Radiosynthesis of perfluorooctanesulfonate (PFOS) and perfluorobutanesulfonate (PFBS), including solubility, partition and adhesion studies

Here, we describe for the first time the synthesis of [³⁵S] PFOS and [³⁵S] PFBS with sulfur-35 enriched sulfur dioxide as the radiolabelled reagent, resulting in 2.5 and 2.3 mCi of product, respectively. Basic information concerning the physicochemical properties of perfluorooctanesulfonate (PFOS), perfluorobutanesulfonate (PFBS) and perfluorooctanoic acid (PFOA) are still limited. Hence, we utilized these radiolabelled perfluoroalkanesulfonates (PFSAs), as well as carbon-14 labelled perfluorooctanoic acid ([¹⁴C] PFOA) to determine some basic characteristics of physiological and experimental significance.The solubility of PFOS in buffered aqueous solutions at pH 7.4 was found to be severely reduced in the presence of potassium and sodium ions, which, however, did not reduce the solubility of PFOA or PFBS. PFOS was found to adhere to a small extent to polypropylene and polystyrene, whereas no such adhesion of PFOA or PFBS was detected. The extents of adhesion of PFOS and PFOA to glass were found to be 20% and 10%, respectively. For the first time, the partition coefficients for PFOS, PFBS and PFOA between n-octanol and water were determined experimentally, to be −0.7, −0.3, and 1.4, respectively, reflecting the difference in the amphiphilic natures of these molecules.     

Salt river project's participation in Arizona's bald eagle conservation efforts

Bald eagle (Haliaeetus leucocephalus) conservation in Arizona, USA, is a prime example of a successful, cooperative environmental management effort. The Salt River Project (SRP) is an active participant in the statewide bald eagle management activities. This paper summarizes the major components of the statewide program and highlights SRP's participation in these efforts. The Southwestern Bald Eagle Management Committee (SWBEMC) was formed as a means of coordinating interagency projects. Chaired by the Arizona Game and Fish Department (AGFD), the SWBEMC is comprised of 15 state, federal, tribal, and private agencies. Together, these agencies sponsor the Nest Watch Program, a unique and effective program dedicated to the study, conservation, and recovery of bald eagles in the southwest. Other significant components of the bald eagle management program include nest monitoring, nest search activities, winter counts, and demography studies.