Conductivity as a tracer of agricultural and urban runoff to delineate water quality impacts in the northern Everglades

Agricultural and urban runoff pumped into the perimeter canals of the Arthur R. Marshall Loxahatchee National Wildlife Refuge (Refuge), a 58,320-ha soft-water wetland, has elevated nutrients which impact the Refuge interior marsh. To best manage the Refuge, linkages between inflows to the perimeter canals and environmental conditions within the marsh need to be understood. Conductivity, which typically is high in the canals and lowest at the most interior sites, was used as a surrogate tracer to characterize patterns of constituent transport. The Refuge was initially classified into four zones based upon patterns and variability in conductivity data: Canal Zone; Perimeter Zone (canal to 2.5 km into the interior); Transition Zone (2.5 to 4.5 km from the canal); Interior Zone (>4.5 km from the canal). Conductivity variability declined from the Perimeter to the Interior Zone, with the highest variability in the marsh observed in the Perimeter Zone and the lowest variability observed in the Interior Zone. Analysis of other water quality parameters indicated that conditions in the Perimeter and Transition Zones were different, and more impacted, than in the Interior Zone. In general, there was a positive relationship between structure inflows and canal phosphorus concentrations, including discharges from treatment wetlands and bypasses of untreated water. This classification approach is applicable for stratified sampling designs, resolving spatial bias in water quality models, and in aiding in management decisions about resource allocation.     

Factors Influencing Phosphorus Levels Delivered to Everglades National Park,Florida, USA

Everglades restoration is dependent on constructed wetlands to treat agricultural phosphorus (P)-enriched runoff prior to delivery to the Everglades. Over the last 5 years, P concentrations delivered to the northern boundary of Everglades National Park (Park) have remained higher than the 8 μg L^?1-target identified to be protective of flora and fauna. Historically, Everglades hydrology was driven by rainfall that would then sheetflow through the system. The system is now divided into a number of large impoundments. We use sodium-to-calcium ratios as a water source discriminator to assess the influence of management and environmental conditions to understand why P concentrations in Park inflows remain higher than that of the target. Runoff from Water Conservation Area 3A (Area 3A) and canal water from areas north of Area 3A are two major sources of water to the Park, and both have distinct Na:Ca ratios. The P concentrations of Park inflows have decreased since the 1980s, and from June 1994 through May 2000, concentrations were the lowest when Area 3A water depths were the deepest. Area 3A depths declined following this period and P concentrations subsequently increased. Further, some water sources for the Park are not treated and are impeding concentration reductions. Promoting sheetflow over channelized flow and treating untreated water sources can work in conjunction with constructed wetlands to further reduce nutrient loading to the sensitive Everglades ecosystem.     

Recent Cattail Expansion and Possible Relationships to Water Management: Changes in Upper Taylor Slough (Everglades National Park,Florida, USA)

Recent appearance of cattail (Typha domingensis) within a southern Everglades slough—Upper Taylor Slough (Everglades National Park)—suggests ecosystem eutrophication. We analyze water quality, nutrient enrichment, and water management operations as potential drivers of eutrophication in Upper Taylor Slough. Further, we attempt to determine why surface water phosphorus, a parameter used commonly to monitor ecosystem health in the Everglades, did not serve as an early warning for eutrophication, which has broader implication for other restoration efforts. We found that surface water total phosphorus concentrations generally were below a 0.01 mg L⁻¹ threshold determined to cause imbalances in flora and fauna, suggesting no ecosystem eutrophication. However, assessment of nutrient loads and loading rates suggest Upper Taylor Slough has experienced eutrophication and that continued total phosphorus loading through a point-source discharge was a major driver. These nutrient loads, combined with increases in hydroperiods, led to the expansion of cattail in Upper Taylor Slough. We recommend other metrics, such as nutrient loads, periphyton and arthropod community shifts, and sediment core analyses, for assessing ecosystem health. Monitoring surface water alone is not enough to indicate ecosystem stress.     

On the origin of water-soluble organic tracer compounds in fine aerosols in two cities: the case of Los Angeles and Barcelona

Water-soluble organic compounds (WSOCs), represented by anhydro-saccharides, dicarboxylic acids, and polyols, were analyzed by gas chromatography interfaced to mass spectrometry in extracts from 103 PM₁ and 22 PM_2.5 filter samples collected in an urban background and road site in Barcelona (Spain) and an urban background site in Los Angeles (USA), respectively, during 1-month intensive sampling campaigns in 2010. Both locations have similar Mediterranean climates, with relatively high solar radiation and frequent anti-cyclonic conditions, and are influenced by a complex mixture of emission sources. Multivariate curve resolution-alternating least squares analyses were applied on the database in order to resolve differences and similarities in WSOC compositions in the studied sites. Five consistent clusters for the analyzed compounds were obtained, representing primary regional biomass burning organic carbon, three secondary organic components (aged SOC, isoprene SOC, and α-pinene SOC), and a less clear component, called urban oxygenated organic carbon. This last component is probably influenced by in situ urban activities, such as food cooking and traffic emissions and oxidation processes.