Phosphorus leaching in sandy outwash soils following potato-processing wastewater application

Land application of wastewater presents potential for ground water pollution if not properly managed. In situ breakthrough tests were conducted using potato (Solanum tuberosum L.)-processing wastewater and a Br tracer to characterize P leaching in seasonally frozen sandy outwash soils. In the first test, P and Br breakthrough were measured in a 7-m deep well following wastewater [2.94 mg L(-1) total P (TP); 280 mg L(-1) Br] application at the site that had 13.1 mg water-extractable P (WEP) kg(-1)and 94.4 mg Bray-1 P kg(-1). Bromide was detected in the well after approximately 0.4 pore volumes, but there was no P break-through after 7 pore volumes. In the second breakthrough test, wastewater containing 3.6 mg L(-1) TP and 259 mg L(-1) Br was applied on 1.5-m deep lysimeters at low (0.8 mg WEP kg(-1); 12.1 mg Bray-1 P kg(-1)) and high soil test P sites (104 mg WEP kg(-1); 585 mg Bray-1 P kg(-1)). Leachate TP concentration during the test remained constant (0.04 mg L(-1)) at the low P sites but increased from approximately 3.5 to 5.6 mg L(-1) at the high P sites. These results indicate no P leaching in low P soils, but leaching in high P soils, thus suggesting that most of the P leached at the high P sites was mainly due to desorption and dissolution of weakly adsorbed P from prior P applications. This was consistent with P transport simulations using the convective-dispersive equation. We conclude that P concentration in land-applied wastewater should be regulated based on soil test-P level plus wastewater P loading.     

Quantitative evaluation of the chilled-ammonia process for CO2 capture using thermodynamic analysis and process simulation

There is strong world-wide interest in developing new and improved processes for post-combustion capture of CO₂, often using chemical absorption. Developers of new processes make positive claims for their proposals in terms of low energy consumption, but these are usually difficult to validate. This paper demonstrates that rigorous application of thermodynamic analysis and process simulation provides a powerful way to quantitatively estimate the energy requirements of CO₂-capture processes by applying the methodology to the analysis and evaluation of the chilled-ammonia process.     

Tillage and manure application effects on mineral nitrogen leaching from seasonally frozen soils

Land application of manure is a common practice in the Upper Midwest of the United States. Recently, there have been concerns regarding the effect of this practice on water quality, especially when manure is applied during winter over frozen soils. A study undertaken on a Rozetta silt loam (fine-silty, mixed, superactive, mesic Typic Hapludalfs) at Lancaster, WI, evaluated the effects of tillage and timing of manure application on surface and subsurface water quality. The daily scrape and haul liquid dairy manure was applied either in the fall (before snow) or in winter (over snow with frozen soil underneath) to be compared with no manure under two tillage systems (no-till and chisel-plowing). In this paper, we report results on the effects of the above treatments on mineral N leaching. Percolation and mineral N leaching during the nongrowing season were, respectively, 72 and 78% of the annual losses, mainly because of the absence of plant water and N uptake. Percolation was generally higher from no-till compared with chisel-plow but there was no significant effect of tillage on mineral N concentration of the leachate or mineral N losses via leaching. Mineral N leaching was statistically higher from the manure-applied vs. no-manure treatment, but there was no difference between winter-applied manure and no-manure treatments. There were significant tillage by manure interactions with fall manure application followed by chisel-plowing resulting in highest N leaching losses. Averaged over the two years, N leaching rates were 52, 38, and 28 kg N ha(-1) yr(-1) from fall-applied, winter-applied, and no-manure treatments, respectively. These results show that there is substantial N leaching from these soils even when no fertilizer or manure is applied. Furthermore, fall-applied manure followed by fall tillage significantly increases N leaching due to enhanced mineralization of both soil and manure organic N.     

Effect of spatial variation on salinity tolerance of macroinvertebrates in Eastern Australia and implications for ecosystem protection trigger values

Salinisation of freshwater has been identified as a serious environmental issue in Australia and around the world. Protective concentrations (trigger values) for salinity can be used to manage salinity impacts, though require locally relevant salinity tolerance information. 72-h acute salinity tolerance values were determined for 102 macroinvertebrates collected from 11 locations in four biologically distinct freshwater bio-regions in Northeast Australia and compared with sensitivities observed in Southeast Australia. The salinity tolerance of individual taxa was consistent across Northeast Australia and between Northeast and Southeast Australia. However, two distinct communities were identified in Northeast Australia using distributions of the acute tolerance values and a calculated index of salinity sensitivity. Salinity trigger values should therefore be representative of local or regionally relevant communities and may be adequately calculated using sensitivity values from throughout Eastern Australia. The results presented provide a basis for assessing salinity risk and determining trigger values for salinity in freshwater ecosystems at local and regional scales in Eastern Australia.     

