Simultaneous Sampling of Gas- and Aerosol-Phase TDI with a Triple Filter System

Abstract

A new triple filter system sampler/model is proposed for the precise and accurate simultaneous sampling and determination of gas- and aerosol-phase 2,4-toluene diisocyanate (TDI). The system consists of two front Teflon filters for sampling aerosol-phase TDI and a final coated glass fiber filter to collect gas-phase TDI. The aerosol-phase TDI is collected on the first Teflon filter, while the second Teflon filter is used to estimate gaseous TDI adsorbed by the first. According to the gas adsorption test of two Teflon filters in series, the TDI gas adsorption fraction of the two filters is almost the same. Results of the evaporation test using pure TDI aerosols collected on the Teflon filter show that significant evaporation of the compound does not occur during sampling. These two findings allow the use of a model to estimate accurate gasand aerosol-phase TDI concentrations. The comparison test with an annular denuder shows that the triple filter system can minimize the TDI sampling bias between the dual filter and the annular denuder systems.     

Assessing heavy metal pollution in the surface soils of a region that had undergone three decades of intense industrialization and urbanization

Heavy metals in the surface soils from lands of six different use types in one of the world’s most densely populated regions, which is also a major global manufacturing base, were analyzed to assess the impact of urbanization and industrialization on soil pollution. A total of 227 surface soil samples were collected and analyzed for major heavy metals (As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, and Zn) by using microwave-assisted acid digestion and inductively coupled plasma–mass spectrometry (ICP-MS). Multivariate analysis combined with enrichment factors showed that surface soils from the region (>7.2?×?10⁴ km²) had mean Cd, Cu, Zn, and As concentrations that were over two times higher than the background values, with Cd, Cu, and Zn clearly contributed by anthropogenic sources. Soil pollution by Pb was more widespread than the other heavy metals, which was contributed mostly by anthropogenic sources. The results also indicate that Mn, Co, Fe, Cr, and Ni in the surface soils were primarily derived from lithogenic sources, while Hg and As contents in the surface soils were controlled by both natural and anthropogenic sources. The pollution level and potential ecological risk of the surface soils both decreased in the order of: urban areas?>?waste disposal/treatment sites?～?industrial areas?>?agricultural lands?～?forest lands?>?water source protection areas. These results indicate the significant need for the development of pollution prevention and reduction strategies to reduce heavy metal pollution for regions undergoing fast industrialization and urbanization.     

Decomposition of SF6 in an RF Plasma Environment

Abstract

Sulfur hexafluoride (SF₆)-contained gas is a common pollutant emitted during the etching process used in the semiconductor industry. This study demonstrated the application of radio-frequency (RF) plasma in the decomposition of SF₆. The decomposition fraction of SF₆ [η_SF6 (C_in–C_out)/C_in x 100%] and the mole fraction profile of the products were investigated as functions of input power and feed O₂/SF₆ ratio in an SiO₂ reactor. The species detected in both SF₆/Ar and SF₆/O₂/Ar RF plasmas were SiF₄, SO₂, F₂, SO₂F₂, SOF₂, SOF₄, S₂F₁₀, S₂OF₁₀, S₂O₂F₁₀, and SF₄. The results revealed that at 40 W, η_SF6 exceeded 99%, and the reaction products were almost all converted into stable compounds such as SiF₄, SO₂, and F₂ with or without the addition of oxygen. Sulfur oxyfluorides such as SO₂F₂, SOF₂, SOF₄, S₂OF₁₀, and S₂O₂F₁₀ were produced only below 40 W. The results of this work can be used to design a plasma/chemical system for online use in a series of a manufacturing process to treat SF₆-containing exhaust gases.     

