基于中俄铁锰分析差异探讨地表水重金属监测样品保存与前处理方法

本文通过中俄两国在水质铁锰测定结果的差异问题,对采样后不同的保存和预处理方法对测定结果的影响进行了实验研究。研究指出了目前对重金属分析测试结果与《地表水环境质量标准》中标准限值的涵义之间存在的问题,并提出了相应解决问题的方式方法。     

盐城蟒蛇河饮用水源原水水质及盐龙湖工程水质净化效果评价

蟒蛇河是盐城市区主要的地表饮用水源地,其水质通常在Ⅳ~Ⅴ类标准。为改善原水水质,中国首个平原上开挖的饮用水源生态净化湖——盐龙湖于2012年6月建成启用。通过水质监测,分析了近年来蟒蛇河原水水质及其污染特征,并对盐龙湖工程水质的净化效果进行了评价。研究表明:(1)蟒蛇河原水在春、秋、冬季水质主要指标基本能满足《地表水环境质量标准》(GB3838-2002)Ⅲ类标准,但夏季水质相对较差;(2)蟒蛇河原水呈现出典型的有机污染特征,营养盐类多是以有机形态存在,但TN与TP的主要污染来源并不一致,在不同季节原水污染特性存在波动规律;(3)近年来蟒蛇河原水中有机物及营养盐浓度有升高趋势;(4)盐龙湖工程水质净化效果在夏季最佳,春、秋季次之,冬季则一般;(5)近一年来,盐龙湖工程累计削减原水高锰酸盐指数、氨氮、TN、TP、SS的量分别达到56.6、35.6、59.8、8.9、1 000.0t(干质量)。     

基于有序Probit模型的铁路险兆事件影响因素识别研究*

为识别铁路险兆事件的影响因素,以宜春车务段2017年9月—2017年10月共1 870条数据为样本,以铁路险兆事件等级为因变量,事件原因、环境特征和事件特征为自变量建立有序Probit模型,探究人、设备、环境和管理因素对铁路险兆事件严重影响程度。研究结果表明:设备设施未按规定防护是影响严重性险兆事件发生的主要因素;与其他人为因素相比,未执行相关作业规定对增加险兆事件严重程度有显著作用。研究结果可为铁路管理部门实现事故预控提供依据。     

The effect of two different biochars on remediation of Cd-contaminated soil and Cd uptake by Lolium perenne

Biochar can be widely used to reduce the bioavailability of heavy metals in contaminated soil because of its adsorption capacity. But there are few studies about the effects of biochar on cadmium uptake by plants in soil contaminated with cadmium (Cd). Therefore, an incubation experiment was used to investigate the effects of rice straw biochar (RSBC) and coconut shell biochar (CSBC) on Cd immobilization in contaminated soil and, subsequently, Cd uptake by Lolium perenne. The results showed that the microbial counts and soil enzyme activities were significantly increased by biochar in Cd-contaminated soil, which were consistent with the decrease of the bioavailability of Cd by biochar. HOAc-extractable Cd in soil decreased by 11.3–22.6% in treatments with 5% RSBC and by 7.2–17.1% in treatments with 5% CSBC, respectively, compared to controls. The content of available Cd in biochar treatments was significantly lower than in controls, and these differences were more obvious in treatment groups with 5% biochar. The Cd concentration in L. perenne reduced by 4.47–26.13% with biochar. However, the biomass of L. perenne increased by 1.35–2.38 times after adding biochar amendments. So, Cd uptake by whole L. perenne was augmented by RSBC and CSBC. Accordingly, this work suggests that RSBC and CSBC have the potential to be used as a useful aided phytoremediation technology in Cd-contaminated soil.

