Spatiotemporal variation of odor-active VOCs in Thessaloniki,Greece: implications for impacts from industrial activities

Environmental Science and Pollution Research - A yearlong study of odor-active VOCs was carried out in the northwestern district of the city of Thessaloniki, Greece, which is in close vicinity to a...     

Biotransformation of atrazine and metolachlor within soil profile and changes in microbial communities

Biotransformation studies of atrazine, metolachlor and evolution of their metabolites were carried out in soils and subsoils of Northern Greece. Trace atrazine, its metabolites and metolachlor residues were detected in field soil samples 1 year after their application. The biotransformation rates of atrazine were higher in soils and subsoils of field previously exposed to atrazine (maize field sites) than in respective layers of the field margin. The DT₅₀ values of atrazine ranged from 5 to 18 d in the surface layers of the adapted soils. DT₅₀ values of atrazine increased as the soil depth increased reaching the value of 43 d in the 80-110 cm depth layer of adapted soils. Metolachlor degraded at slower rates than atrazine in surface soils, subsoils of field and field margins with the respective DT₅₀ values ranging from 56 to 72 d in surface soils and from 165 to 186 d in subsoils. Hydroxyatrazine was the most frequently detected metabolite of atrazine. The maximum concentrations of metolachlor-OXA and metolachlor-ESA were detected in the soil layers of 20-40 cm depth after 90 d of incubation. Principal Component Analysis (PCA) of soil Phospholipid Fatty Acids (PLFAs), fungal/bacterial and Gram-negative/Gram-positive ratios of the PLFA profiles revealed that the higher biotransformation rates of atrazine were simultaneously observed with the abundance of Gram-negative bacteria while the respective rates of metolachlor were observed in soil samples with abundance of fungi.     

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Abstract

The basic aim of this article is to briefly explore the links between socio-economic dynamics and desertification in western Lesvos, Greece. The area is characterised by certain socio-economic and development disadvantages, dependence on few productive sectors (mainly on livestock breeding) and by severe problems of land degradation and desertification. The linkages between socio-economic profile, characteristics and development trajectory with the state of environment in the area are identified through a series of in-depth qualitative interviews with local producers (livestock breeders). Research findings reveal the major socio-economic driving forces towards unsustainable productive practices, which contribute to the persistence of the problems of land degradation and desertification.     

Socio-economic dynamics, local development and desertification in western Lesvos, Greece

The basic aim of this article is to briefly explore the links between socio-economic dynamics and desertification in western Lesvos, Greece. The area is characterised by certain socio-economic and development disadvantages, dependence on few productive sectors (mainly on livestock breeding) and by severe problems of land degradation and desertification. The linkages between socio-economic profile, characteristics and development trajectory with the state of environment in the area are identified through a series of in-depth qualitative interviews with local producers (livestock breeders). Research findings reveal the major socio-economic driving forces towards unsustainable productive practices, which contribute to the persistence of the problems of land degradation and desertification.     

Local deposition of mercury in topsoils around coal-fired power plants: is it always true?

Mercury (Hg) is a toxic element that is emitted to the atmosphere through human activities, mainly fossil fuel combustion. Hg accumulations in soil are associated with atmospheric deposition, while coal-burning power plants remain the most important source of anthropogenic mercury emissions. In this study, we analyzed the Hg concentration in the topsoil of the Kozani–Ptolemais basin where four coal-fired power plants (4,065 MW) run to provide 50 % of electricity in Greece. The study aimed to investigate the extent of soil contamination by Hg using geostatistical techniques to evaluate the presumed Hg enrichment around the four power plants. Hg variability in agricultural soils was evaluated using 276 soil samples from 92 locations covering an area of 1,000 km². We were surprised to find a low Hg content in soil (range 1–59 μg kg^?1) and 50 % of samples with a concentration lower than 6 μg kg^?1. The influence of mercury emissions from the four coal-fired power plants on soil was poor or virtually nil. We associate this effect with low Hg contents in the coal (1.5–24.5 μg kg^?1) used in the combustion of these power plants (one of the most Hg-poor in the world). Despite anthropic activity in the area, we conclude that Hg content in the agricultural soils of the Kozani–Ptolemais basin is present in low concentrations.     

An IoT-based bin level monitoring system for solid waste management

Journal of Material Cycles and Waste Management - Improper disposal of solid waste that impacts human health and pollutes the environment, arising a need for successful and necessary collection of...     

