Thermal and mechanical properties of poly(lactic Acid) and poly(ethylene/butylene Succinate) blends

In this study, blends of poly (lactic acid) (PLA) with poly(ethylene/butylene succinate) (Bionolle) have been investigated for their thermal and mechanical properties as a function of the concentration of Bionolle. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile tests were used to characterize the blends. From the results of the DMA and DSC, it was found that this blend system was not miscible within the compositions studied. DSC results showed that adding Bionolle aids in crystallization of PLA. It was observed that increasing the Bionolle concentration led to a slight increase in the strain-at-break of the blends but a decrease in the Young’s modulus and ultimate tensile strength. Biaxially oriented films showed an increase in tensile strength, modulus, and strain-at-break.     

Use of native mosses as biomonitors of heavy metals and nitrogen deposition in the surroundings of two steel works

A biomonitoring survey using the moss species Hypnum cupressiforme Hedw. was conducted in the surroundings of two steel plants located in the North of Spain. Levels of V, Cr, Ni, Cu, Zn, As, Cd, Hg, Pb and N were determined. Very high concentrations in the areas of study were detected when compared to nearby unaffected regions. Similar trends were observed for all the elements in the differently orientated transects, showing an appreciable influence of the NW prevailing winds of the region in the dispersion of pollutants, as well as a clear decreasing gradient in the concentrations of metals in mosses within a distance of 1500 meters from the facilities. A differentiation between the elements emitted by the chimney as result of the industrial activity (V, Cr, Ni, Cu and As) and those with a high presence in steel slag deposits (Zn, Cd, Hg and Pb) was observed. The range of contamination was also established by means of the Contamination Factor, indicating a category 4 out of 6 categories, which shows the high levels reported in the areas of study. A different dynamic was registered for nitrogen regarding the rest of the heavy metals analysed except for Hg, probably due to the elevated volatility and mobility of both elements, as well as their high persistence in the atmosphere.     

Meadow Restoration Increases Baseflow and Groundwater Storage in the Sierra Nevada Mountains of California

In mountains of the western United States, channel incision has drawn down the water table across thousands of square kilometers of meadow floodplain. Here climate change is resulting in earlier melt and reduced snowpack and water resource managers are responding by investing in meadow restoration to increase springtime storage and summer flows. The record‐setting California drought (2012–2015) provided an opportunity to evaluate this strategy under the warmer and drier conditions expected to impact mountain water supplies. In 2012, 0.1 km² of meadow floodplain was reconnected by filling an incised channel through Indian Valley in the central Sierra Nevada Mountains of California. Despite sustained drought conditions after restoration, summer baseflow from the meadow increased 5–12 times. Before restoration, the total summer outflow from the meadow was 5% more than the total summer inflow. After restoration, total summer outflow from the meadow was between 35% and 95% more than total summer inflow. In the worst year of the drought (2015), when inflow to the meadow ceased for at least one month, summer baseflow was at least five times greater than before restoration. Groundwater levels also rose at four out of five sites near the stream channel. Filling the incised channel and reconnecting the meadow floodplain increased water availability and streamflow, despite unprecedented drought conditions.     

Early reproductive success of western bluebirds and ash-throated flycatchers: a landscape-contaminant perspective

Eggshell quality, clutch size, sex ratio, and hatching success of western bluebirds (Sialia mexicana) and ash-throated flycatchers (Myiarchus cinerascens) were studied on a landscape-soil contaminant gradient at Los Alamos National Laboratory (LANL) in New Mexico from 1997 to 1999. A variety of contaminants (heavy metals, chemicals, insecticides, polychlorinated biphenyls (PCBs), organochlorines, and radioactive isotopes) range across different spatial scales and concentrations on LANL land. This study is an example of a monitoring program over a large area with varying degree of contamination that is used to highlight locations of concern for future research. There were two locations where the flycatcher had a lower hatching success. The bluebirds at Sandia wetland, a location of concern for PCBs. had a thinner eggshell thickness index (RATCLIFFE) and the eggs were smaller than at other locations. The flycatcher had thinner eggshells than bluebirds, which could add to sensitivity to exposure to contaminants. There was no variation in clutch size or sex ratio between locations or areas closer to contaminant release sites for both species. Percent females in the clutch ranged from 0 to 100% in the WEBL and from 33 to 67% for ATFL.     

