Simultaneous removal of cyanobacterial blooms and production of clean water by coupling flocculation with a rotary drum filter

Environmental Science and Pollution Research - A mechanical harvesting technology based on coupling flocculation with a rotary drum filter (RDF, 35-μm) was applied to remove cyanobacterial...     

煤与瓦斯共采在错层位巷道布置中的机理研究及应用构想

为了完善现有煤与瓦斯共采技术，创新煤与瓦斯共采方法，对错层位巷道布置下的煤与瓦斯共采系统展开研究，利用相似模拟试验，分析错层位巷道布置覆岩运动情况，预测其开采围岩裂隙发育和瓦斯运移形式，提出了创新煤与瓦斯共采技术构想。研究结果表明:采空区覆岩三带高度随接续工作面的增加而增大，相邻采空区垮落矸石压实区呈现“O-L-O”形变化，多个相邻采空区覆岩出现大“O”形圈裂隙带；相邻采空区内瓦斯可实现相互运移，大“O”形圈裂隙带内赋存大量瓦斯气体；研究提出了地面钻井抽采瓦斯、走向高位瓦斯抽采巷和外错尾巷穿层钻孔3种煤与瓦斯共采技术，比传统巷道布置情况下的煤与瓦斯共采技术在安全、经济等方面更具优势。     

分层开采工艺对地表沉降的影响研究

分层开采是厚煤开采的经典工艺,这种工艺对地表沉降的影响比较复杂。通过测试原岩物理力学参数,利用有限元软件flac3D对分层和一次采全高时地表沉降进行了数值模拟。结果表明,如果采高较小,砌体梁距煤层较近,且采完上分层后长时间停采,给顶板再生留足时间,分层开采较一次采全高对地表沉降影响要小。     

三峡工程与长江中游沿江产业带建设

讨论了长江中游沿江产业带发展条件、限制因素和未来发展，指出三峡工程的建设将对长江中游产业的布局和经济发展带来深刻的变化；防洪作用促进中游两岸大型工业项目的兴建，调整现有沿江城镇的布局，使之结构趋于合理化；电力供应经解能源的紧张状态，改善航运条件，发挥长江黄金水道的综合效益。当然，由于坝下河道冲刷，对现有的码头带来一定的影响，由于冬季水位抬升引起两岸低湖田地下水位上升，加剧两岸土壤潜育化和沼泽化。     

水雾荷电净化空气飘尘与细菌的研究

研究一种高压静电水雾场产生的荷电净化空气中飘尘与细菌的方法。实验结果表明:在静电电压15kV、通风量540m~3/h的工况下,实验装置的一次性除尘效率高于80%、除菌效率达到88%以上;实验装置可以连续运行,能耗低、出风无二次污染。     

链霉菌(Streptomyces sp.)对吡啶的降解特性

从焦化废水的活性污泥中分离出对溶液中吡啶具有降解效果的链霉菌（Streptomyces sp．），考察了吡啶初始质量浓度、初始pH、降解温度、振荡速度等对吡啶降解效果的影响，初步探讨了该菌降解吡啶的动力学与机理。实验结果表明，该菌对吡啶有很强的耐受力，能以吡啶为惟一碳源和氮源生长。链霉菌在初始pH=8、降解温度30℃、振荡速度100r／min的条件下培养7d后，吡啶的质量浓度从250mg/L降至6．6mg/L，吡啶降解率达97．4％。该菌对吡啶的降解反应符合一级动力学方程，初始质量浓度为100mg／L时的吡啶降解速率常数为0．4011d^-1。紫外一可见光谱分析表明，吡啶经该菌降解后的特征环被破坏。     

Algal toxicity induced by effluents from textile-dyeing wastewater treatment plants

This research aimed to evaluate the alga Scenedesmus obliquus toxicity induced by textiledyeing effluents(TDE).The toxicity indicator of TDE in alga at the physiological(algal growyth),biochemical(chlorophyll-a(Chl-a) synthesis and superoxide dismutase(SOD) activity) and structural(cell membrane integrity) level were investigated.Then we further study the relationship among toxicity indicators at physiological and biochemical level,and supplemented by research on algal biomacromolecules.According to the analysis of various endpoints of the alga,the general sensitivity sequence of toxicity endpoints of Scenedesmus obliquus was:SOD activity Chl-a synthesis algal growth.The stimulation rate of SOD activity increased from day 3(57.25%～83.02%) to day 6(57.25%～103.81%),and then decreased on day 15(-4.23%～-32.96%),which indicated that the antioxidant balance system of the algal cells was destroyed.The rate of Chl-a synthesis inhibition increased gradually,reaching19.70%～79.39% on day 15,while the rate of growth inhibition increased from day 3(-12.90%～10.16%) to day 15(-21.27%～72.46%).Moreover,the algal growth inhibition rate was positively correlated with the inhibition rate of SOD activity or Chl-a synthesis,with the correlation coefficients were 0.6713 and 0.5217,respectively.Algal cells would be stimulating to produce excessive reactive oxygen species,which would cause peroxidation in the cells,thereby destroying chloroplasts,inhibiting chlorophyll synthesis and reducing photosynthesis.With increasing exposure time,irreversible damage to algae can lead to death.This study is expected to enhance our understanding of the ecological risks through algal tests caused by TDE.     

