Effects of flue gas composition on the catalytic destruction of chlorinated aromatic compounds with a V-oxide catalyst

When using catalytic flue gas cleaning, several flue gas compounds may influence oxidation reactions of hazardous volatile organic compounds, possibly leading to lower reaction rates and, thus, to an incomplete destruction. Experimental investigations were performed with regard to the influence of selected flue gas compounds, like hydrogen chloride, sulfur dioxide, oxygen, and water vapour, on the catalytic destruction behavior of chlorobenzenes under flue gas cleaning conditions of an incineration plant. For this purpose, a metal oxide catalyst was operated at different temperatures at a space velocity of 3600 h-1 in a laboratory-scale fixed bed reactor with model flue gases, and with real flue gases generated from the TAMARA waste incineration plant. The results obtained from the studies with model flue gas were analyzed with respect to reaction kinetics. These kinetics were applied for comparison with the experimental data gained in the real flue gas.     

Toward sustainable livelihoods after war: Reconstituting rural land tenure systems

Land tenure plays a primary role in sustainable development efforts. However armed conflict and its repercussions reconfigure the network of social relations upon which all land tenure systems depend. In post‐conflict settings new laws have the opportunity to address tenure issues in the context of what people are already doing ‘on the ground’, with a view to moving from the fluidity of post‐conflict situations to a more solidified and peaceful social and legal environment. However there exists a lack of tools to analyze postwar land tenure and the prospects for reconstituting tenure systems to support recovery and development. This paper uses the Sustainable Livelihoods framework to examine postwar land tenure issues in order to draw out latent opportunities within emergent informal smallholder tenure constructs which may have utility in the reconstitution of national tenure systems.     

Migrant land rights reception and 'clearing to claim' in sub-Saharan Africa: A deforestation example from southern Zambia

The relationship between migration and deforestation in the developing world continues to receive significant attention. However beyond direct population increase, the precise mechanisms that operate within the intersection of migrant/host land rights remain largely unexamined. Where migrants are provided with land and rights by the State and/or local communities, how such rights are perceived by the migrants is of primary importance in their interaction with land resources, and in aggregate it impacts the development opportunities and environmental repercussions of migration. The authors analyze the operative aspects of land rights reception (as opposed to provision) by migrant populations, and the relationship between this reception and deforestation. The article examines a case in Zambia to analyze how tenurial constructs, emerging from the way rights are perceived by migrants, lead to the continued clearing of areas much larger than needed for cultivation, even when the arrangement appears counter‐productive in terms of land rights provision and labour allocation. While valuable policy efforts have focused on providing resource rights to migrants, how such rights are received and the relationship of this reception to resource management needs greater policy attention.     

The role of off-farm employment in tropical forest conservation: labor, migration, and smallholder attitudes toward land in western Uganda

The potential for off-farm employment (OFE) to contribute significantly to forest conservation in the tropics is a widely held logic among donors, governments, and social scientists. While an aggregate level examination of OFE cases can support this logic, there is disagreement as to the operative aspects of specific linkages and assumptions. This study examines the case of the tea industry in western Uganda, and uses a combination of fieldwork and remote sensing to pursue a more nuanced examination of the role of migration and non-monetary aspects of OFE on forest conservation in both a national park and unprotected forest contexts. Results indicate that the tea industry does serve as an off-farm employer to a limited number of local smallholders but these benefits are offset by the industry's overwhelming dependence on migrant labor which sees OFE as temporary, then seeks to settle locally. There is also evidence that the tea industry is contributing to conservation efforts of Kibale National Park by unintentionally serving as a physical buffer zone, which inhibits both human encroachment on the park and wildlife encroachment on smallholder crops. The latter represents a site-specific phenomenon that holds much potential for future management plans of the area and exemplifies the importance of considering the site-specific circumstances associated with OFE development.     

