Methyl methacrylate (MMA) and alumina recovery from waste artificial marble powder pyrolysis

Journal of Material Cycles and Waste Management - Owing to various advantages of artificial marble compared to natural marble, its application has been rising exponentially, which has resulted in...     

Investigations of ash fouling with cattle wastes as reburn fuel in a small-scale boiler burner under transient conditions

Fouling behavior under reburn conditions was investigated with cattle wastes (termed as feedlot biomass [FB]) and coal as reburn fuels under a transient condition and short-time operation. A small-scale (30 kW or 100,000 Btu/hr) boiler burner research facility was used for the reburn experiments. The fuels considered for these experiments were natural gas (NG) for the ashless case, pure coal, pure FB, and blends of coal and FB. Two parameters that were used to characterize the ash "fouling" were (1) the overall heat-transfer coefficient (OHTC) when burning NG and solid fuels as reburn fuels, and (2) the combustible loss through ash deposited on the surfaces of heat exchanger tubes and the bottom ash in the ash port. A new methodology is presented for determining ash-fouling behavior under transient conditions. Results on the OHTCs for solid reburn fuels are compared with the OHTCs for NG. It was found that the growth of the layer of ash depositions over longer periods typically lowers OHTC, and the increased concentration of ash in gas phase promotes radiation in high-temperature zones during initial periods while decreasing the heat transfer in low-temperature zones. The ash analyses indicated that the bottom ash in the ash port contained a smaller percentage of combustibles with a higher FB percentage in the fuels, indicating better performance compared with coal because small particles in FB burn faster and the FB has higher volatile matter on a dry ash-free basis promoting more burn out.     

Distribution of diatoms in the surficial sediments of the Mangyung-Dongjin tidal flat,west coast of Korea (Eastern Yellow Sea)

The relationship between the distribution of benthic diatoms and sediment characteristics of the Mangyung-Dongjin tidal flat on the west coast of Korea was investigated during June and July 1988. Diatoms were collected from the upper 5 mm of sediments at 60 sites along eight transect lines running perpendicular to the shore line. Of the 371 taxa encountered in the study area, 88% were pennate diatoms. Genera represented by the greatest number of species were Navicula, Nitzschia, Amphora, Cocconeis, Fragilaria and Achnanthes. The most abundant species were Paralia sulcata, Navicula sp. #1, N. arenaria and Cymatosira belgica; all were broadly distributed across the tidal flats. The 60 sites could be assigned to eight clusters with respect to similarity in species composition. Discriminant analysis showed that separation cluster was primarily related to the mean grain size of the sediment. The species could not be separated into groups based on similarities in occurrence; a high degree of spatial overlap was observed. The preferences of the more abundant species for grain size were, therefore, analysed by plotting numerical abundance against mean grain size. There were at least four patterns: species groups could be associated with finegrained sediments, those of intermediate size and coarser sediments and the last group showed no discernible pattern.     

Induction of cytochrome P4501A and endocrine disrupting effects of school incinerator residues

The emission of the dioxin-like compounds from on-site waste incinerators of seven schools in Kyonggi Province of Korea was evaluated by determination of the cytochrome P4501A(CYP1A) catalytic activity and antiestrogenic activity using cell culturemicrobioassay. The residue samples were extracted in a Soxhlet apparatus using toluene for 20 hr. The concentrated crude extractswere fractionated with a basic alumina column. Dioxin-like compounds were then extracted. Induction of CYP1A activity in a rat(H4IIE) hepatoma cell line was used as indicator of biologicaleffect of incinerator residues and measured as 7-ethoxyresorufin-O-deethylase(EROD) activities. The EROD activities of fraction II extracts (one of the two extracts) in the H4IIE cells were from 0.044±0.002 to 4.424±0.351 ng-TEQ g^-1 (TCDD Toxicity equivalent), showing relatively high inducing capacity. Antisetrogenicity of the extracts was measured as decrease in E₂-induced cell proliferation. Most of the extracts showed antiestrogenic activity in MCF7-BUS cell.The TEQ levels of the incinerator residues and the antiestrogenicactivities were in good correlation, strongly suggesting that thepotent toxic emissions were indeed produced from the on-site school waste semi-incinerators and could cause the antiestrogenicity.     

Seasonal characteristics of haze observed by continuous visibility monitoring in the urban atmosphere of Kwangju, Korea

Continuous visibility monitoring has been carried out inKwangju, Korea since May 1999. The total light extinctioncoefficient b _ext measured by a transmissometer andreveals seasonal trends in urban visual air quality,especially under hazy conditions with a visual range of lessthan 15 km. Seasonal atmospheric visibility under lowrelative humidity during the winter was observed to be betterthan during any other seasons. Summertime visibility wasseverely degraded due to highly increased light scattering byhygroscopic particles under high humidity atmosphericconditions. Visibility during spring and fall was alsomoderate. However, yellow sand in spring caused the lowestvisibility conditions over the measurement area for a fewdays. With continuous monitoring using the transmissometer,the daily average seasonal visual range was measured to be13.1, 9.2, 11.0, and 13.9 km in spring, summer, falland winter, respectively. Under the atmospheric humiditycondition less than 60%, visual range was observed tobe 16.1, 13.9, 15.1, and 16.6 km in spring, summer,fall, and winter, respectively. The mean light extinctionbudget by sulfate and nitrate aerosols was determined to bethe highest value of 63.71% during the summer and thelowest value of 27.08% during spring. During the `yellow sand dust' period, a mean light extinction budget by soil particles was estimated to be at an unusually high value of 44.22%.     

