC) is a by-product of incomplete fuel combustion, and contributes adversely to human health, visibility, and climate impacts. Previous studies have examined nondestructive techniques for particle light attenuation measurements on Teflon® filters to estimate BC. The incorporation of an inline Magee Scientific OT21 transmissometer into the MTL AH-225 robotic weighing system provides the opportunity to perform optical transmission measurements on Teflon filters at the same time as the gravimetric mass measurement. In this study, we characterize the performance of the inline OT21, and apply it to determine the mass absorption cross-section (MAC) of PM_2.5 BC across the United States. We analyzed 5393 archived Teflon® filters from the Chemical Speciation Network (CSN) collected during 2010–2011 and determined MAC by comparing light attenuation on Teflon® filters to corresponding thermal EC on quartz-fiber filters. Results demonstrated the importance of the initial transmission (I₀) value used in light attenuation calculations. While light transmission varied greatly within filter lots, the average I₀ of filter blanks during the sampling period provided an estimate for archived filters. For newly collected samples, it is recommended that filter-specific I₀ measurements be made (i.e., same filter before sample collection). The estimated MAC ranged from 6.9 to 9.4 m²/g and varied by region and season across the United States, indicating that using a default value may lead to under- or overestimated BC concentrations. An analysis of the chemical composition of these samples indicated good correlation with EC for samples with higher EC content as a fraction of total PM_2.5 mass, while the presence of light-scattering species such as crustal elements impacted the correlation affecting the MAC estimate. Overall, the method is demonstrated to be a quick, cost-effective approach to estimate BC from archived and newly sampled Teflon® filters by combining both gravimetric and BC measurements.

Implications: Robotic optical analysis is a valid, cost-effective means to obtain a vast amount of BC data from archived and current routine filters. A tailored mass absorption cross-section by region and season is necessary for a more representative estimate of BC. Initial light transmission measurements play an important role due to the variability in blank filter transmission. Combining gravimetric mass and BC analysis on a single Teflon® filter reduces costs for monitoring agencies and maximizes data collection.     

Best Practices in Environmental Communication: A Case Study of Louisiana's Coastal Crisis

This mixed-method case study of environmental communication best practices in Louisiana, USA, identifies trends and approaches as informed by environmental psychology. The results provide key insights for environmental communicators, especially communicators in coastal regions. In-depth interviews with both environmental psychologists and environmental communicators showed that both groups emphasized knowing the audience, telling local stories, building relationships with target audiences and targeted messaging. Both psychologists and communicators also frequently mentioned general messaging concerns of source credibility, avoiding controversial terms and talking about issues, impacts and solutions to which the target audience can relate. A representative survey revealed that Louisiana residents are most interested in hearing about how environmental issues such as climate change, coastal land loss and flooding are affecting their own communities. This finding supports the idea that environmental communicators could do a better job tapping into strong place attachment and sense of community among coastal residents to promote action.     

Another avenue of action: an examination of climate change countermovement industries’ use of PAC donations and their relationship to Congressional voting over time

The political mobilization of American business elites in the 1970s and 1980s has been well studied by political scientists. Environmental sociologists have explored how industries in this elite countermovement have organized to prevent environmental legislation. The literature often focuses on the efforts of this movement to shape public opinion on climate change. However, political scientists argue business elites are running several parallel strategies simultaneously in order to protect their interests. FEC data are utilized in multilevel logit models to examine how donations from industrial Political Action Committees (PACs) relate to Congressional representative’s environmental voting behavior over a 20-year period. Industries associated with the environmental countermovement have increasingly used PAC donations over time, and every additional $10,000 a representative received from countermovement industries significantly decreased odds of their taking the pro-environmental stance even when controlling for representatives’ demographics, districts, Congressional polarization and time-period.     