     

污水处理厂中污水臭气除臭技术的研究与应用

污水处理厂中恶臭气体污染已成为环境污染的重大问题,除臭技术的研究与应用已经成为一个热点。通过介绍处理厂中污水臭气的来源、成分以及对人体的危害,详细分析了各种除臭技术的发展历程,并比较了各自的优缺点,展望了其发展的趋势与应用领域。通过各种除臭技术的比选,最终确定污水处理厂臭气除臭形式采用生物滤池法,最终满足污染物排放标准的要求。展望了今后的研究方向是寻找研究新型的、高效的、环保的除臭技术。     

沉淀池中异重流对混凝沉淀效果影响的试验

沉淀池中异重流会给混凝沉淀带来不良影响,为了提高混凝沉淀效果,防止异重流对絮凝池的间接影响,本研究对平流沉淀池中异重流的形成原因进行讨论,并对异重流的特性进行试验研究与分析。研究表明:控制水流流型的稳定性是对沉淀池中异重流进行控制的主要措施。     

Nanoscale zero-valent metals: a review of synthesis,characterization, and applications to environmental remediation

Engineered nanoscale zero-valent metals (NZVMs) representing the forefront of technologies have been considered as promising materials for environmental remediation and antimicrobial effect, due to their high reducibility and strong adsorption capability. This review is focused on the methodology for synthesis of bare NZVMs, supported NZVMs, modified NZVMs, and bimetallic systems with both traditional and green methods. Recent studies have demonstrated that self-assembly methods can play an important role for obtaining ordered, controllable, and tunable NZVMs. In addition to common characterization methods, the state-of-the-art methods have been developed to obtain the properties of NZVMs (e.g., granularity, size distribution, specific surface area, shape, crystal form, and chemical bond) with the resolution down to subnanometer scale. These methods include spherical aberration corrected scanning transmission electron microscopy (Cs-corrected STEM), electron energy-loss spectroscopy (EELS), and near edge X-ray absorption fine structure (NEXAFS). A growing body of experimental data has proven that nanoscale zero-valent iron (NZVI) is highly effective and versatile. This article discusses the applications of NZVMs to treatment of heavy metals, halogenated organic compounds, polycyclic aromatic hydrocarbons, nutrients, radioelements, and microorganisms, using both ex situ and in situ methods. Furthermore, this paper briefly describes the ecotoxicological effects for NZVMs and the research prospects related to their synthesis, modification, characterization, and applications.     

基于AHP的有机氟化物泄漏事故应急能力评估

基于氟化物泄漏事故特点,从应急组织体系、应急救援队伍、应急物资装备、应急预案、应急演练和教育培训等6个方面,建立了氟化物泄漏事故应急能力评估指标体系,并采用层次分析法(AHP)对其进行分析。基于各项指标权重结果,对影响氟化物泄漏事故的关键因素提出了针对性建议,为提高其应急能力提供了基础支撑。     

环境税税制设计的探讨

结合国外经验与中国国情，论述了环境税的设计原则，。探讨了在我国环境税时，税制三大要素：税种，税基和税率的制定及实施方法。     

菹草生理特性对底质物理性质变化的响应

沉水植物的恢复是水生态修复的关键,但在光照、溶解氧以及水力条件等满足的情况下,不同性质的底质会影响沉水植物的生长。以菹草（Potrmogeton crispus）为研究对象,通过向过适宜营养条件下的底泥中添加原底泥30%、70%、100%体积量的沙,以改变底质的物理性质,在30 d内测定菹草的过氧化物酶（POD）、过氧化氢酶（CAT）、植物叶绿素、植物干物率、植物根系活力的变化情况。结果表明,几种处理试验组中,掺加原底泥体积70%沙组的CAT活性响应得较慢,在第20天时才达最大;全底泥和掺加原底泥体积30%沙的2个试验组10 d后POD活性持续上升,而掺加原底泥体积70%和100%组对POD的响应则几乎停止;各试验组植物叶绿素整体呈现下降趋势,但掺加原底泥体积100%沙组中植物叶绿素最高。植物干物率在20 d后都呈现下降的趋势。研究表明,若只通过加沙改变河道底质性质,则加原底泥体积70%～100%的沙对菹草的生长相对最有利。