Reply to Discussion

In the Discussion, Nash et al. (2019) estimate the seasonal change in groundwater volume for a portion of the restored Sierra Nevada Meadow that we evaluated (Hunt et al. 2018) and use this estimate as an upper bound on the possible contribution to flow that is attributable to restoration. The authors conclude that raising the channel bed elevation and reconnecting the meadow floodplain most likely reduced summer streamflow. In contrast, we report at least a fivefold increase in baseflow from the meadow in the years following restoration. In addition, we observed that, after restoration, the previously intermittent stream below the meadow flowed continuously throughout the summer months, despite record drought conditions, and in 2015, the lowest snowpack on record. We suggest that the groundwater budget presented in the Discussion may not adequately represent conditions within the meadow because the authors extrapolate from 5 near‐channel groundwater wells across 62 ha of meadow and assume an area of influence that is approximately one‐sixth of the meadow area. We conclude that the conversion of an intermittent stream to perennial flow during drought conditions is a stronger check on our gauge data than the groundwater budget presented in the Discussion.     

Stable isotope dynamics of nitrogen sewage effluent uptake in a semi-arid wetland

Our objectives were to determine (1) how much N is transferred into the food web via plants from a wetland receiving not only inputs of treated sewage effluent, but also containing contaminants such as polychlorinated biphenyls (PCBs), (2) how birds, as consumers, utilize exogenous N and uptake PCBs in relation to the food web of the wetlands, (3) the feasibility of using isotopic analysis in estimating trophic levels in a semi-arid system. Our results demonstrate that there is very high spatial variability in the N isotopic composition of primary producers. Birds had lower variability in delta15N, despite feeding at multiple trophic levels. In very high spatial variability in delta15N of primary producers, it is difficult to use N isotope techniques to define trophic levels relevant to the bioaccumulation of organic pollutants, but it is possible to track the flow of exogenous N through the food web.     

Relation of Benzene Soluble Organic Matter to Suspended Participate Matter in the Atmosphere

This paper presents information concerning the response to the availability of control program grants under Sect. 4 of the Clean Air Act, P.L. 88-206. Statistics concerning awards are presented together with a discussion of the nature of the projects supported and the impact of this support on air pollution control efforts throughout the country.     

Occurrence of triclosan in plasma of wild Atlantic bottlenose dolphins (Tursiops truncatus) and in their environment

The presence of triclosan, a widely-used antibacterial chemical, is currently unknown in higher trophic-level species such as marine mammals. Blood plasma collected from wild bottlenose dolphins (Tursiops truncatus) in Charleston, SC (CHS) (n = 13) and Indian River Lagoon, FL (IRL) (n = 13) in 2005 was analyzed for triclosan. Plasma concentrations in CHS dolphins ranged from 0.12 to 0.27 ng/g wet weight (mean 0.18 ng/g), with 31% of the sampled individuals having detectable triclosan. The mean IRL dolphin plasma concentrations were 0.072 ng/g wet weight (range 0.025–0.11 ng/g); 23% of the samples having detectable triclosan. In the CHS area, triclosan effluent values from two WWTP were both 190 ng/L and primary influents were 2800 ng/L and 3400 ng/L. Triclosan values in CHS estuarine surface water samples averaged 7.5 ng/L (n = 18) ranging from 4.9 to 14 ng/L. This is the first study to report bioaccumulation of anthropogenic triclosan in a marine mammal highlighting the need for further monitoring and assessment.     

The development and application of remote sensing to monitor sand dune habitats

Sand dunes are complex systems that contain several habitats, often as mosaics or transitions between types. Several of these habitats are afforded protection under European Legislation and in the UK nationally within Special Areas of Conservation (SAC) and Sites of Special Scientific Interest (SSSI). Natural England has a statutory duty to report to Europe on the conservation status and condition of sand dunes; and is required to report to the UK Government on designated sites. To achieve this we have sought ways of capturing, analysing and interpreting data on the extent and location of sand dune habitats. This requires an ability to be able to obtain data over large areas of coastline in an efficient way. Natural England and Environment Agency Geomatics have worked collaboratively for over 16 years, sharing data and ecological knowledge. In 2012 work started to evaluate the use of remote sensing to map UK BAP and Annex I sand dune habitats. A methodology has now been developed and tested to map sand dune habitats. The key objective was to provide an operational tool that will help to map these habitats and understand change on sites around England. This has been achieved through analysis of LIDAR and Compact Airborne Spectrographic Imager (CASI) data using Object Orientated Image Analysis. Quality Control (QC) and accuracy assessments have shown this approach to be successful and 11 sites have been mapped to date. These techniques are providing a new approach to monitoring change in coastal vegetation communities and informing management of protected sites.