Aerosol Optical and Radiative Properties Observed at Anmyeon and Jeju, Korea in the Spring of 2000 and 2001

The radiative properties of atmospheric aerosols are determined by their masses, chemical characteristics, and optical properties, such as aerosol optical depth (AOD), Åstrom;ngström parameter (α) and single scattering albedo (SSA). In particular, the aerosol optical properties determine the surface temperature perturbation that may give some information in understanding regional atmospheric radiative forcing. To understand the radiative forcing and regional source of an aerosol, the present study focused on the analysis of the aerosol optical properties based on two different observations in the spring season, during the special Asian dust storm period. The Korean Global Atmosphere Watch Observatory (KGAWO), at Anmyeon Island, and the ACE-Asia super-site, at Gosan, Jeju Island, have measured radiations and aerosols since 2000. The sites are located in the mid-west and south of the Korean peninsula, which are strongly affected by the Asian dust coming from China every spring. The aerosol optical properties, measured by ground-based sun and sky radiometers, over both sites were analyzed to gain an understanding of the radiation and climate properties.The probability distributions of the aerosol optical depths were rather narrow, with a modal value of approximately 0.38 at both sites during 2001 and 2002. The Ångström parameter frequency distributions showed two peaks at Anmyeon GAW, but only one peak at the Jeju ACE-Asia super site. One peak, around 0.63, characterizes the situation of a day having Asian dust, the second peak, around 1.13, corresponded to the relatively dust-free cases. The correlation between the aerosol optical depth and the Ångström exponents resulted in a wide range of the Ångström parameter, α, over a wide range of optical depths at Anmyeon, whereas a narrow range of α, with moderate to low values for the AOD at Jeju. Under dust free conditions the single scattering albedo (SSA) decreased with wavelength, while in the presence of Asian dust,the SSA either stayed neutral, or increased slightly with wavelength at Anmyeon, and showed higher value than Jeju. The change in the surface temperature was highly correlated with increases in the aerosol optical depth at Anmyeon to a greater extent than at Jeju.     

Hydro-thermal reaction according to the CaO/SiO2 mole-ratio in silico-manganese slag

Journal of Material Cycles and Waste Management - SiMn slag is a by-product of the production of ferroalloy, and has a chemical composition that could be used as a cement admixture. It is not...     

Inhibition of residual <Emphasis Type="Italic">n</Emphasis>-hexane in anaerobic digestion of lipid-extracted microalgal wastes and microbial community shift

Converting lipid-extracted microalgal wastes to methane (CH₄) via anaerobic digestion (AD) has the potential to make microalgae-based biodiesel platform more sustainable. However, it is apparent that remaining n-hexane (C₆H₁₄) from lipid extraction could inhibit metabolic pathway of methanogens. To test an inhibitory influence of residual n-hexane, this study conducted a series of batch AD by mixing lipid-extracted Chlorella vulgaris with a wide range of n-hexane concentration (～10 g chemical oxygen demand (COD)/L). Experimental results show that the inhibition of n-hexane on CH₄ yield was negligible up to 2 g COD/L and inhibition to methanogenesis became significant when it was higher than 4 g COD/L based on quantitative mass balance. Inhibition threshold was about 4 g COD/L of n-hexane. Analytical result of microbial community profile revealed that dominance of alkane-degrading sulfate-reducing bacteria (SRB) and syntrophic bacteria increased, while that of methanogens sharply dropped as n-hexane concentration increased. These findings offer a useful guideline of threshold n-hexane concentration and microbial community shift for the AD of lipid-extracted microalgal wastes.     

Concentration of trace elements in feathers of waterfowl,Korea

Cadmium (Cd), lead (Pb), chromium (Cr), copper (Cu), manganese (Mn), zinc (Zn), and iron (Fe) were analyzed in the breast feather of white-fronted geese (Anser albifrons, n?=?15), mallards (Anas platyrhynchos, n?=?4), and spot-billed ducks (Anas poecilorhyncha, n?=?13) found dead in Gimpo, Korea. All of the mallards and eight of the 13 spot-billed ducks had embedded shot. Concentrations of Pb, Cr, Cu, Mn, Zn, and Fe were significantly different among waterfowl species. Mallards with embedded shot had relatively higher Pb, Cr, Mn, and Fe concentrations than the other species. Cd and Cr in feathers of waterfowl species were within the range reported for other birds, and no specimen exceeded the tentative threshold effect levels of Cd (2 μg/g dry weight (dw)) and Cr (2.8 μg/g dw) for birds. However, Pb in feathers of all four mallards and two spot-billed ducks exceeded the threshold for deleterious effects (>4 μg/g dw). Essential elements such as Cu, Mn, Zn, and Fe in the feather of waterfowl species were not at toxic levels and within the background or normal range for the homeostatic mechanisms.     

Lead and cadmium contaminations in feathers of heron and egret chicks

In birds, concentrations of heavy metal contaminants were associated with their diet and environmental quality. This study presents concentrations of lead and cadmium in feathers and the relationship between concentrations in the feather and stomach content of three species of heron and egret chicks. Cadmium concentrations were higher in the Little Egret (geomean 0.75 μg/g dry weight) and Black-crowned Night Heron (geomean 0.88 μg/g dry weight) chicks than in Grey Heron chicks (geomean 0.48 μg/g dry weight). Lead and cadmium concentrations had significant correlations between feathers and stomach contents of heron and egret chicks. The mean lead and cadmium concentrations in feathers were within the background levels for wild birds. Heron and egret species forage around breeding colony (4–7 km). Lead and cadmium concentrations in heron and egret chicks were moderately associated with those of prey concentrations. These results suggest that contaminant concentrations such as lead and cadmium in feathers of heron and egret chicks can reflect local heavy metal contaminations and serve as a great biological indicator for monitoring heavy metal contamination. In addition, the feathers can be a routine monitoring tool over time and space without harming the wild birds.