Magnetic nanoparticles incorporation into different substrates for dyes and heavy metals removal—A Review

Environmental Science and Pollution Research - Substantial discharge of hazardous substances, especially dyes and heavy metal ions to the environment, has become a global concern due to...     

Treating wastewater under zero waste principle using wetland mesocosms

• Smart wetland was designed to treat wastewater according to zero waste principle. • The system included a dynamic roughing filter, Cyperus papyrus (L.) and zeolite. • It removed 98.8 and 99.8% of chemical and bacterial pollutants in 3 days. • The effluent reused to irrigate a landscape and the sludge recycled as fertilizer. • The plant biomass is a profitable resource for antibacterial and antioxidants. The present investigation demonstrates the synergistic action of using a sedimentation unit together with Cyperus papyrus (L.) wetland enriched with zeolite mineral in one-year round experiment for treating wastewater. The system was designed to support a horizontal surface flow pattern and showed satisfactory removal efficiencies for both physicochemical and bacteriological contaminants within 3 days of residence time. The removal efficiencies ranged between 76.3% and 98.8% for total suspended solids, turbidity, iron, biological oxygen demand, and ammonia. The bacterial indicators (total and fecal coliforms, as well as fecal streptococci) and the potential pathogens (Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa) showed removal efficiencies ranged between 96.9% and 99.8%. We expect the system to offer a smart management for every component according to zero waste principle. The treated effluent was reused to irrigate the landscape of pilot area, and the excess sludge was recycled as fertilizer and soil conditioner. The zeolite mineral did not require regeneration for almost 36 weeks of operation, and enhanced the density of shoots (14.11%) and the height of shoots (15.88%). The harvested plant biomass could be a profitable resource for potent antibacterial and antioxidant bioactive compounds. This could certainly offset part of the operation and maintenance costs and optimize the system implementation feasibility. Although the experiment was designed under local conditions, its results could provide insights to upgrade and optimize the performance of other analogous large-scale constructed wetlands.     

Removal of dye using peroxidase-immobilized Buckypaper/polyvinyl alcohol membrane in a multi-stage filtration column via RSM and ANFIS

Environmental Science and Pollution Research - The feasibility and performance of Jicama peroxidase (JP) immobilized Buckypaper/polyvinyl alcohol (BP/PVA) membrane for methylene blue (MB) dye...     

Spongy Ni/Fe carbonate-fluorapatite catalyst for efficient conversion of cooking oil waste into biodiesel

Environmental Chemistry Letters - Biodiesel produced from animal and plant fat oils is sustainable, but there is a need for efficient heterogeneous catalysts for transesterification of crude oils...     

Carbon and polymer-based magnetic nanocomposites for oil-spill remediation—a comprehensive review

Environmental Science and Pollution Research - Oil spills are a major contributor to water contamination, which sets off a significant impact on the environment, biodiversity, and economy....     

Synthesis of Chitosan@activated Carbon Beads with Abundant Amino Groups for Capture of Cu(II) and Cd(II) from Aqueous Solutions

In this study, chitosan and bio-based activated carbon obtained from sugarcane bagasse biowaste were used for the synthesis of efficient sorbent for Cu(II) and Cd(II) ion via precipitation method. The prepared material was enriched with amino groups through grafting tetraethylenepentamine and tested for heavy metal remediation from water samples. The influence of pH was investigated showing optimum sorption at pH 6 for Cu(II) and Cd(II). Sorption tests, explained by means of the most common sorption models, evidenced that the best performances were reached pointing out the promising application of the prepared sorbent for water purification treatments: Uptake kinetics are relatively fast: the equilibrium was reached within 140 min; and the kinetic profiles were preferentially fitted by the pseudo-second order rate equation. Sorption isotherms are fitted by Langmuir equation. The sorbent showed high metal ion sorption capacity with negligible influence of ion strength. The maximum sorption capacities reached 3.44 and 2.38 mmol g^??1 for Cu(II) and Cd(II), respectively at 298 K. Thermodynamic parameters were evaluated through variation of temperature. The sorption is unfavorable at elevated temperatures. Metal ions were successfully desorbed using 1 M HNO₃ solution.     

Magnetic nanocomposites for sustainable water purification—a comprehensive review

Numerous contaminants in huge amounts are discharged to the environment from various anthropogenic activities. Waterbodies are one of the major receivers of these contaminants. The contaminated water can pose serious threats to humans and animals, by distrubing the ecosystem. In treating the contaminated water, adsorption processes have attained significant maturity due to lower cost, easy operation and environmental friendliness. The adsorption process uses various adsorbent materials and some of emerging adsorbent materials include carbon- and polymer-based magnetic nanocomposites. These hybrid magnetic nanocomposites have attained extensive applications in water treatment technologies due to their magnetic properties as well as combination of unique characteristics of organic and inorganic elements. Carbon- and polymer-related magnetic nanocomposites are more adapted materials for the removal of various kinds of contaminants from waterbodies. These nanocomposites can be produced via different approaches such as filling, pulse-laser irradiation, ball milling, and electro-spinning. This comprehensive review is compiled by reviewing published work of last the latest recent 3 years. The review article extensively focuses on different approaches for producing various carbon- and polymer-based magnetic nanocomposites, their merits and demerits and applications for sustainable water purification. More specifically, use of carbon- and polymer-based magnetic nanocomposites for removal of heavy metal ions and dyes is discussed in detail, critically analyzed and compared with other technologies. In addition, commercial viability in terms of regeneration of adsorbents is also reviewed. Furthermore, the future challenges and prospects in employing magnetic nanocomposites for contaminant removal from various water sources are presented.

