NOx Reduction in a Gas Fired Utility Boiler by Combustion Modifications

Data on the effect of several combustion modifications on the formation of nitrogen oxides and on boiler efficiency were acquired and analyzed for a 110 MW gas fired utility boiler. The results from the study showed that decreasing the oxygen in the flue gas from 2.2% to 0.6% reduced the NO_x formation by 33% and also gave better boiler efficiencies. Flue gas recirculation through the bottom of the firebox was found to be ineffective. Staged combustion was found to reduce the NO_x emissions by as much as 55 % while decreasing the efficiency by about 5%. Adjustment of the burner air registers reduced the NO_x formation by about 20 ppm. The lowest NO_x emissions of 42 ppm (at about 3% O₂) in the stack was obtained for air only to one top burner and 0.5% oxygen in the flue gas.     

Calculating pesticide sorption coefficients (Kd) using selected soil properties

Pesticide soil/solution distribution coefficients ( Kd values), commonly referred to as pesticide soil sorption values, are utilized in computer and decision aid models to predict soil mobility of the compounds. The values are specific for a given chemical in a given soil sample, normally taken from surface soil, a selected soil horizon, or at a specific soil depth, and are normally related to selected soil properties. Pesticide databases provide Kd values for each chemical, but the values vary widely depending on the soil sample on which the chemicals were tested. We have correlated Kd values reported in the literature with the reported soil properties for an assortment of pesticides in an attempt to improve the accuracy of a Kd value for a specific chemical in a soil with known soil properties. Mathematical equations were developed from regression equations for the related properties. Soil properties that were correlated included organic matter content, clay mineral content, and/or soil pH, depending on the chemical properties of the pesticide. Pesticide families for which Kd equations were developed for 57 pesticides include the following: Carboxy acid, amino sulfonyl acid, hydroxy acid, weakly basic compounds and nonionizable amide/anilide, carbamate, dinitroaniline, organochlorine, organophosphate, and phenylurea compounds. Mean Kd values for 32 additional pesticides, many of which had Kd values that were correlated with specific soil properties but for which no significant Kd equations could be developed are also included.     

Uptake of dissolved inorganic nitrogen by the symbiotic clam Tridacna gigas and the coral Acropora sp.

Dissolved inorganic nitrogen flux was studied in the giant clam Tridacna gigas and the corals Acropora sp. and Tubastrea micrantha from the tropical reefs of Belau, Micronesia in 1983. T. micrantha, a nonsymbiotic coral, excreted ammonium. However, Tridacna gigas and Acropora sp., which contain symbiotic dinoflagellates (zooxanthellae) were able to take up both ammonium and nitrate. The requirement for a previous light exposure to sustain uptake by T. gigas is reported. The uptake kinetics of these symbioses are described and include the capacity of the zooxanthellae for surge uptake when given nutrient spikes.Contribution No. 417 of the Allan Hancock Foundation     

Improved Bankfull Channel Geometry Prediction Using Two‐Year Return‐Period Discharge1

He, Laien and Gregory V. Wilkerson, 2011. Improved Bankfull Channel Geometry Prediction Using Two‐Year Return‐Period Discharge. Journal of the American Water Resources Association (JAWRA) 47(6):1298–1316. DOI: 10.1111/j.1752‐1688.2011.00567.x Abstract:  Bankfull discharge (Q_bf) and bankfull channel geometry (i.e., width, W_bf; mean depth, D_bf; and cross‐section area, A_bf) are important design parameters in stream restoration, habitat creation, mined land reclamation, and related projects. The selection of values for these parameters is facilitated by regional curves (regression models in which Q_bf, W_bf, D_bf, and A_bf are predicted as a function of drainage area, A_da). This paper explores the potential for the two‐year return‐period discharge (Q₂) to improve predictions of W_bf, D_bf, and A_bf. Improved predictions are expected because Q₂ estimates integrate the effects of basin drainage area, climate, and geology. For conducting this study, 29 datasets (each representing one hydrologic region) spanning 14 states in the United States were analyzed. We assessed the utility of using Q₂ by comparing statistical measures of regression model performance (e.g., coefficient of determination and Akaike’s information criterion). Compared to using A_da, Q₂ is shown to be a “clearly superior” predictor of W_bf, D_bf, and A_bf, respectively, for 21, 13, and 25% of the datasets. By contrast, A_da yielded a clearly superior model for predicting W_bf, D_bf, and A_bf, respectively, for 0, 0, and 14% of the datasets. Our conclusion is that it alongside with developing conventional regional curves using A_da it is prudent to develop regional curves that use Q₂ as an independent variable because in some cases the resulting model will be superior.     