Advanced molecular-fingerprinting analysis of dissolved organic sulfur by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry using optimal spray solvent

Molecular level characterization of dissolved organic sulfur (DOS) by electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS) is necessary for further understanding of the role of DOS in the environment. Here, ESI spray solvent, a key parameter for ion production during ESI process, was investigated for its effect on the molecular characterization of DOS by ESI-FTICR MS. 100% MeOH as spray solvent was found for the first time to remarkably enhance the ionization efficiency of the majority of CHOS-molecules in NOM, which facilitated a total of 1473 CHOS-molecular formulas with one sulfur atom to be detected. The number of CHOS-molecular formulas obtained using 100%MeOH as spray solvent increased notably over 740 in comparison with those using 50% MeOH aqueous solution (731) or 50% ACN aqueous solution (653). Moreover, due to the enhancement of ionization efficiency of DOS during ESI processes, the tandem mass spectra of the NOM CHOS-molecules could be easily obtained using 100% MeOH as spray solvent, which were hardly obtained using 50% MeOH aqueous solution as spray solvent. The results of the tandem mass spectra suggested the first discovery of organosulfates or sulfonic acids in Suwannee River NOM sample. A simple method based on 100% MeOH as ESI spray solvent for advanced molecular characterization of DOS by ESI-FTICR MS was proposed and applied, and the results revealed more molecular information of DOS in sea DOM samples.     

保定市大气污染特征和潜在输送源分析

保定市是京津冀地区重要城市之一.为了解保定市大气污染物质量浓度特征和潜在输送源,对保定市国控点2017年1月1日-12月31日PM₁₀、PM_2.5、SO₂、NO₂、O₃、CO等常规大气污染物数据进行分析,并利用TrajStat后向轨迹模型进行区域传输研究.结果表明:①ρ（PM₁₀）、ρ（PM_2.5）、ρ（SO₂）、ρ（NO₂）分别为（138±96）（84±66）（29±23）和（50±24）μg/m3,与2016年相比分别下降5.9%、9.1%、25.5%和13.1%;ρ（CO）较2016年下降了14.0%;ρ（O₃）较2016年增长了25.2%.ρ（PM₁₀）、ρ（PM_2.5）、ρ（NO₂）和ρ（O₃）分别超过GB 3095-2012《环境空气质量标准》二级标准限值的0.97、1.40、0.25和0.34倍,ρ（SO₂）和ρ（CO）未超标.②除ρ（O₃）外,其他污染物质量浓度均呈冬季最高、夏季最低的季节性特征,其中,冬季PM_2.5污染最为严重,春季PM_2.5~10（粗颗粒物）污染严重.③空气质量模型源解析结果显示,保定市ρ（PM_2.5）约60.0%~70.0%来自本地污染源排放.后向轨迹结果表明,在外来区域传输影响中,保定市主要受到西北方向气团（占比为21.7%~60.0%）远距离传输和正南方向气团（占比为34.8%~50.5%）近距离传输的影响.④PSCF（潜在源贡献因子分析法）和CWT（浓度权重轨迹分析法）分析表明,除保定市及周边区县本地污染贡献外,位于太行山东麓沿线西南传输通道的邯郸市、邢台市、石家庄市是影响保定市PM_2.5的主要潜在源区.研究显示,PM_2.5为保定市大气中的主要污染物,并呈冬季高、夏季低的变化特征,其主要来自西北远距离输送和南部近距离传输.      

2-丁烯醛生产废水的臭氧脱毒预处理

CMW（crotonaldehyde manufacturing wastewater,2-丁烯醛生产废水）污染物浓度高、毒性强、直接采用生物法处理难度大.为了降低CMW的生物处理毒性,采用臭氧氧化法对CMW进行脱毒预处理,并通过考察不同臭氧氧化条件对废水COD_Cr、TOC（总有机碳）、UV_{254 nm}去除率及SMA（specific methanogenic activity,比产甲烷活性）抑制率的影响,获得了优化的臭氧氧化条件,进一步分析了废水脱毒机理.结果表明:①优化的臭氧氧化条件为接触反应时间180 min、初始pH 3.0、反应温度35℃、气相臭氧浓度30.3 mg/L,进气流量500 mL/min;并且在该条件下,CMW中COD_Cr、TOC和UV_{254 nm}的去除率分别为19.9%、9.9%和70.6%,主要特征有机污染物[包括2-丁烯醛、（E,E）-2,4-己二烯醛、3-（2-甲基-2-丙烯）-5-戊内酯、1,5-二甲基-1-烯-4-羰基-环氧己烷、山梨酸乙酯等]的去除率在74.4%以上.②厌氧产甲烷毒性试验结果显示,CMW的SMA抑制率由臭氧氧化前的82.0%降至臭氧氧化后的47.2%.③反应动力学研究显示,CMW中COD_Cr、TOC及UV_{254 nm}的去除过程均符合一级反应动力学方程,R2分别为0.82、0.97、0.94.研究显示,臭氧氧化预处理可以较好地去除CMW中的特征有机污染物,降低废水的厌氧生物处理毒性,是一种可行的脱毒预处理方法.