Antibiotic losses in leaching and surface runoff from manure-amended agricultural land

A 3-yr field study quantified leaching and runoff losses of antibiotics from land application of liquid hog (chlortetracycline and tylosin) and solid beef (chlortetracycline, monensin, and tylosin) manures under chisel plowing and no-tillage systems. The study was conducted in southwestern Wisconsin, a karst area with steep, shallow, macroporous soils. Relative mass losses of chlortetracycline, monensin, and tylosin were <5% of the total amount applied with manure. Chlortetracycline was only detected in runoff, whereas monensin and tylosin were detected in leachate and runoff. Highest concentrations of monensin and tylosin in the leachate were 40.9 and 1.2 microg L(-1), respectively. Highest chlortetracycline, monensin, and tylosin concentrations in runoff were 0.5, 57.5, and 6.0 microg L(-1), respectively. For all three antibiotics, >90% of detections and 99% of losses occurred during the non-growing season due to fall manure application and slow degradation of antibiotics at cold temperatures. During years of high snowmelt, runoff accounted for nearly 100% of antibiotic losses, whereas during years of minimal snowmelt, runoff accounted for approximately 40% of antibiotic losses. Antibiotic losses were generally higher from the no-tillage compared with chisel plow treatment due to greater water percolation as a result of macroporosity and greater runoff due to lack of surface roughness in the no-tillage plots during the non-growing season. The results from this study suggest that small quantities of dissolved antibiotics could potentially reach surface and ground waters in the Upper Midwestern USA from manure-amended shallow macroporous soils underlain with fractured bedrock.     

Phosphorus sequestration by chemical amendments to reduce leaching from wastewater applications

Phosphorus-immobilizing amendments can be useful in minimizing P leaching from high P soils that may be irrigated with wastewater. This study tested the P-binding ability of various amendment materials in a laboratory incubation experiment and then tested the best amendment in a field setup using drainage lysimeters. The laboratory experiment involved incubating 100-g samples of soil (72 mg kg(-1) water-extractable phosphorus, WEP) with various amendments at different rates for 63 d at field moisture capacity and 25 degrees C. The amendments tested were alum [Al2SO4)3.14H2O], ferric chloride (FeCl3), calcium carbonate (CaCO3), water treatment residual (WTR), and sugarbeet lime (SBL). Ferric chloride and alum at rates of 1.5 and 3.9 g kg(-1), respectively, were the most effective amendments that decreased WEP to 20 mg kg(-1), below which leaching has previously been shown to be low. Alum (1.3 kg m(-2)), which is less sensitive to redox conditions, was subsequently tested under field conditions, where it reduced WEP concentration in the 0- to 0.15-m layer from 119 mg kg(-1) on Day 0 to 36.1 mg kg(-1) (85% decrease) on Day 41. Lysimeter breakthrough tests using tertiary-treated potato-processing wastewater (mean total phosphorus [TP] = 3.4 mg L(-1)) showed that alum application reduced leachate TP and soluble reactive phosphorus (SRP) concentrations by 27 and 25%, respectively. These results indicate that alum application may be an effective strategy to immobilize P in high P coarse-textured soils. The relatively smaller decreases in TP and SRP in the leachate compared to WEP suggest some of the P may be coming from depths below 0.2 m. Thus, to achieve higher P sequestration, deeper incorporation of the alum may be necessary.     

Nitrogen and phosphorus leaching from growing season versus year-round application of wastewater on seasonally frozen lands

Land application of wastewater has become an important disposal option for food-processing plants operating year-round. However, there are concerns about nutrient leaching from winter wastewater application on frozen soils. In this study, P and N leaching were compared between nongrowing season application of tertiary-treated wastewater plus growing season application of partially treated wastewater (NGS) vs. growing season application of partially treated wastewater (GS) containing high levels of soil P. As required by the Minnesota Pollution Control Agency (MPCA), the wastewater applied to the NGS fields during October through March was treated such that it contained < or =6 mg L(-1) total phosphorus (TP), < or =10 mg L(-1) NO3-N, and < or =20 mg L(-1) total Kjeldahl nitrogen (TKN). The only regulation for wastewater application during the growing season (April through September) was that cumulatively it did not exceed the agronomic N requirements of the crop in any sprayfield. Application of tertiary-treated wastewater during the nongrowing season plus partially treated wastewater during the growing season did not significantly increase NO3-N leaching compared with growing season application of nonregulated wastewater. However, median TP concentration in leachate was significantly higher from the NGS (3.56 mg L(-1)) than from the GS sprayfields (0.52 mg L(-1)) or nonirrigated sites (0.52 mg L(-1)). Median TP leaching loss was also significantly higher from the NGS sprayfields (57 kg ha(-1)) than from the GS (7.4 kg ha(-1)) or control sites (6.9 kg ha(-1)). This was mainly due to higher hydraulic loading from winter wastewater application and limited or no crop P uptake during winter. Results from this study indicate that winter application of even low P potato-processing wastewater to high P soils can accelerate P leaching. We conclude that the regulation of winter wastewater application on frozen soils should be based on wastewater P concentration and permissible loading. We also recommend that winter irrigation should take soil P saturation into consideration.     

Primary biodegradation of linear alkyltoluene and alkylbenzene sulfonates

Studies on the primary biodegradation of linear dodecylbenzene sulfonate, linear dodecyltoluene sulfonate, linear C(10-14) benzene sulfonate, linear C(10-14) toluene sulfonate, commercial samples of linear C(10-14) benzene sulfonate and branched dodecylbenzene sulfonate (DDBS) were carried out using a microbial culture developed from garden soil. Results show that linear alkyl toluene (LAT) is as degradable as linear alkylbenzene (LAB) in 7 days. However, a slower rate of degradation was noted with LAT. Various distributions of the positional isomers of the phenyl ring in the alkane chain of C(10-14) LAB showed no change in the pattern of primary biodegradation.