Introducing roadside hazard severity indicator based on evidential reasoning approach

Safety experts have, in recent years, been attentive to roadside accident severity and occurrence. Hitherto, to prioritize road segment hazardousness, there have been little efforts to quantify a well defined indicator. In this regard, the existing indicators are usually very plain and the overall configuration of roadside is rated by experts with an exact number describing its condition. Hence, the uncertainties which come with the subjective judgments cannot be regarded as of any substance. This research contribution therefore presents a procedure to assess the road safety (roadside safety indicator) by means of the evidential reasoning (ER) approach. The betterment of ER as opposed to the available procedures for roadside safety assessment is that the proposed approach makes allowance for the uncertainties which may arise from individual judgments. Additionally, when there is a dearth of evidence concerning factors which affect roadside hazardousness severity to collate several roadside segments, this procedure will offer the benefits of utilizing the maximum/minimum utility function. With the aid of the drawn indicator, organizations and agencies responsible for ensuring road safety can reach more flexible decisions to set in-place uncertain planning and road segments priorities. This indicator can also be utilized as a variable to include roadside conditions in crash severity prediction models. A field case study has also been carried out in an attempt to follow and validate the proposed approach which is based on the run-off accident history for a sample road segments. The crash data confirm the suggested indicator.     

Biofuel production,hydrogen production and water remediation by photocatalysis,biocatalysis and electrocatalysis

The energy crisis and environmental pollution have recently fostered research on efficient methods such as environmental catalysis to produce biofuel and to clean water. Environmental catalysis refers to green catalysts used to breakdown pollutants or produce chemicals without generating undesirable by-products. For example, catalysts derived from waste or inexpensive materials are promising for the circular economy. Here we review environmental photocatalysis, biocatalysis, and electrocatalysis, with focus on catalyst synthesis, structure, and applications. Common catalysts include biomass-derived materials, metal–organic frameworks, non-noble metals nanoparticles, nanocomposites and enzymes. Structure characterization is done by Brunauer–Emmett–Teller isotherm, thermogravimetry, X-ray diffraction and photoelectron spectroscopy. We found that water pollutants can be degraded with an efficiency ranging from 71.7 to 100%, notably by heterogeneous Fenton catalysis. Photocatalysis produced dihydrogen (H₂) with generation rate higher than 100 μmol h⁻¹. Dihydrogen yields ranged from 27 to 88% by methane cracking. Biodiesel production reached 48.6 to 99%.

     

Investigation on the role of traffic volume in accidents on urban highways

Introduction

Roadway safety is a major concern for the general public and public agencies, as roadway crashes claim many lives and cause substantial economic loss each year. In Iran, a large number of vehicles are involved in road accidents each year, which cause many deaths and extensive property damage; such accidents are among the major causes of death and disability in the country. Method: To reduce roadway accidents, the factors that affect the occurrence and severity of accidents should be scrutinized to prevent or reduce their effect. The method that many researchers have adopted to determine the effective parameters surrounding road accidents in recent years is through statistical modeling of accidents. In this article, the role of different kinds of vehicles in traffic flow are investigated separately in terms of the likelihood of crashes on urban highways, and the vehicles are divided into three groups: passenger cars, heavy vehicles, and light non-passenger car vehicles. Poisson and negative binomial (NB) regression models were applied to model the accidents in this research, which were categorized into two groups: no injury (property damage only) accidents and more severe (injury and fatal) accidents. Results: Ultimately, we conclude that light non-passenger car vehicles (i.e., taxis and motorcycles) play the largest role in the occurrence of crashes on urban highways for both types of accidents.     

Kinetic study on photocatalytic degradation of Acid Orange 52 in a baffled reactor using TiO2 nanoparticles

In this study, a baffled photocatalytic reactor was used for the treatment of colored wastewater containing the azo dye of Acid Orange 52(AO52). A study on the active species of the photocatalytic process using TiO_2 nanoparticles indicated that hydroxyl radical and superoxide have the greatest contribution to the dye degradation process respectively.Given that a level of biological oxygen demand/chemical oxygen demand(BOD5/COD) equal to 0.4 was achieved after about 5 hr from the beginning of the experiment, the reactor seems to be capable of purifying the wastewater containing AO52 dye after this time in order to discharge into a biological treatment system to continue the treatment process.The results of the liquid chromatography-mass spectrometry(LC-MS) test showed that during the first 4 hr of the experiment, with the breakdown of the azo bond, the contaminant was decomposed into the benzene annular compounds with less toxicity indicating a reduction in the toxicity of wastewater after removing the dye agent. The study on the kinetics of these reactions followed the pseudo-first-order kinetic model in all conditions and corresponded well to Langmuir–Hinshelwood model. According to the kinetic model for the simultaneous occurrence of possible pathways, the kinetic constant of production and degradation of intermediate products in optimal conditions was estimated to be between 0.0029 and 0.0391 min~(-1).     

Microplastics in urban waters and its effects on microbial communities: a critical review

Environmental Science and Pollution Research - Microplastic (MP) pollution is one of the emerging threats to the water and terrestrial environment, forcing a new environmental challenge due to the...