Gold Mining: Is It Worth Its Weight?

Gold (Au) accounts for only 0.004 g/ton of the earth's crust and is the most desired element. With an average annual world production of approximately 2,500 tons, the current methods of Au mining in developing countries cause major environmental issues. These issues vary from deforestation to cyanide and mercury (Hg) contamination. This article presents several cases of environmental catastrophes caused by Au mining in different regions of the world (Africa, the Middle East, Eastern Europe, and South America). It discusses the currently available processes for the large-scale extraction of metallic Au grains and supports the need for an alternative sustainable process.     

At the intersection of disaster risk and religion: interpretations and responses to the threat of Tsho Rolpa glacial lake

Over the last several decades, the scientific community has replaced the ‘acts of god’ explanations for disasters with a view that disasters are actually ‘acts of nature,’ and more recently, ‘acts of human behavior and decision making.’ Despite the secular orientation of contemporary disaster research, religious beliefs still govern people’s interpretations of natural events across many continents and cultures. Using a case study of a rural Sherpa community in Nepal, this paper responds to the challenge of linking religion and disaster risk in the context of a climate change-induced glacial lake outburst flood hazard. Data collection employed ethnographic techniques including participant observation and 53 interviews with community members. Results indicate that the case study community’s religious belief system influences how they interpret and respond to the glacial lake hazard, although their beliefs co-exist with more scientific interpretations of risk. Rather than being immobilised by their belief system, we found that religious aspects like rituals and prayer can enhance social cohesion and contribute to capacities for coping with fear and uncertainty in this community. We assert that religion can yield valuable resources to glacial lake risk reduction strategies, which will benefit from incorporating social-cultural factors more profoundly.     

Probabilistic Flood Inundation Forecasting Using Rating Curve Libraries

One approach for performing uncertainty assessment in flood inundation modeling is to use an ensemble of models with different conceptualizations, parameters, and initial and boundary conditions that capture the factors contributing to uncertainty. However, the high computational expense of many hydraulic models renders their use impractical for ensemble forecasting. To address this challenge, we developed a rating curve library method for flood inundation forecasting. This method involves pre‐running a hydraulic model using multiple inflows and extracting rating curves, which prescribe a relation between streamflow and stage at various cross sections along a river reach. For a given streamflow, flood stage at each cross section is interpolated from the pre‐computed rating curve library to delineate flood inundation depths and extents at a lower computational cost. In this article, we describe the workflow for our rating curve library method and the Rating Curve based Automatic Flood Forecasting (RCAFF) software that automates this workflow. We also investigate the feasibility of using this method to transform ensemble streamflow forecasts into local, probabilistic flood inundation delineations for the Onion and Shoal Creeks in Austin, Texas. While our results show water surface elevations from RCAFF are comparable to those from the hydraulic models, the ensemble streamflow forecasts used as inputs to RCAFF are the largest source of uncertainty in predicting observed floods.     

Low-disturbance manure incorporation effects on ammonia and nitrate loss

Low-disturbance manure application methods can provide the benefits of manure incorporation, including reducing ammonia (NH3) emissions, in production systems where tillage is not possible. However, incorporation can exacerbate nitrate (NO3?) leaching. We sought to assess the trade-offs in NH3 and NO3? losses caused by alternative manure application methods. Dairy slurry (2006-2007) and liquid swine manure (2008-2009) were applied to no-till corn by (i) shallow (<10 cm) disk injection, (ii) surface banding with soil aeration, (iii) broadcasting, and (iv) broadcasting with tillage incorporation. Ammonia emissions were monitored for 72 h after application using ventilated chambers and passive diffusion samplers, and NO3? leaching to 80 cm was monitored with buried column lysimeters. The greatest NH3 emissions occurred with broadcasting (35-63 kg NH3-N ha?), and the lowest emissions were from unamended soil (<1 kg NH-N ha?1). Injection decreased NH-N emissions by 91 to 99% compared with broadcasting and resulted in lower emissions than tillage incorporation 1 h after broadcasting. Ammonia-nitrogen emissions from banding manure with aeration were inconsistent between years, averaging 0 to 71% that of broadcasting. Annual NO3? leaching losses were small (<25 kg NO3-N ha?1) and similar between treatments, except for the first winter when NO3? leaching was fivefold greater with injection. Because NO3? leaching with injection was substantially lower over subsequent seasons, we hypothesize that the elevated losses during the first winter were through preferential flow paths inadvertently created during lysimeter installation. Overall, shallow disk injection yielded the lowest NH3 emissions without consistently increasing NO3? leaching, whereas manure banding with soil aeration conserved inconsistent amounts of N.     

