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Zakaria Man Nawshad Muhammad Ariyanti Sarwono Mohamad Azmi Bustam M. Vignesh Kumar Sikander Rafiq 《Journal of Polymers and the Environment》2011,19(3):726-731
In this paper cellulose nanocrystals were prepared by treating microcrystalline cellulose with 1-butyl-3-methylimidazolium
hydrogen sulphate ionic liquid. Cellulose nanocrystals, after separation from ionic liquid, were characterized by X-ray diffraction
(XRD), Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM) Transmission Electron Microscope
(TEM) and Thermogravimetric analysis. XRD results showed no changes in type of cellulose after the treatment with ionic liquid,
however, high crystallinity index was observed in the ionic liquid treated sample. Cellulose nanocrystals, having length around
50–300 nm and diameter around 14–22 nm were observed in the ionic liquid treated sample under FESEM and TEM, and similar patterns
of peaks as that of microcrystalline cellulose were observed for cellulose nanocrystals in the FTIR spectra. The thermal stability
of the cellulose nanocrystals was measured low as compare to microcrystalline cellulose. 相似文献
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Ariyanti Sarwono Zakaria Man M. Azmi Bustam 《Journal of Polymers and the Environment》2012,20(2):540-549
Epoxy resin prepared by the reaction of a diglycidyl ether of bisphenol A (DGEBA) and m-xylylenediamine (m-XDA) was modified with 10% wt of epoxidized palm oil (EPO). The EPO was first pre-polymerized with m-XDA at various temperatures and reaction times. The resulting product was then mixed with the epoxy resin at 40?°C and allowed to react at 120?°C for another 3?h. The fully reacted DGEBA/m-XDA/EPO blend was characterized by using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis, tensile test, hardness indentation and dynamic mechanical analysis. The SEM study shows that different types of morphology, ranging from phase separated to miscible blends were obtained. A miscible blend was obtained when the m-XDA and EPO were reacted for more than 2?h. The results from DSC analysis show that the incorporation of EPO at 10% wt in the epoxy blend reduced the glass transition temperature (T g). The lowered T g and mechanical properties of the modified epoxy resins are caused by a reduction in crosslinking density and plasticizer effect. 相似文献
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