Partitioning of mercury onto suspended sediments in estuaries

Radiochemical partitioning experiments using 203Hg have been undertaken with mixtures of river, seawater and sediment samples taken from three geochemically contrasting UK estuaries: the Plym, Beaulieu and Mersey. Species of dissolved Hg were determined using reversed-phase C18 chelating columns and particulate species were determined by sequential leaching with 1 M NH4OAc and 1 M HCl. Mercury had a high particle reactivity with partition coefficients, KDs, ranging from 10(4) to 5 x 10(5) ml g(-1), depending on salinity, the chemical composition of the end-member waters, and on the physico-chemical characteristics of the sediment. Dissolved organic matter present in the waters (humic substances and/or anthropogenic compounds) was found to be the main factor governing the forms of dissolved Hg and their reactivity. From the spiked 203Hg, up to 95% of the dissolved metal was retained on the C18 columns for the Mersey waters, whereas this fraction was < 60% in the Plym and Beaulieu waters. Quasi-irreversible adsorption of Hg onto particles from each estuary was observed over a time-scale of a few hours and < 20% of total particulate Hg was released by the sequential leach. In this paper, physico-chemical processes are proposed to explain the estuarine behaviour of Hg and the results are discussed in terms of Hg availability in estuarine systems.     

Prenatal diagnosis of infantile GM 2 gangliosidosis type II (sandhoff disease) by detection of N-acetylglucosaminyl-oligosaccharides in amniotic fluid with high-performance liquid chromatography

Prenatal diagnosis of Sandhoff disease (infantile onset) at 16 weeks gestation has been made by detection and analysis of N-acetylglucosaminyl-oligosaccharides in amniotic fluid using high performance liquid chromatography. The elution profile for the branched chain oli-gosaccharides was identical with that obtained with neonatal and infantile Sandhoff urine. The concentration of the oligosaccharides in the fluid was 1/100th that of urine but when calculated relative to creatinine the levels were similar. No oligosaccharides were detected in normal control amniotic fluids (10 patients) at a similar gestational age. Based on the levels of the amniotic fluid oligosaccharides and the sensitivity limits of the assay, prenatal diagnosis of patients with the juvenile onset form of the disease may also be possible with this technique.     

Comparing Environmental Conditions Using Indicators of Pollution Hazard

/ Land use/land cover classifications for 1973 and 1991, derived from the interpretation of satellite imagery, are quantified on the basis of biophysical land units in a study area in southeastern Australia. Nutrient export potentials are estimated for each land unit based on their composition of land use/land cover classes. Spatial and temporal comparisons are made of the land units based on the calculated pollution hazard indicators to provide an insight into changes in the state of the environment and the regional significance of land use changes. For example, one ecosystem, unique to the study, showed a large increase in pollution hazard over the study period as a manifestation of an 11-fold rise in cleared area and an expansion of cropping activities. The benefits to environmental management in general are discussed.KEY WORDS: Land cover change; Nutrient export; Environmental condition; Pollution hazard; Agricultural pollution; Nonpoint source pollution; Diffuse pollution; Environmental degradation     

Pressures,trends, and impacts in coastal zones: Interactions between socioeconomic and natural systems

This paper assesses the status of coastal zones in the context of expected climate change and its related impacts, as well as current and future socioeconomic pressures and impacts. It is argued that external stresses and shocks relating to sea-level rise and other changes will tend to exacerbate existing environmental pressures and damage in coastal zones. Coastal zones are under increasing stress because of an interrelated set of planning failures including information, economic market, and policy intervention failures. Moves towards integrated coastal zone management are urgently required to guide the coevolution of natural and human systems. Overtly technocentric claims that assessments of vulnerability undertaken to date are overestimates of likely future damages from global warming are premature. While it is the case that forecasts of sea-level rise have been scaled down, much uncertainty remains over, for example, combined storm, sea surge, and other events. In any case, within the socioeconomic analyses of the problem, resource valuations have been at best only partial and have failed to incorporate sensitivity analysis in terms of the discount rates utilized. This would indicate an underestimation of potential damage costs. Overall, a precautionary approach is justified based on the need to act ahead of adequate information acquisition, economically efficient resource pricing and proactive coastal planning.     

Modeling wetland loss in coastal Louisiana: Geology,geography, and human modifications

Habitat change in coastal Louisiana from 1955/6 to 1978 was analyzed to determine the influence of geological and man-made changes on landscape patterns within 7.5 min quadrangle maps. Three quantitative analyses were used: principal components anlaysis, multiple regression analysis, and cluster analysis.Regional differences in land loss rates reflect variations in geology and the deltaic growth/decay cycles, man-induced chages in hydrology (principally canal dredging and spoil banking), and land-use changes (principally urbanization and agricultural expansion). The coastal zone is not homogeneous with respect to these variables and the interaction between causal factors leading to wetland loss is therefore locally variable and complex.The relationship between wetland loss, hydrologic changes, and geology can be described with statistically meaningful results, even though these data are insufficient to precisely quantify the relationship. However, these data support the hypothesis that the indirect impacts of man-induced changes (hydrologic and land use) may be as influential as the direct impacts resulting in converting wetlands to open water (canals) or modified (impounded) habitat.Three regions within the Louisiana coastal zone can be defined, based on the potential causal factors used in the analyses. The moderate (mean = 22%) wetland loss rates in region 1 are a result of relatively high canal density and developed area in marshes which overlie sediments of moderate age and depth; local geology acts, in this case, to lessen indirect impacts. On the other hand, wetland loss rates in region 2 are high (mean = 36%), despite fewer man-induced impacts; the potential for increased wetland loss due to both direct and indirect effects of man's activity in these areas is high. Conversely, wetland loss (mean = 20%) in region 3 is apparently least influenced by man's activity in the coastal zone because of sedimentary geology (old, thin sediments), even though these areas have already experienced significant direct habitat alteration and wetland loss.     

Packaging waste and the polluter pays principle: a taxation solution

Packaging waste has become a focus for attention by policy‐makers in a number of countries. This article offers a simple policy measure — a packaging tax or levy — which serves the required aims of policy, namely: reducing waste at source; increasing the rate of recycling; and consistency with the polluter pays principle. The tax is illustrated in the context of beverage containers in the UK and Japan. The merits of the proposal are its simplicity and flexibility. The article suggests that the relevant environmental damages are captured by waste disposal costs and litter. Other life cycle impacts, such as emissions from energy use, could be included but only if there are not more efficient ways of regulating them.