Risk and cooperation: managing hazardous fuel in mixed ownership landscapes

Managing natural processes at the landscape scale to promote forest health is important, especially in the case of wildfire, where the ability of a landowner to protect his or her individual parcel is constrained by conditions on neighboring ownerships. However, management at a landscape scale is also challenging because it requires cooperation on plans and actions that cross ownership boundaries. Cooperation depends on people's beliefs and norms about reciprocity and perceptions of the risks and benefits of interacting with others. Using logistic regression tests on mail survey data and qualitative analysis of interviews with landowners, we examined the relationship between perceived wildfire risk and cooperation in the management of hazardous fuel by nonindustrial private forest (NIPF) owners in fire-prone landscapes of eastern Oregon. We found that NIPF owners who perceived a risk of wildfire to their properties, and perceived that conditions on nearby public forestlands contributed to this risk, were more likely to have cooperated with public agencies in the past to reduce fire risk than owners who did not perceive a risk of wildfire to their properties. Wildfire risk perception was not associated with past cooperation among NIPF owners. The greater social barriers to private-private cooperation than to private-public cooperation, and perceptions of more hazardous conditions on public compared with private forestlands may explain this difference. Owners expressed a strong willingness to cooperate with others in future cross-boundary efforts to reduce fire risk, however. We explore barriers to cooperative forest management across ownerships, and identify models of cooperation that hold potential for future collective action to reduce wildfire risk.     

Inbreeding Depression, Environmental Stress, and Population Size Variation in Scarlet Gilia (Ipomopsis aggregata)

Despite a large body of theory, few studies have directly assessed the effects of variation in population size on fitness components in natural populations of plants. We conducted studies on 10 populations of scarlet gilia, Ipomopsis aggregata , to assess the effects of population size and year-to-year variation in size on the relative fitness of plants. We showed that seed size and germination success are significantly reduced in small populations (those 100 flowering plants) of scarlet gilia. Plants from small populations are also more susceptible to environmental stress. When plants from small and large populations were subjected to an imposed stress (combined effects of transplanting and experimental clipping, simulating ungulate herbivory) in a common garden experiment, plants from small populations suffered higher mortality and were ultimately of smaller size than plants from large populations. In addition, experimental evidence indicates that observed fitness reductions are genetic, due to the effects of genetic drift and/or inbreeding depression. When pollen was introduced from distant populations into two small populations, seed mass and percentage of germination were bolstered, while pollen transferred into a large population had no significant effect. Year-to-year variation in population size and its effects on plant fitness are also discussed. In one small population, for example, a substantial increase in size from within did not introduce sufficient new (archived) genetic material to fully overcome the effects of inbreeding depression.     

A review of current knowledge concerning dry deposition of atmospheric mercury

The status of the current knowledge concerning the dry deposition of atmospheric mercury, including elemental gaseous mercury (Hg⁰), reactive gaseous mercury (RGM), and particulate mercury (Hg_p), is reviewed. The air–surface exchange of Hg⁰ is commonly bi-directional, with daytime emission and nighttime deposition over non-vegetated surfaces and vegetated surfaces with small leaf area indices under low ambient Hg⁰ conditions. However, daytime deposition has also been observed, especially when the ambient Hg⁰ is high. Typical dry deposition velocities (V_d) for Hg⁰ are in the range of 0.1–0.4 cm s^?1 over vegetated surfaces and wetlands, but substantially smaller over non-vegetated surfaces and soils below canopies. Meteorological, biological, and soil conditions, as well as the ambient Hg⁰ concentrations all play important roles in the diurnal and seasonal variations of Hg⁰ air–surface exchange processes. Measurements of RGM deposition are limited and are known to have large uncertainties. Nevertheless, all of the measurements suggest that RGM can deposit very quickly onto any type of surface, with its V_d ranging from 0.5 to 6 cm s^?1. The very limited data for Hg_p suggest that its V_d values are in the range of 0.02–2 cm s^?1.A resistance approach is commonly used in mercury transport models to estimate V_d for RGM and Hg_p; however, there is a wide range of complexities in the dry deposition scheme of Hg⁰. Although resistance-approach based dry deposition schemes seem to be able to produce the typical V_d values for RGM and Hg⁰ over different surface types, more sophisticated air–surface exchange models have been developed to handle the bi-directional exchange processes. Both existing and newly developed dry deposition schemes need further evaluation using field measurements and intercomparisons within different modelling frameworks.     