Microtubule integrity and cell viability under metal (Cu,Ni and Cr) stress in the seagrass Cymodocea nodosa

The effects of increasing Cu, Ni and Cr concentrations (0.5, 5, 10, 20 and 40 mg L⁻¹) on microtubule organization and the viability of leaf cells of the seagrass Cymodocea nodosa for 13 consecutive days were investigated under laboratory conditions. Increased oblique microtubule orientation, microtubule depolymerization at the 5–40 mg L⁻¹ Ni treatments after 3 d of exposure, and a complete microtubule depolymerization at all Ni treatments after 5 d were observed. Cu depolymerised microtubules after three to 7 d of exposure, while Cr caused an extensive microtubule bundling after 9 or 11 d of exposure, depending on metal dosage. Fluorescence intensity measurements further consolidated the above phenomena. Cell death, occurring at later time than microtubule disturbance, was also observed at all Cu and Ni treatments and at the 10–40 mg L⁻¹ Cr treatments and adding to the above quantification of the number of dead cells clearly showed that only a portion of the cell population studied died. The data presented, being the first assessment of microtubule disturbance in seagrasses, indicate that microtubules in seagrass leaf cells could be used as a valuable and early marker of metal-induced stress in biomonitoring programmes.     

Wildfire policy and use of science in the context of a socio-ecological system on the Aegean Archipelago

This paper summarizes the results of a primarily qualitative (with certain quantitative elements) socio-ecological study on three Greek islands of the Aegean Archipelago to characterize fire science and policy at regional and local levels, and perceptions of fire risk. Among the most important factors influencing dynamics of fire regimes on the islands are changing land use patterns and practices, and changes in climate and fuel conditions. While use of scientific information is not widespread, there are individuals in all three islands who regularly consult scientific sources. Although fire policy is largely controlled at the national and European Union levels, local activity also occurs, most notably through the volunteer fire fighting organizations, interactions with local officials, and public education efforts. However, though seen as important, significant lack of financial support and resources exist to support prevention and pre-suppression programs. Prevention of fires on the islands, including the use of prescribed burning, is relatively inadequate, and while an intense interest in preventing the loss of communities and ecosystems is frequently encountered, public participation in fire prevention remains limited. The findings suggest that relying on local knowledge, in combination with fire managers’ decision-making abilities, could improve fire management options and reduce wildfire suppression costs and ecological disasters.     

Biodegradation and detoxification of olive mill wastewater by selected strains of the mushroom genera Ganoderma and Pleurotus

Thirty-nine white-rot fungi belonging to nine species of Agaricomycotina (Basidiomycota) were initially screened for their ability to decrease olive-mill wastewater (OMW) phenolics. Four strains of Ganoderma australe, Ganoderma carnosum, Pleurotus eryngii and Pleurotus ostreatus, were selected and further examined for key-aspects of the OMW biodegradation process. Fungal growth in OMW-containing batch cultures resulted in significant decolorization (by 40-46% and 60-65% for Ganoderma and Pleurotus spp. respectively) and reduction of phenolics (by 64-67% and 74-81% for Ganoderma and Pleurotus spp. respectively). COD decrease was less pronounced (12-29%). Cress-seeds germination increased by 30-40% when OMW was treated by Pleurotus strains. Toxicity expressed as inhibition of Aliivibrio fischeri luminescence was reduced in fungal-treated OMW samples by approximately 5-15 times compared to the control. As regards the pertinent enzyme activities, laccase and Mn-independent peroxidase were detected for Ganoderma spp. during the entire incubation period. In contrast, Pleurotus spp. did not exhibit any enzyme activities at early growth stages; instead, high laccase (five times greater than those of Ganoderma spp.) and Mn peroxidases activities were determined at the end of treatment. OMW decolorization by Ganoderma strains was strongly correlated to the reduction of phenolics, whereas P. eryngii laccase activity was correlated with the effluent’s decolorization.     

Chemical composition and mass closure of ambient coarse particles at traffic and urban-background sites in Thessaloniki,Greece

Concentrations and chemical composition of the coarse particle fraction (PM_c) were investigated at two urban sites in the city of Thessaloniki, Greece, through concurrent sampling of PM₁₀ and PM_2.5 during the warm and the cold months of the year. PM_c levels at the urban-traffic site (UT) were among the highest found in literature worldwide exhibiting higher values in the cold period. PM_c levels at the urban-background site (UB) were significantly lower exhibiting a reverse seasonal trend. Concentration levels of minerals and most trace metals were also higher at the UT site suggesting a stronger impact from traffic-related sources (road dust resuspension, brake and tire abrasion, road wear). According to the chemical mass closure obtained, minerals (oxides of Si, Al, Ca, Mg, Fe, Ti, and K) dominated the PM_c profile, regardless of the site and the period, with organic matter and secondary inorganic aerosols (mainly nitrate) also contributing considerably to the PM_c mass, particularly in the warm period. The influence of wind speed to dilution and/or resuspension of coarse particles was investigated. The source of origin of coarse particles was also investigated using surface wind data and atmospheric back-trajectory modeling. Finally, the contribution of resuspension to PM_c levels was estimated for air quality management perspectives.