Investigating the chemical nature of humic-like substances (HULIS) in North American atmospheric aerosols by liquid chromatography tandem mass spectrometry

The high-molecular weight water-soluble organic compounds present in atmospheric aerosols underwent functional-group characterization using liquid chromatography tandem mass spectrometry (LC-MS/MS), with a focus on understanding the chemical structure and origins of humic-like substances (HULIS) in the atmosphere. Aerosol samples were obtained from several locations in North America at times when primary sources contributing to organic aerosol were well-characterized: Riverside, CA, Fresno, CA, urban and peripheral Mexico City, Atlanta, GA, and Bondville, IL. Chemical analysis targeted identification and quantification of functional groups, such as aliphatic, aromatic, and bulk carboxylic acids, organosulfates, and carbohydrate-like substances that comprise species with molecular weights (MW) 200–600 amu. Measured high-MW functional groups were compared to modeled primary sources with the purpose of identifying associations between aerosol sources, high-MW aerosol species, and HULIS. Mobile source emissions were linked to high-molecular weight carboxylic acids, especially aromatic acids, biomass burning was associated with carboxylic acids and carbohydrate-like substances, and secondary organic aerosol (SOA) correlated well with the total amount of HULIS measured, whereas organosulfates showed no correlation with aerosol sources and exhibited unique spatial trends. These results suggested the importance of motor vehicles, biomass burning, and SOA as important sources of precursors to HULIS. Structural characteristics of atmospheric HULIS were compared to terrestrial humic and fulvic acids and revealed striking similarities in chemical structure, with the exception of organosulfates which were unique to atmospheric HULIS.     

The consequences of failure should be considered in siting geologic carbon sequestration projects

Geologic carbon sequestration is the injection of anthropogenic CO₂ into deep geologic formations where the CO₂ is intended to remain indefinitely. If successfully implemented, geologic carbon sequestration will have little or no impact on terrestrial ecosystems aside from the mitigation of climate change. However, failure of a geologic carbon sequestration site, such as large-scale leakage of CO₂ into a potable groundwater aquifer, could cause impacts that would require costly remediation measures. Governments are attempting to develop regulations for permitting geologic carbon sequestration sites to ensure their safety and effectiveness. At present, these regulations focus largely on decreasing the probability of failure. In this paper we propose that regulations for the siting of early geologic carbon sequestration projects should emphasize limiting the consequences of failure because consequences are easier to quantify than failure probability.     

The Superfund Remedial Action Decision Process: A Review of Fifty Records of Decision

Abstract

Although the Superfund remedial action decision process is a complex process involving a variety of technical, political, and public health issues, the primary goal of remedial action is the protection of public health. We performed an in-depth analysis of 50 post-SARA Records of Decision in order to characterize the role of risk assessment in the decision-making process and determine whether decisions are being made in an effective and environmentally protective manner. Our findings indicate that the majority of decisions to remediate Superfund sites are based on the existence of contamination per se and not on actual public health risk. Although hypothetical risk is an essential consideration, this gray area is not well-defined in the current decision-making process.

The lack of assessment of the degree of risk reduction associated with the remedial alternatives evaluated and the lack of support indicating the effectiveness of the remedial alternatives selected also constitute major weaknesses in the majority of decisions. These inadequacies undermine rationales regarding the protectiveness and cost-effectiveness of the remedial alternatives selected. The fact that objectives beyond addressing public health risk are often unclear in the decision-making process also weakens rationales for costeffectiveness.     

Kinetics study of fermentative hydrogen production from liquid swine manure supplemented with glucose under controlled pH

Kinetics of H₂ production from liquid swine manure supplemented with glucose by mixed anaerobic cultures was investigated using batch experiments under four different pH conditions (4.4, 5.0, 5.6, and uncontrolled). The temperature for the experiments was controlled at 37 ± 1°C and the length of experiments varied between 50 and 120 hours, depending upon the time needed for completion of each individual experiment. The modified Gompertz model was evaluated for its suitability for describing the H₂ production potential, H₂ production rate, and substrate consumption rate for all the experiments. The results showed that the Gompertz model could adequately fit the experimental results. The effect of pH was significant on all kinetic parameters for H₂ production including yield, production rate and lag time, and the substrate utilization rate. The optimal pH was found to be 5.0, at which a maximum H₂ production rate (0.64 L H₂/h) was obtained, and deviation from the optimal pH could result in substantial reductions in H₂ production rate (0.32 L H₂/h for pH 4.0 and 0.43 L H₂/h for pH 5.6). The results also showed that if pH was not controlled for the batch fermentation process, the substrate utilization efficiency could steeply decrease from 98.8% to 33.7%.