HYDRAULIC GEOMETRY RELATIONSHIPS FOR URBAN STREAMS THROUGHOUT THE PIEDMONT OF NORTH CAROLINA1

ABSTRACT: Hydraulic geometry relationships, or regional curves, relate bankfull stream channel dimensions to watershed drainage area. Hydraulic geometry relationships for streams throughout North Carolina vary with hydrology, soils, and extent of development within a watershed. An urban curve that is the focus of this study shows the bankfull features of streams in urban and suburban watersheds throughout the North Carolina Piedmont. Seventeen streams were surveyed in watersheds that had greater than 10 percent impervious cover. The watersheds had been developed long enough for the streams to redevelop bankfull features, and they had no major impoundments. The drainage areas for the streams ranged from 0.4 to 110.3 square kilometers. Cross‐sectional and longitudinal surveys were conducted to determine the channel dimension, pattern, and profile of each stream and power functions were fitted to the data. Comparisons were made with regional curves developed previously for the rural Piedmont, and enlargement ratios were produced. These enlargement ratios indicated a substantial increase in the hydraulic geometry for the urban streams in comparison to the rural streams. A comparison of flood frequency indicates a slight decrease in the bankfull discharge return interval for the gaged urban streams as compared to the gaged rural streams. The study data were collected by North Carolina State University (NCSU), the University of North Carolina at Charlotte (UNC), and Charlotte Storm Water Services. Urban regional curves are useful tools for applying natural channel design in developed watersheds. They do not, however, replace the need for field calibration and verification of bankfull stream channel dimensions.     

Daily photosynthesis,respiration, and carbon budgets in a tropical marine jellyfish (Mastigias sp.)

From measured diel photosynthesis and respiration rates, using oxygen electrodes, estimates of carbon flux between symbiotic algae (zooxanthellae) and host animal are presented for the marine scyphomedusan Mastigias sp. from a marine lake in Palau, Western Caroline Islands, during February and March 1982. The carbon budgets calculated for these lake medusae indicate that carbon fixed photosynthetically by zooxanthellae and made available to the host may satisfy up to 100% of the host's daily metabolic carbon demand (CZAR). The stable carbon isotope (¹³C) signature of the mesogleal carbon of lake Mastigias sp. was close to that of the zooxanthellae, supporting the interpretation that while these medusae may feed holozoically, some of their carbon comes from their symbionts. The diel photosynthesis, respiration, and preliminary estimates of carbon budgets of three individuals of another ecotype of Mastigias sp. collected from nearby oceanic lagoons are also given. Photosynthesis of lagoon medusae was generally greater than that for lake medusae of similar size, and lagoon medusae were phototrophic with respect to carbon, with commensurately greater CZAR values. Carbon translocated from the symbiotic algae also may contribute to the growth requirements of both lake and lagoon medusae. From carbon flux data, the lake jellyfish were estimated to contribute about 16% to the total primary productivity of their marine lake habitat.     

Improved Bankfull Discharge Prediction Using 2‐Year Recurrence‐Period Discharge1

Abstract:  Knowledge of bankfull discharge (Q_bf) is essential for planners, engineers, geomorphologists, environmentalists, agricultural interests, developments situated on flood prone lands, surface mining and reclamation activities, and others interested in floods and flooding. In conjunction with estimating Q_bf, regionalized bankfull hydraulic geometry relationships, which relate Q_bf and associated channel dimensions (i.e., width, depth, and cross‐section area) to drainage basin area (A_da), are often used. This study seeks to improve upon the common practice of predicting Q_bf using A_da exclusively. Specifically, we hypothesize that predictions of Q_bf can be improved by including estimates of the 2‐year recurrence‐period discharge (Q₂) in regression models for predicting Q_bf. For testing this hypothesis, we used Q_bf estimates from 30 reports containing data for streams that span 34 hydrologic regions in 16 states. Corresponding values of Q₂ and A_da were compiled from flood‐frequency reports and other sources. By comparing statistical measures (i.e., root mean squared error, coefficient of determination, and Akaike’s information criterion), we determined that predicting Q_bf from Q₂ rather than A_da yields consistently better estimates of Q_bf. Other principal findings are (1) data are needed for at least 12 sites in a region for reliable hydraulic geometry model selection and (2) an approximate range of values for Q_bf/Q₂ is 0.10‐3.0.     

Bankfull Regional Curves for North and Northwest Florida Streams1

Abstract: Regional curves, which relate bankfull channel dimensions and discharge to watershed drainage area, are developed to aid in identifying the bankfull stage in ungaged watersheds, and estimating the bankfull discharge and dimensions for river studies and natural channel design applications. This study assessed 26 stable stream reaches in two hydro‐physiographic regions of the Florida Coastal Plain: the Northwest Florida Coastal Plain (NWFCP) and the North Florida Coastal Plain (NFCP). Data from stream reaches in Georgia and Alabama were also used to develop the Florida regional curves, since they are located in the same hydro‐physiographic region. Reaches were selected based on the presence of U.S. Geological Survey gage stations and indicators of limited watershed development (e.g., <10% impervious surface). Analyses were conducted to determine bankfull channel dimensions, bankfull discharge, average channel slope, and Rosgen stream classification. Based on these data, significant relationships were found between bankfull cross‐sectional area, width, mean depth, and discharge as a function of drainage area for both regions. Data from this study suggested that bankfull discharges and channel dimensions were larger from NWFCP streams than from Coastal Plain streams in North Carolina and Maryland. Bankfull discharges were similar between NFCP and Georgia coastal plain streams; therefore, the data were combined into one regional curve. In addition, the data were stratified by Rosgen stream type. This stratification strengthened the relationships of bankfull width and mean depth as a function of drainage area.