排序方式: 共有19条查询结果,搜索用时 194 毫秒
1.
2.
3.
Angélique C. Belfroid Willem Scinen Kees C. A. M. van Gestel Joop L. M. Hermens Kees J. van Leeuwen 《Environmental science and pollution research international》1995,2(1):5-15
In this paper a method is developed which can be used to estimate the body burden of organic hydrophobic chemicals in earthworms. In contrast to the equilibrium partitioning theory, two routes of uptake are incorporated: uptake from interstitial water and dietary uptake. Although many uncertainties still remain, calculations show that for earthworms steady state body burdens are mainly determined by uptake from interstitial water. Under most circumstances, the contribution of dietary uptake is small, except for hydrophobic chemicals (log Kow > 5) in soils with a high organic matter (OM) content of ≈ 20 %. Under those conditions, estimates of the steady state body burden calculated with the equilibrium partitioning model, in which only uptake from interstitial water is taken into account, might result in a small underestimation of the real body burden of chemicals in earthworms. 相似文献
4.
Eric M. J. Verbruggen Willem M. G. M. van Loon Joop L. M. Hermens 《Environmental science and pollution research international》1996,3(3):163-168
Hydrophobicity is an important property in risk assessment of chemicals. A group parameter that reflects the hydrophobicity of technical mixtures is not yet available. However, many substances are complex organic mixtures, for which it is practically impossible to determine each component separately. An experimental procedure to measure the hydrophobicity of organic mixtures without knowledge of the individual components was developed and tested for a mixture of benzene and twelve chlorobenzenes. This procedure is based on separation of the mixture into fractions of increasing hydrophobicity by reversed-phase HPLC, after which the total molar concentration in each fraction is determined by vapour pressure osmometry. The obtained information on hydrophobicity can be used for assessing bioaccumulation and sediment sorption after emission of the mixture to water has occurred. 相似文献
5.
Steven T.J. Droge Joop L.M. Hermens 《Environmental pollution (Barking, Essex : 1987)》2010,158(10):3116-3122
Mineral surfaces form the main sorption phase for alcohol ethoxylates (AEs) in marine sediment. Competition for adsorption sites is investigated for marine sediment and kaolinite clay using simple mixtures of AE homologues. For both sorbents, adsorption sites on mineral surfaces can be effectively blocked by an AE homologue with the strongest adsorption affinity. The strongly adsorbed AE, however, forms a second sorption phase to which weakly adsorbing AE will sorb, forming bilayers. An extended dual-mode model accounts for competition effects, while still based on sorption properties of individual compounds. Competition effects become apparent when total adsorbed concentrations reach ∼10% of the adsorption capacity. Deviations from individual sorption isotherms depend on affinity constants and dissolved homologue composition. Competition will not often occur in contaminated field sediments, with AEs concentrations usually far below the adsorption capacity, but will affect sorption studies, sediment toxicity tests or applications with nonionic surfactant mixtures. 相似文献
6.
5 –106 times higher compared with less sensitive species. The use of assessment factors in effect assessment procedures may lead
to an underestimation of effects on the more sensitive species.
For many priority pollutants there is little information on their ecotoxicity. Predictive techniques are needed to compensate
for this lack of data. Knowledge of the relation between modes of action of compounds and interspecies variation in sensitivity
should be integrated in risk assessment procedures in order to make more efficient use of the limited financial resources
available. 相似文献
7.
8.
Field contaminated soils are often homogenized before application in bioassays and chemical assays that estimate the (bio)availability of their contaminants. The homogenization of the soil might affect the availability, and thereby the outcome of a bioassay might not reflect field situations. In this study, uptake kinetics of polycyclic aromatic hydrocarbons (PAH) by a negligible depletive passive sampler exposed to a ground and non-ground field contaminated soil were tested. The measurements illustrate how freely dissolved pore water concentrations of contaminants can be affected by soil treatment. It took more than a month, and over a year to reach steady state in the passive sampler exposed to the ground and non-ground soil, respectively. The uptake rate seemed to be limited by desorption from the soil, even though the fiber only extracted 0.2% of the soil-sorbed PAH at maximum. If these observations are translated to the field situation, where contaminants are not homogeneously distributed and disappear by (bio)degradation or physical transport processes, it is unlikely that pore water concentrations are solely determined by a thermodynamic equilibrium. Hence, exposure of organisms in these soils cannot always be estimated by sorption studies and an equilibrium partitioning approach. 相似文献
9.
Environmental impact assessment (EIA) is based on the results of effect prediction. In general, there is much diversity in
the expertise in the field of environmental prediction between the different categories of actors involved in EIA. In practice
it became obvious in The Netherlands that the accessibility and comprehensibility of existing relevant information was insufficient.
For improvement, a series of systematic handbooks on effect prediction, useful for all categories of actors, has been developed
in The Netherlands. In this way, the selection of effect prediction methods to be used in concrete circumstances is improved
and speeded up for all parties involved in environmental prediction. After a discussion of the purpose of the handbook, the
realization and structure of the series are presented. Finally, the use and (potential) benefits of the handbooks for environmental
management are indicated. 相似文献
10.
Dissolved organic carbon/water distribution coefficients (K(DOC)) were measured for a selection of PCBs with octanol/water partition coefficients (K(OW)) ranging from 10(5.6) to 10(7.5). A solid phase dosing and sampling technique was applied to determine K(DOC) to Aldrich humic acid. This technique is in particular suitable for determining the distribution of very hydrophobic chemicals to complex matrices like humic acids. The K(DOC) values were calculated from the experimental data using a linear model. Determined K(DOC)'s were evaluated in relation to octanol/water partition coefficients of the test compounds, and compared to literature data. Measured K(DOC) values were somewhat higher than literature data, which can probably be attributed to the overestimation of freely dissolved aqueous concentration as a result of incomplete phase separation in other studies, and to the unique character of Aldrich humic acid as a "sorbent" or co-solute or to the fact that Aldrich humic acid is not a typical DOC, and other (adsorption) processes can occur. This study reports DOC distribution coefficients that belong to the highest ones ever measured. In addition, the DOC distribution was discussed in relation to current risk assessment modeling. 相似文献