Nitrate leaching and turf quality in established 'Floratam' St. Augustinegrass and 'Empire' zoysiagrass

The objectives of this research were to evaluate nitrate N (NO3-N) leaching and turf response to nitrogen rate (NR) and irrigation regime (IR) in 'Floratam' St. Augustinegrass ( [Walt.] Kuntze.) and 'Empire' zoysiagrass ( Steud). The research was conducted in Citra, FL, from 2005 through 2007. Nitrogen (N) was applied at annual rates of 32, 64, 128, and 196 kg ha?1 in 2005, and at 49, 196, 343, or 490 kg ha?1 in 2006 and 2007. Irrigation treatments consisted of 1.3 cm applied twice weekly or 2.6 cm applied once weekly. In general, NO?-N leaching was greater from zoysiagrass. In 2007, annual NO?-N leached varied due to the interaction of NR, IR, and grass. There was little association between NR and increased NO?-N leaching in St. Augustinegrass in any year. While St. Augustinegrass had no differences in NO?-N leached within NR due to IR, there were some differences in NO?-N leached from zoysiagrass at some N levels, with greater NO?-N leached from the more frequent irrigation regime. Turf quality (TQ) was generally above an acceptable level in St. Augustinegrass at all but the lowest NRs and at all NRs in zoysiagrass with the exception of the spring fertilizer cycle (SFC) in 2007, when high NR treatments resulted in disease. Maintenance of a healthy turfgrass cover is an important strategy for reducing potential nutrient movement from fertilizer application. The current recommended rates for St. Augustinegrass provide good turf cover and health, and result in minimal NO?-N leaching. Zoysiagrass N rates may need to be revised downward to reduce disease, improve turf cover, and reduce NO?-N leaching.     

Restocking refugee pastoralists in the horn of Africa

Repeated and lingering famine in the Horn of Africa has produced enormous pastoralist refugee populations in a region where livestock production is a major form of land use. Permanently settling destitute pastoralists has a record of failure. It can disrupt host land-uses, causing social and ecological problems, and prevent the utilization of very large grazing areas where pastoralism may be the only ecologically and economically sustainable land-use. Herd reconstitution should be considered an option in relief and rehabilitation programmes for pastoralists. This paper examines a design where the most proven and immediate way of sustaining stockless pastoralists – farming – can be used to facilitate restocking objectives. Using data gathered in Somalia, estimates of livestock carrying capacity are linked with forage resources, land area, livestock units, and the frequency of good, average, and poor (drought) water years, to explore the possibilities for incorporating restocking into refugee rehabilitation efforts.     

Mastrus ridibundus parasitoids eavesdrop on cocoon-spinning codling moth, Cydia pomonella, larvae

Cocoon-spinning larvae of the codling moth, Cydia pomonella L. (Lepidoptera: Olethreutidae) employ a pheromone that attracts or arrests conspecifics seeking pupation sites. Such intraspecific communication signals are important cues for illicit receivers such as parasitoids to exploit. We tested the hypothesis that the prepupal C. pomonella parasitoid Mastrus ridibundus Gravenhorst (Hymenoptera: Ichneumonidae) exploits the larval aggregation pheromone to locate host prepupae. In laboratory olfactometer experiments, female M. ridibundus were attracted to 3-day-old cocoons containing C. pomonella larvae or prepupae. Older cocoons containing C. pomonella pupae, or larvae and prepupae excised from cocoons, were not attractive. In gas chromatographic-electroantennographic detection (GC-EAD) analyses of bioactive Porapak Q extract of cocoon-derived airborne semiochemicals, ten compounds elicited responses from female M. ridibundus antennae. Comparative GC-mass spectrometry of authentic standards and cocoon-volatiles determined that these compounds were 3-carene, myrcene, heptanal, octanal, nonanal, decanal, (E)-2-octenal, (E)-2-nonenal, sulcatone, and geranylacetone. A synthetic 11-component blend consisting of these ten EAD-active compounds plus EAD-inactive (+)-limonene (the most abundant cocoon-derived volatile) was as effective as Porapak Q cocoon extract in attracting both female M. ridibundus and C. pomonella larvae seeking pupation sites. Only three components could be deleted from the 11-component blend without diminishing its attractiveness to M. ridibundus, which underlines the complexity of information received and processed during foraging for hosts. Mastrus ridibundus obviously eavesdrop on the pheromonal communication signals of C. pomonella larvae that reliably indicate host presence.

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