Why ozonolysis may not increase the hydrophilicity of particles

It is commonly assumed that atmospheric oxidation of hydrocarbon particles or hydrocarbon coatings on particles leads to polar products and increased water uptake, altering atmospheric visibility and increasing the likelihood they will act as cloud condensation nuclei (CCN). We show here through laboratory experiments that increased water uptake depends on the 3-dimensional structure of the particles. Laboratory studies of particles formed during ozonolysis of surface-bound alkenes, present as terminally unsaturated self-assembled monolayers (C8= SAM) on a silica substrate, were carried out at room temperature and 1 atm pressure. SAMs were exposed to ～10¹³ O₃ molecules cm^?3 for 40 min and resultant particles were analyzed using single particle Fourier transform infrared micro-spectroscopy (micro-FTIR) and secondary ion mass spectroscopy (SIMS). Spectroscopy results show that –COOH and other polar groups are formed but are buried inside a hydrophobic shell, consistent with earlier observations (McIntire et al., 2005, Moussa et al., 2009) that water uptake does not increase after reaction of the terminal alkene with O₃. These insights into the 3-D structure of particles formed on oxidation have important implications for the ability of secondary organic aerosols to act as CCN. In addition, the nature of the surface of the particles is expected to determine their uptake into biological systems such as the surface of the lungs.     

A lake classification concept for a more accurate global estimate of the dissolved inorganic carbon export from terrestrial ecosystems to inland waters

The magnitude of lateral dissolved inorganic carbon (DIC) export from terrestrial ecosystems to inland waters strongly influences the estimate of the global terrestrial carbon dioxide (CO₂) sink. At present, no reliable number of this export is available, and the few studies estimating the lateral DIC export assume that all lakes on Earth function similarly. However, lakes can function along a continuum from passive carbon transporters (passive open channels) to highly active carbon transformers with efficient in-lake CO₂ production and loss. We developed and applied a conceptual model to demonstrate how the assumed function of lakes in carbon cycling can affect calculations of the global lateral DIC export from terrestrial ecosystems to inland waters. Using global data on in-lake CO₂ production by mineralization as well as CO₂ loss by emission, primary production, and carbonate precipitation in lakes, we estimated that the global lateral DIC export can lie within the range of \( {0.70}_{-0.31}^{+0.27} \) to \( {1.52}_{-0.90}^{+1.09} \) Pg C yr^?1 depending on the assumed function of lakes. Thus, the considered lake function has a large effect on the calculated lateral DIC export from terrestrial ecosystems to inland waters. We conclude that more robust estimates of CO₂ sinks and sources will require the classification of lakes into their predominant function. This functional lake classification concept becomes particularly important for the estimation of future CO₂ sinks and sources, since in-lake carbon transformation is predicted to be altered with climate change.     

USE OF THE DELPHI METHOD IN RESOLVING COMPLEX WATER RESOURCES ISSUES1

ABSTRACT: The tri‐state river basins, shared by Georgia, Alabama, and Florida, are being modeled by the U.S. Fish and Wildlife Service and the U.S. Army Corps of Engineers to help facilitate agreement in an acrimonious water dispute among these different state governments. Modeling of such basin reservoir operations requires parallel understanding of several river system components: hydropower production, flood control, municipal and industrial water use, navigation, and reservoir fisheries requirements. The Delphi method, using repetitive surveying of experts, was applied to determine fisheries' water and lake‐level requirements on 25 reservoirs in these interstate basins. The Delphi technique allowed the needs and requirements of fish populations to be brought into the modeling effort on equal footing with other water supply and demand components. When the subject matter is concisely defined and limited, this technique can rapidly assess expert opinion on any natural resource issue, and even move expert opinion toward greater agreement.     

