排序方式: 共有9条查询结果,搜索用时 804 毫秒
1
1.
L.L. Lamparski T.J. Nestrick N.N. Frawley R.A. Hummel C.W. Kocher N.H. Mahle J.W. McCoy D.L. Miller T.L. Peters J.L. Pillepich W.E. Smith S.W. Tobey 《Chemosphere》1986,15(9-12):1445-1452
During 1983 and 1984, The Dow Chemical Company conducted a study to determine the extent of dioxin contamination at its Midland, Michigan plant and the surrounding area. The primary objectives of this study were to identify, rank order, and when possible quantify potential sources of dioxins to the environment and also to determine the extent of contamination in areas affected by the Dow facility. Early in the study, it was estimated that approximately 0.6g/year of 2378-TCDD was being emitted in 2.5 × 1010L of wastewater effluent. Data will describe observed sources of TCDD (both current and historical), environmental levels, existing water treatment methods, control measures taken, and future improvements on the water system to reduce TCDD in the effluent. 相似文献
2.
Collins JJ Bodner K Burns CJ Budinsky RA Lamparski LL Wilken M Martin GD Carson ML 《Chemosphere》2007,66(6):1079-1085
Several studies have found that current levels of 2,3,7,8 tetrachlorodibenzo-p-dioxin in serum lipids are related to age with older persons generally having higher levels. To account for this age pattern, reference ranges based on national samples have been established in order to allow determination of background levels for regional studies. In several studies, body mass index (BMI), has also been associated with current 2,3,7,8 tetrachlorodibenzo-p-dioxin levels with increasing body mass index related to increasing levels. We measured lipid-adjusted serum levels for all 2,3,7,8-substituted dioxins and furans in 62 chemical manufacturing workers with chlorophenol exposures and 36 workers without chlorophenol exposures employed at the same location. We then assessed the impact of age and BMI on the serum levels of all these compounds in the presence of other potential confounders. We found that both factors are important independent determinants of serum levels of 2,3,7,8-substituted dioxins and furans. Specifically, age and BMI are both important factors for assessing background levels of 2,3,7,8 tetrachlorodibenzo-p-dioxin, 1,2,3,7,8 pentachlorodibenzo-p-dioxin and the calculated total toxic equivalency. BMI, but not age, is important for assessing background levels of higher chlorinated dioxins and some hexachlorofurans. We conclude that age and BMI are both important considerations when comparing a potentially exposed group to a referent group, or to national norms. Further, age and BMI may also be important in epidemiology studies where back-extrapolation from current dioxin levels is used to assess historical chlorophenol exposure. 相似文献
3.
4.
Analysis of a sample of MILORGANITE® fertilizer which had been sealed in glass for exhibition in 1933 shows a broad range of chlorodibenzo-p-dioxins remarkably similar to that of more recent material. It is speculated that the compounds were formed mainly by condensation reactions after chlorination of phenolic substances in the water supply and wastes. 相似文献
5.
6.
7.
Brominated dibenzo-p-dioxin and dibenzofuran (BDD/BDF) isomers, specifically having from one to three halogens located in the 2,3,7,8-substituent positions, that are [13C]-labeled for use as analytical internal standards in mass spectrometric methods are not yet commercially available. Based upon the current availability of [13C]-labeled dibenzo-p-dioxin and dibenzofuran (DD/DF) precursors, we have developed a simple and efficient synthetic procedure which produces brominated congeners that are predominantly substituted in the 2,3,7, and 8-positions. The gas/solid reaction of vaporized precursor and surface-supported iron (III) bromide occurs rapidly (seconds) at temperatures ≥ 240°C and can provide total product yields in the range of 30 to 50 mole % for initial precursor amounts between 1 μg and 10 mg. In this paper we shall describe the utility of this approach to produce 5 μg quantities of [13C12]-2,7-dibromodibenzo-p-dioxin (27-DBDD) and [13C12]-2,8-dibromodibenzo-p-dioxin (28-DBDD). 相似文献
8.
T.J. Nestrick L.L. Lamparski N.N. Frawley R.A. Hummel C.W. Kocher N.H. Mahle J.W. McCoy D.L. Miller T.L. Peters J.L. Pillepich W.E. Smith S.W. Tobey 《Chemosphere》1986,15(9-12):1453-1460
On November 5, 1984, The Dow Chemical Company issued a report entitled: “Point Sources and Environmental Levels of 2378-TCDD on the Midland Plant Site of The Dow Chemical Company and in the City of Midland, Michigan.” This report is based upon the efforts of a 22-person task force who dedicated approx. 21 months of effort to the generation and analysis of over 6000 analytical data points regarding specific CDD/CDF concentrations in the four basic environmental elements of air, earth, fire (incineration), and water. A summarization of this study will be presented which includes methodology, analytical QA-QC criteria, and representative soil analyses, as they pertain to the survey conclusions. 相似文献
9.
To supplement an epidemiological investigation into respiratory cancer, a synthetic fabric called tak was used to study the deposition of atmospheric metal pollution within the town of Armadale, central Scotland. Pollution maps showed high concentrations of several metals in areas close to the town's steel foundry and in a second area in the north of the town. Through further statistical analyses, those metals were identified which had probably been emitted by the foundry, and temporal variations in metal deposition patterns were examined. The advantages of this method of low technology sampling, which include the low cost and a high density of sampling sites, are described. 相似文献
1