Potential of fly ash for neutralisation of acid mine drainage

Lignite (PK), bituminous (FI) and biomass (SE) fly ashes (FAs) were mineralogically and geochemically characterised, and their element leachability was studied with batch leaching tests. The potential for acid neutralisation (ANP) was quantified by their buffering capacity, reflecting their potential for neutralisation of acid mine drainage. Quartz was the common mineral in FAs detected by XRD with iron oxide, anhydrite, and magnesioferrite in PK, mullite and lime in FI, and calcite and anorthite in SE. All the FAs had high contents of major elements such as Fe, Si, Al and Ca. The Ca content in SE was six and eight times higher compared to PK and FI, respectively. Sulphur content in PK and SE was one magnitude higher than FI. Iron concentrations were higher in PK. The trace element concentrations varied between the FAs. SE had the highest ANP (corresponding to 275 kg CaCO₃?tonne^?1) which was 15 and 10 times higher than PK and FI, respectively. The concentrations of Ca²⁺, SO₄ ^2?, Na⁺ and Cl^? in the leachates were much higher compared to other elements from all FA samples. Iron, Cu and Hg were not detected in any of the FA leachates because of their mild to strong alkaline nature with pH ranging from 9 to 13. Potassium leached in much higher quantity from SE than from the other ashes. Arsenic, Mn and Ni leached from PK only, while Co and Pb from SE only. The concentrations of Zn were higher in the leachates from SE. The FAs used in this study have strong potential for the neutralisation of AMD due to their alkaline nature. However, on the other hand, FAs must be further investigated, with scaled-up experiments before full-scale application, because they might leach pronounced concentrations of elements of concern with decreasing pH while neutralising AMD.     

Efficacy of feed improvement in livestock farming to offset climate variations in Punjab,Pakistan: silage as an example

Environmental Science and Pollution Research - Globally, climate change is an alarming threat to the livestock industry. Such changes in the climate can also adversely affect the returns of...     

The role of technology innovation and people’s connectivity in testing environmental Kuznets curve and pollution heaven hypotheses across the Belt and Road host countries: new evidence from Method of Moments Quantile Regression

Environmental Science and Pollution Research - The Belt and Road Initiative (BRI) is closely linked to the ecological sustainability of the infrastructure ventures that intrinsically include the...     

Impact of economic capabilities and population agglomeration on PM2.5 emission: empirical evidence from sub-Saharan African countries

Environmental Science and Pollution Research - The utilization of economic capabilities to raise production in the economy enhances the industrial activities and use of transportation. These...     

Multisensory vocal communication in primates and the evolution of rhythmic speech

The integration of the visual and auditory modalities during human speech perception is the default mode of speech processing. That is, visual speech perception is not a capacity that is “piggybacked” on to auditory-only speech perception. Visual information from the mouth and other parts of the face is used by all perceivers to enhance auditory speech. This integration is ubiquitous and automatic and is similar across all individuals across all cultures. The two modalities seem to be integrated even at the earliest stages of human cognitive development. If multisensory speech is the default mode of perception, then this should be reflected in the evolution of vocal communication. The purpose of this review is to describe the data that reveal that human speech is not uniquely multisensory. In fact, the default mode of communication is multisensory in nonhuman primates as well but perhaps emerging with a different developmental trajectory. Speech production, however, exhibits a unique bimodal rhythmic structure in that both the acoustic output and the movements of the mouth are rhythmic and tightly correlated. This structure is absent in most monkey vocalizations. One hypothesis is that the bimodal speech rhythm may have evolved through the rhythmic facial expressions of ancestral primates, as indicated by mounting comparative evidence focusing on the lip-smacking gesture.     

Fiscal spending and the environment: Theory and empirics

During economic crises, governments often increase fiscal spending to stimulate the economy. While the fiscal spending surge may be temporary, spending composition is often altered in favor of expenditures on social programs and other public goods which may persist over time. We model and measure the impact of fiscal spending patterns on the environment. The model predicts that a reallocation of government spending composition towards social and public goods reduces pollution. However, increasing total government spending without altering its composition does not reduce pollution. We empirically test these predictions for air and water pollutants showing that they are fully supported.     

Degradation of sodium 4-dodecylbenzenesulphonate photoinduced by Fe(III) in aqueous solution

The Fe(III)-photoinduced degradation of 4-dodecylbenzenesulphonate (DBS) in aqueous solution was investigated. The mixing of DBS (1 mm) and Fe(III) (1 mm) solutions immediately led to the formation of a precipitate that contained DBS and monomeric Fe(OH)2+, the predominant Fe(III) species. Both species were also present in the supernatant. Irradiation of the supernatant solution resulted in a photoredox process that yielded Fe(II) and *OH radicals. The disappearance of DBS was shown to involve only attack by *OH radicals; the quantum yield of DBS disappearance is similar to the quantum yield of *OH radical formation. A wavelength effect was also observed; the rate of DBS disappearance was higher for shorter wavelength irradiation. Five photoproducts, all containing the benzene sulphonate group, were identified. *OH radicals preferentially abstract hydrogen from the carbon in the alpha position of the aromatic ring. The results show that the Fe(III)-photoinduced degradation of DBS could be used as an alternative method for polluted water treatment.     

Mercury cycling and species mass balances in four North American lakes

A mass balance model for mercury based on the fugacity concept is applied to Lake Superior, Lake Michigan, Onondaga Lake and Little Rock Lake to evaluate model performance, analyze cycling of three mercury species groups (elemental, divalent and methyl mercury), and identify important processes that determine the source-to-concentration relationship of the three mercury species groups in these lakes. This model application to four disparate ecosystems is an extension of previous applications of fugacity-based models describing mercury cycling. The model performs satisfactorily following site-specific parameterization, and provides an estimate of minimum rates of species interconversion that compare well with literature. Volatilization and sediment burial are the main processes removing mercury from the lakes, and uncertainty analyses indicate that air-water exchange of elemental mercury and water-sediment exchange of divalent mercury attached to particles are influential in governing mercury concentrations in water. Any new model application or field campaign to quantify mercury cycling in a lake should consider these processes as important.