Wettability hysteresis and its implications for DNAPL source zone distribution

Subsurface heterogeneity at sites contaminated with nonaqueous phase liquids (NAPLs) reduces the effectiveness of traditional remediation measures. One cause may be the increased proportion of NAPL that is hydraulically isolated due to capillary trapping in heterogeneously-wetted materials. This study examines the wettability of ten materials, ranging from minerals, such as calcite and dolomite, to carbonaceous materials, such shale and coal, in air and water, NAPL and air, and NAPL and water systems. The wettability differed depending on which phase the solid material was initially immersed in: the less crystalline solids, if initially contacted by water were water-wet, but if initially contacted by NAPL were NAPL-wet. This difference, termed here wettability hysteresis, was observed for a suite of halogenated NAPLs and was independent of equilibration time. The degree of wettability hysteresis was greatest in the NAPL and water systems, with the magnitude of the difference increasing with the carbonaceous materials. Since the degree of capillary trapping in subsurface materials is related to wettability, the phenomenon of wettability hysteresis suggests that system history is a factor that may increase the heterogeneity of NAPL source zones.     

Improving food security in Swaziland: The transition from subsistence to communally managed cash cropping

The Komati Downstream Development Project (KDDP), based upon the Maguga Dam has enabled 6,000 hectares of semi‐arid lowveld, in a region with low and highly variable rainfall to be converted from subsistence to irrigated commercial farming, mainly of sugar cane. This has transformed the Swazi sugar industry from one dominated by a small number of large‐scale commercial estates to one where more than 1,500 previously impoverished small‐scale Swazi farmers have been able to enter the industry by joining farmers’ associations and creating communally managed farms. Recent changes to the EU's Sugar Protocol have undermined the financial viability of the KDDP farms and undermined food security, especially for the poorest, due to the cut in sugar prices. However, some farmers’ associations have opted to keep some of their land as irrigated home gardens, rather than convert all their land to sugar cane. This model has improved food security at a time of low sugar prices and points to a more sustainable way of using water from large scale dams than the conventional model. It is argued that the EU should target support to members of the KDDP who have taken out large‐scale loans to pay for the in‐field infrastructure and encourage all farmers’ associations to adopt the food garden model. This would enable them to continue to benefit from the irrigation through improved production of subsistence crops, whilst they diversify their commercial production into novel markets.     

Evaluating Cover Crops (Sudex,Sunn Hemp,Oats) for Use as Vegetative Filters to Control Sediment and Nutrient Loading From Agricultural Runoff in a Hawaiian Watershed1

Abstract: A study was conducted to determine the effects of three land covers (sunn hemp –Crotalaria juncea, sudex, a sorghum‐sudangrass hybrid –Sorghum bicolor x S. bicolor var. sudanese, and common oats –Avena sativa) planted as vegetative filter strips on the reduction of sediment and nutrient loading of surface runoff within the Kaika‐Waialua watershed on the island of Oahu, Hawaii. Runoff samples were collected and analyzed for total suspended solids (TSS), total dissolved solids (TDS), phosphorous, and three forms of nitrogen (nitrate, ammonium, total nitrogen). Study results show that during seven out of 10 runoff events, the three cover crop treatments significantly reduced TSS as compared to the fallow treatment. Average removal efficiencies were 85, 77, and 73% for oats, sunn hemp, and sudex, respectively, as compared to the fallow treatment. Nutrient concentrations were low with phosphorous concentrations, lower than 1 (μg/ml) for all treatments, and total nitrogen (TN) concentrations below 7 (μg/ml) except in the sunn hemp treatment, where TN concentrations were less than 10 (μg/ml). Results of analysis of TDS showed that the cover crop treatments did not decrease dissolved solids concentrations in comparison with the fallow treatment. Analysis of nutrient concentrations in runoff samples did not detect any significant decreases in phosphorous, nitrogen, ammonium, or TN concentrations in comparison to the fallow treatment. However, a significant increase in TN concentrations in the sunn hemp treatment was detected and showed the nitrogen fixing capacity of sunn hemp. No treatment effects on runoff volume were detected, and runoff volumes were directly correlated with rainfall amounts showing no crops significantly impacted soil infiltration rates. These results were attributed to extremely low soil hydraulic conductivities (0.0001‐7 cm/day at the soil surface, 15 and 30 cm below the soil surface). This study showed that cover crops planted as vegetative filters can effectively reduce sediment loads coming from idle and fallow fields on moderately steep volcanically derived highly weathered soils.     