Effects of instrument precision and spatial variability on the assessment of the temporal variation of ambient air pollution in Atlanta, Georgia

Data from the U.S. Environmental Protection Agency Air Quality System, the Southeastern Aerosol Research and Characterization database, and the Assessment of Spatial Aerosol Composition in Atlanta database for 1999 through 2002 have been used to characterize error associated with instrument precision and spatial variability on the assessment of the temporal variation of ambient air pollution in Atlanta, GA. These data are being used in time series epidemiologic studies in which associations of acute respiratory and cardiovascular health outcomes and daily ambient air pollutant levels are assessed. Modified semivariograms are used to quantify the effects of instrument precision and spatial variability on the assessment of daily metrics of ambient gaseous pollutants (SO2, CO, NOx, and O3) and fine particulate matter ([PM2.5] PM2.5 mass, sulfate, nitrate, ammonium, elemental carbon [EC], and organic carbon [OC]). Variation because of instrument imprecision represented 7-40% of the temporal variation in the daily pollutant measures and was largest for the PM2.5 EC and OC. Spatial variability was greatest for primary pollutants (SO2, CO, NOx, and EC). Population-weighted variation in daily ambient air pollutant levels because of both instrument imprecision and spatial variability ranged from 20% of the temporal variation for O3 to 70% of the temporal variation for SO2 and EC. Wind     

Enhancing polychlorinated biphenyl dechlorination in fresh water sediment with biostimulation and bioaugmentation

Polychlorinated biphenyls (PCBs) are toxic compounds ubiquitously distributed in ecosystems. Microbial attenuation of these contaminants is a potential means of remediation. Two promising microbial PCB remediation technologies, biostimulation and bioaugmentation, were investigated in different sediments. Biostimulation experiments in which electron donor was supplied (H2 via elemental iron, Fe(0)) resulted in only a marginal improvement in the dechlorination of amended 2,3,4,5-tetrachlorobiphenyl (2,3,4,5-CB), likely because of an inadequate population of indigenous H2-utilizing dechlorinators. Extensive dechlorination was observed, however, after bioaugmenting microcosms with a PCB-dechlorinating enrichment culture. Dechlorination of 2,3,4,5-CB began prior to the 20th day of incubation and proceeded to 2-chlorobiphenyl. This extensive dechlorination activity was maintained in both sediments over 70d at 10 and 25 degrees C. This research demonstrates that although past studies of biostimulation were promising, a great deal must be known about the PCB-dechlorinating organisms present before successful biostimulation is expected. Bioaugmentation, however, appears to be a promising PCB remediation strategy and should be further pursued.     

Comparison of Field Performance of Multiple Soil Moisture Sensors in a Semi‐Arid Rangeland1

Abstract:  Automated electronic soil moisture sensors, such as time domain reflectometry (TDR) and capacitance probes are being used extensively to monitor and measure soil moisture in a variety of scientific and land management applications. These sensors are often used for a wide range of soil moisture applications such as drought forage prediction or validation of large‐scale remote sensing instruments. The convergence of three different research projects facilitated the evaluation and comparison of three commercially available electronic soil moisture probes under field application conditions. The sensors are all installed in shallow soil profiles in a well instrumented small semi‐arid shrub covered subwatershed in Southeastern Arizona. The sensors use either a TDR or a capacitance technique; both of which indirectly measure the soil dielectric constant to determine the soil moisture content. Sensors are evaluated over a range of conditions during three seasons comparing responses to natural wetting and drying sequences and using water balance and infiltration simulation models. Each of the sensors responded to the majority of precipitation events; however, they varied greatly in response time and magnitude from each other. Measured profile soil moisture storage compared better to water balance estimates when soil moisture in deeper layers was accounted for in the calculations. No distinct or consistent trend was detected when comparing the responses from the sensors or the infiltration model to individual precipitation events. The results underscore the need to understand how the sensors respond under field application and recognize the limitations of soil moisture sensors and the factors that can affect their accuracy in predicting soil moisture in situ.