     

Rapid adsorption of toxic Pb(Ⅱ) ions from aqueous solution using multiwall carbon nanotubes synthesized by microwave chemical vapor deposition technique

Multiwall carbon nanotubes(MWCNTs) were synthesized using a tubular microwave chemical vapor deposition technique, using acetylene and hydrogen as the precursor gases and ferrocene as catalyst. The novel MWCNT samples were tested for their performance in terms of Pb(Ⅱ)binding. The synthesized MWCNT samples were characterized using Fourier Transform Infrared(FT-IR), Brunauer, Emmett and Teller(BET), Field Emission Scanning Electron Microscopy(FESEM) analysis, and the adsorption of Pb(Ⅱ) was studied as a function of p H,initial Pb(Ⅱ) concentration, MWCNT dosage, agitation speed, and adsorption time, and process parameters were optimized. The adsorption data followed both Freundlich and Langmuir isotherms. On the basis of the Langmuir model, Qmaxwas calculated to be 104.2 mg/g for the microwave-synthesized MWCNTs. In order to investigate the dynamic behavior of MWCNTs as an adsorbent, the kinetic data were modeled using pseudo first-order and pseudo second-order equations. Different thermodynamic parameters, viz., ΔH0, ΔS0and ΔG0were evaluated and it was found that the adsorption was feasible, spontaneous and endothermic in nature. The statistical analysis revealed that the optimum conditions for the highest removal(99.9%) of Pb(Ⅱ) are at p H 5, MWCNT dosage 0.1 g, agitation speed 160 r/min and time of 22.5 min with the initial concentration of 10 mg/L. Our results proved that microwave-synthesized MWCNTs can be used as an effective Pb(Ⅱ) adsorbent due to their high adsorption capacity as well as the short adsorption time needed to achieve equilibrium.     

Genetic polymorphisms in XRCC1, OGG1, and XRCC3 DNA repair genes and DNA damage in radiotherapy workers

DNA damage may develop at any dose of ionizing radiation. DNA damage activates pathways that regulate cell growth and division or coordinate its replication and repair. The repair pathways, base excision repair (BER) and single-strand break repair (SSBR), can repair such damages efficiently and maintain genome integrity. Loss of this repair process or alteration of its control will be associated with serious outcomes for cells and individuals. This study aimed to determine the relationship between XRCC1 (Arg194Trp, Arg280His, and Arg399Gln), OGG1 (Ser326Cys), and XRCC3 (Thr241Met) SNPs and DNA damage and to identify high-risk individuals with reduced DNA repair capacity. This case-control study was conducted on 80 subjects; 50 subjects working in Clinical Oncology and Nuclear Medicine Department in Assiut University Hospital along with 30 controls. A total of 1 mL blood samples were collected for Single-Cell Gel Electrophoresis Technique (Comet Assay) for detection of DNA damage in those subjects. A total of 3 mL fresh blood samples were collected and analyzed by polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP)–based technique. DNA damage detected by comet test was significantly high in IR-exposed workers than control. Statistically high significant difference was found in exposed subjects versus control subjects regarding the frequencies of the variant alleles of hOGG1³²⁶, XRCC1^{280 & 399}, and XRCC3²⁴¹. The level of DNA damage was not affected by OGG1³²⁶ SNPs when comparing subjects of wild genotype with those of (pooled) variants either in the exposed staff or in the control group while XRCC1^{280, 399} and XRCC3²⁴¹ variant alleles had an influence on the studied DNA damage biomarker. Moreover, genotyping distribution pattern was highly variable in relation to gender. The present study indicated a relationship between DNA damage detected by comet test and single nucleotide polymorphisms in genes coding for DNA certain repair enzymes. Individuals occupationally exposed to low doses of ionizing radiation could be at great risk and more susceptible to the increased DNA damage if they have inherited genetic polymorphism.

     

Environmental chemistry in the twenty-first century

Human society actually faces many environmental challenges such as environmental pollution, climate changes and loss of biodiversity. These issues induce major risks for ecosystems and are a serious threat for further life on Earth. Anthropogenic pressure may continue to exacerbate the present-day problems. Prevention and mitigation of environmental issues demands sound science and dedicated political support. For that, environmental chemistry is a central and multidisciplinary science that will provide new concepts and applied methods to solve actual environmental issues. Here, we outline the scope of environmental chemistry. The Anthropocene era and major chemical disasters are discussed. We present also the challenges of atmospheric chemistry, analytical chemistry, statistics and chemometrics, and education in environmental chemistry.