Elimination of Cs+ from aquatic systems by an adsorbent prepared by immobilization of potassium copper hexacyanoferrate on the SBA-15 surface: kinetic,thermodynamic, and isotherm studies

Environmental Science and Pollution Research - For elimination of cesium from aqueous solutions, mesoporous SBA-15 was synthesized and employed as the support for immobilization of potassium copper...     

Quantitative assessment of desertification in south of Iran using MEDALUS method

The main aim of this study was the quantitative assessment of desertification process in the case study area of the Fidoye-Garmosht plain (Southern Iran). Based on the MEDALUS approach and the characteristics of study area a regional model developed using GIS. Six main factors or indicators of desertification including: soil, climate, erosion, plant cover, groundwater and management were considered for evaluation. Then several sub-indicators affecting the quality of each main indicator were identified. Based on the MEDALUS approach, each sub-indicator was quantified according to its quality and given a weighting of between 1.0 and 2.0. ArcGIS 9 was used to analyze and prepare the layers of quality maps using the geometric mean to integrate the individual sub-indicator maps. In turn the geometric mean of all six quality maps was used to generate a single desertification status map. Results showed that 12% of the area is classified as very severe, 81% as severe and 7% as moderately affected by desertification. In addition the plant cover and groundwater indicators were the most important factors affecting desertification process in the study area. The model developed may be used to assess desertification process and distinguish the areas sensitive to desertification in the study region and in regions with the similar characteristics.     

Investigation of wind erosion process for estimation, prevention, and control of DSS in Yazd–Ardakan plain

Wind erosion is a phenomenon that is reasonably common in regions where dry winds blow. For the most part, these regions correspond to the dry lands; areas where the soil, generally, is dry and shifting and lacks vegetation for most of the year. The winds are sufficiently strong to lift and move sands and soil particles. The repeated removal of superficial layers by the action of winds can modify the texture of the topsoil, by removing the fine particles and leaving the larger particles. Dust and sandstorm (DSS) is the generic term for a serious environmental phenomenon that involves strong winds that blow a large quantity of dust and fine sand particles away from the ground and carry them over a long distance with significant environmental impacts along the way. In the realm of DSS in Iran country, the people who live in Yazd and Sistan–Baluchestan provinces form a single ecological community due to their geographic proximity and climatic contiguity. The major sources of DSS in the region are believed to be the desert and semidesert areas of the Yazd–Ardakan plain in Yazd province. Both Sistan and Baluchestan are the recipients of this dust. To address the long-range transboundary environmental problem of DSS, a regional cooperation mechanism must be established among the provinces in the region. Yazd–Ardakan plain, with area of about 650,000 ha, is located in the center of Iran, between Yazd and Ardakan cities. The mean annual rainfall is less than 65 mm. Rainfall distribution is a simple modal and more than 70% of it occurs in winter. Plant density varies from 0% to 25%, and Artemisia sieberi is the dominant plant species. The major part of Yazd–Ardakan plain is bare land. According to the recent investigation, more than 20,000-m³ dust with less than 100-μm diameter falls down annually on Yazd city with an area of 7,000 ha. Horizontal visibility is reduced to less than 6 m in stormy days in some parts of Yazd–Ardakan plain. This phenomenon causes car accidents on the main roads of Yazd–Ardakan and can cancel the airplane flights in the stormy days. At present, it is estimated that wind erosion causes more than $6.8 million damages to socioeconomic resources in Yazd plain each year. This paper describes the pattern of occurrence of wind erosion and major contributing factors, summarizes measured rates of wind erosion, outlines the techniques used to mitigate wind erosion hazard, and suggests research priorities. Also, damages of DSS have been estimated and methods for prevention and control are suggested.     

Simultaneous removal of Congo red and cadmium(II) from aqueous solutions using graphene oxide–silica composite as a multifunctional adsorbent

Graphene oxide is a very high capacity adsorbent due to its functional groups and π?π interactions with other compounds. Adsorption capacity of graphene oxide, however, can be further enhanced by having synergistic effects through the use of mixed-matrix composite. In this study, silica-decorated graphene oxide (SGO) was used as a high-efficiency adsorbent to remove Congo red (CR) and Cadmium (II) from aqueous solutions. The effects of solution initial concentration (20 to 120 mg/l), solution pH (pH 2 to 7), adsorption duration (0 to 140 min) and temperature (298 to 323 K) were measured in order to optimize the adsorption conditions using the SGO adsorbent. Morphological analysis indicated that the silica nanoparticles could be dispersed uniformly on the graphene oxide surfaces. The maximum capacities of adsorbent for effective removal of Cd (II) and CR were 43.45 and 333.33 mg/g based on Freundlich and Langmuir isotherms, respectively. Langmuir and Freundlich isotherms displayed the highest values of Q_max for CR and Cd (II) adsorption in this study, which indicated monolayer adsorption of CR and multilayer adsorption of Cd (II) onto the SGO, respectively. Thermodynamic study showed that the enthalpy (ΔH) and Gibbs free energy(ΔG) values of the adsorption process for both pollutants were negative, suggesting that the process was spontaneous and exothermic in nature. This study showed active sites of SGO (π-π, hydroxyl, carboxyl, ketone, silane-based functional groups) contributed to an enormous enhancement in simultaneous removal of CR and Cd (II) from an aqueous solution, Therefore, SGO can be considered as a promising adsorbent for future water pollution control and removal of hazardous materials from aqueous solutions.