Modeling scale up of anthropogenic impacts from individual pollinator behavior to pollination systems

Understanding how anthropogenic disturbances affect plant–pollinator systems has important implications for the conservation of biodiversity and ecosystem functioning. Previous laboratory studies show that pesticides and pathogens, which have been implicated in the rapid global decline of pollinators over recent years, can impair behavioral processes needed for pollinators to adaptively exploit floral resources and effectively transfer pollen among plants. However, the potential for these sublethal stressor effects on pollinator–plant interactions at the individual level to scale up into changes to the dynamics of wild plant and pollinator populations at the system level remains unclear. We developed an empirically parameterized agent-based model of a bumblebee pollination system called SimBee to test for effects of stressor-induced decreases in the memory capacity and information processing speed of individual foragers on bee abundance (scenario 1), plant diversity (scenario 2), and bee–plant system stability (scenario 3) over 20 virtual seasons. Modeling of a simple pollination network of a bumblebee and four co-flowering bee-pollinated plant species indicated that bee decline and plant species extinction events could occur when only 25% of the forager population showed cognitive impairment. Higher percentages of impairment caused 50% bee loss in just five virtual seasons and system-wide extinction events in less than 20 virtual seasons under some conditions. Plant species extinctions occurred regardless of bee population size, indicating that stressor-induced changes to pollinator behavior alone could drive species loss from plant communities. These findings indicate that sublethal stressor effects on pollinator behavioral mechanisms, although seemingly insignificant at the level of individuals, have the cumulative potential in principle to degrade plant–pollinator species interactions at the system level. Our work highlights the importance of an agent-based modeling approach for the identification and mitigation of anthropogenic impacts on plant–pollinator systems.     

Tracking post-nesting movements of loggerhead turtles (Caretta caretta) with sonic and radio telemetry on the southwest coast of Florida, USA

Nine post-nesting loggerhead turtles (Caretta caretta) were tracked using sonic and radio telemetry. Tracking began immediately after the turtles left the beach and continued until contact was either lost or terminated. As sonic tags transmit continuously underwater, they were much more effective than the radio tags in determining the paths of the turtles. Radio tags transmit only at the surface and were useful in ascertaining submergence durations. For nine of the ten turtles tracked with sonic signals, the gross movement was away from the beach in a westerly direction. The tracking periods ranged from 3.35 to 8.25 h, while the straight-line movements ranged from 3.05 to 12.88 km, respectively. Sixty-seven percent of the submergence durations recorded were <3 min. This respiratory behavior suggests continuous swimming, and the paths of the turtles suggested directed movement offshore immediately after nesting. The gradual littoral slope and lack of nearshore structure in this part of the Gulf of Mexico could be contributing factors to the patterns of dispersal observed, as benthic structures provide resting and foraging habitat for loggerheads.     

Biodiversity below ground: probing the subterranean ant fauna of Amazonia

Ants are abundant, diverse, and ecologically dominant in tropical forests. Subterranean ants in particular are thought to have a significant environmental impact, although difficulties associated with collecting ants underground and examining their ecology and behavior have limited research. In this paper, we present the results of a study of subterranean ant diversity in Amazonian Ecuador that employs a novel probe to facilitate the discovery of species inhabiting the soil horizon. Forty-seven species of ants in 19 genera, including new and apparently rare species, were collected in probes. Approximately 19% of the species collected at different depths in the soil were unique to probe samples. Analysis of similarity (ANOSIM) results showed that the species composition of ants collected with the probe was significantly different from samples collected using other techniques. Additionally, ANOSIM computations indicated the species assemblage of ants collected 12.5 cm below the surface was significantly different from those found at 25, 37.5, and 50 cm. Ant diversity and species accumulation rates decreased with increasing depth. There were no species unique to the lowest depths, suggesting that subterranean ants may not be distributed deep in the soil in Amazonia due to the high water table. The technique we describe could be used to gain new insights into the distribution and biology of subterranean ant species and other members of the species-rich soil invertebrate macrofauna.