Development of regenerative dye impregnated mesoporous silica materials for assessing exposure to ammonia

The mesostructured materials MCM-41 and SBA-15 were studied as possible supports of bromocresol green (BG) dye impregnation for the ammonia gas detection because of their large surface area, high regenerative property, and high thermal stability. X-ray diffraction, transmission electron microscopy, scanning electron microscope, and N2 adsorption analysis were used to characterize the prepared materials. These materials could sense ammonia via visible color change from yellowish-orange to blue color. The color change process of the nanostructured materials was fully reversible during 10 cyclic tests. The results indicated that the ammonia absorption responses of the two nanostructured materials were both very sensitive, and high linear correlation and high precision were achieved. As the gaseous ammonia concentrations were 50 and 5 ppmv, the response times for the SBA-15/BG were only 1 and 5 min, respectively. Moreover the BG dye-impregnated SBA-15 was less affected by the variation in the relative humidity. It also had faster response for the detection of NH3, as well as lower manufacturing price as compared to that of the dye-impregnated MCM-41. Such feature enables SBA-15/BG to be a very promising material for the detection of ammonia gas.     

Management of sustainability transitions through planning in shrinking resource city contexts: an evaluation of Yubari City,Japan

This paper evaluates the planning competences required to enact a managed transition to sustainability at the municipal level for cities facing population, economic and employment decline. Drawing on the ‘shrinking cities’ literature, we argue consolidation of the built environment can become a focal point for sustaining citizen welfare when transitioning cities that are facing decline, especially those previously reliant on resource industries. We evaluate the former coal mining city of Yubari, Japan, which is developing a consolidated urban form with the aim of creating a ‘sustainable’ future city. Findings from interviews and content analysis of Yubari’s planning policy indicate, however, that to translate ‘shrinking’ a city into a managed transition, spatial planning must be accompanied by a wider range of social policy measures and strong cross-sectoral engagement. We also caution that the unique geographical and political context of Yubari mean its model may not be directly replicable in other contexts.     

Immediate behavioural responses to earthquakes in Christchurch,New Zealand,and Hitachi,Japan

This study examines people's immediate responses to earthquakes in Christchurch, New Zealand, and Hitachi, Japan. Data collected from 257 respondents in Christchurch and 332 respondents in Hitachi revealed notable similarities between the two cities in people's emotional reactions, risk perceptions, and immediate protective actions during the events. Respondents' physical, household, and social contexts were quite similar, but Hitachi residents reported somewhat higher levels of emotional reaction and risk perception than did Christchurch residents. Contrary to the recommendations of emergency officials, the most frequent response of residents in both cities was to freeze. Christchurch residents were more likely than Hitachi residents to drop to the ground and take cover, whereas Hitachi residents were more likely than Christchurch residents to evacuate immediately the building in which they were situated. There were relatively small correlations between immediate behavioural responses and demographic characteristics, earthquake experience, and physical, social, or household context.     

COMPARATIVE STUDY OF OPTIMIZATION TECHNIQUES FOR IRRIGATION PROJECT PLANNING1

ABSTRACT: This study presents three optimization techniques for on‐farm irrigation scheduling in irrigation project planning: namely the genetic algorithm, simulated annealing and iterative improvement methods. The three techniques are applied to planning a 394.6 ha irrigation project in the town of Delta, Utah, for optimizing economic profits, simulating water demand, and estimating the crop area percentages with specific water supply and planted area constraints. The comparative optimization results for the 394.6 ha irrigated project from the genetic algorithm, simulated annealing, and iterative improvement methods are as follows: (1) the seasonal maximum net benefits are $113,826, $111,494, and $105,444 per season, respectively; and (2) the seasonal water demands are 3.03*10³ m³, 3.0*10³ m³, and 2.92*10³ m³ per season, respectively. This study also determined the most suitable four parameters of the genetic algorithm method for the Delta irrigated project to be: (1) the number of generations equals 800, (2) population size equals 50, (3) probability of crossover equals 0.6, and (4) probability of mutation equals 0.02. Meanwhile, the most suitable three parameters of simulated annealing method for the Delta irrigated project are: (1) initial temperature equals 1,000, (2) number of moves equal 90, and (3) cooling rate equals 0.95.