Degradation of bisphenol A in aqueous solution by persulfate activated with ferrous ion

Degradation of bisphenol A (BPA) in aqueous solution was studied with high-efficiency sulfate radical (SO₄ ^?·), which was generated by the activation of persulfate (S₂O₈ ^2?) with ferrous ion (Fe²⁺). S₂O₈ ^2? was activated by Fe²⁺ to produce SO₄ ^?·, and iron powder (Fe⁰) was used as a slow-releasing source of dissolved Fe²⁺. The major oxidation products of BPA were determined by liquid chromatography-mass spectrometer. The mineralization efficiency of BPA was monitored by total organic carbon (TOC) analyzer. BPA removal efficiency was improved by the increase of initial S₂O₈ ^2? or Fe²⁺ concentrations and then decreased with excess Fe²⁺ concentration. The adding mode of Fe²⁺ had significant impact on BPA degradation and mineralization. BPA removal rates increased from 49 to 97 % with sequential addition of Fe²⁺, while complete degradation was observed with continuous diffusion of Fe²⁺, and the latter achieved higher TOC removal rate. When Fe⁰ was employed as a slow-releasing source of dissolved Fe²⁺, 100 % of BPA degradation efficiency was achieved, and the highest removal rate of TOC (85 %) was obtained within 2 h. In the Fe⁰–S₂O₈ ^2? system, Fe⁰ as the activator of S₂O₈ ^2? could offer sustainable oxidation for BPA, and higher TOC removal rate was achieved. It was proved that Fe⁰–S₂O₈ ^2? system has perspective for future works.     

垂直撞击下混凝土框架结构振动响应及其影响因素分析

采用ABAQUS有限元分析软件建立了三层三跨混凝土框架结构,研究了撞击位置、撞击质量和初始撞击速度对框架结构动力响应的影响。研究结果表明:撞击力峰值受初始撞击速度影响最大,其次是撞击质量,而撞击位置影响最小;梁跨中最大挠度和最终挠度受初始撞击速度的影响较大,而撞击位置和撞击质量对其影响较小;当撞击力作用于同层边跨梁时,相邻梁柱节点混凝土拉伸损伤较为严重,而当撞击力作用于同层中跨梁时,整个框架梁柱节点混凝土拉伸损伤相对较轻,但损伤分布相对较广;随着撞击质量和初始撞击速度的增大,整个框架结构损伤越来越严重,框架梁和梁柱节点是主要耗能部位。     

Characterization of a novel marine aerobic denitrifier Vibrio spp. AD2 for efficient nitrate reduction without nitrite accumulation

Environmental Science and Pollution Research - Aerobic denitrifiers have the potential to reduce nitrate in polluted water under aerobic conditions. A salt-tolerant aerobic denitrifier was newly...     

试论我国陆地再生能源资源及其特征

在世界矿物能源资源日趋减少的今天,再生能源资源引起人们广泛的兴趣,特别是陆地再生能源资源更是如此。本文对我国陆地再生能源资源——太阳能、风能、水能、生物质能——中的前两种能源资源进行了分区及分省计算,并依据全国已有的调查及普查资料,对后两种源能资源进行了分省及分区统计,在此基础上又对全国陆地再生能源资源的数量、分布及特征进行了对比分析,并从宏观上提出了开发利用我国陆地再生能源资源的建议和设想。     

球衣菌吸附重金属Hg2+的理化条件及其机理研究

采用球衣菌(Sphaerotglus natans)FQ32为生物吸附剂,研究了初始离子浓度、吸附剂用量、菌龄、pH值、温度和吸附时间等理化因素对其吸附重金属Hg2 的影响,并进一步研究了吸附机理.结果表明,球衣菌在Hg2 浓度为16 mg·L-1、吸附剂用量0.4g·L-1、菌龄16h、pH 7、温度30℃、吸附时间90 rmin时的优化条件下,对Hg2 的吸附量为72.86 mg·g-1;该吸附过程是一个快速的过程,在吸附5 min时,吸附量达总吸附量的74.10%,90 min达到吸附平衡;此过程符Langmuir等温方程.等温模型、透射电镜观察和红外光谱分析显示,菌体细胞表面的活性基团与Hg2 的络合反应是球衣菌吸附Hg2 的主要机理.     

丙烯腈、醋酸乙烯酯罐区火险分析及对策

对丙烯腈、醋酸乙酯罐系统危险性及罐区泄漏潜在危险性进行了系统分析。并对丙烯腈、醋酸乙烯酯罐区的防火防爆提出了相应的对策,对泡沫消防设备及可燃气体检测器灭火系统的可行性和实用性进行了重点介绍和探讨。     

Research on polyhydroxyalkanoates and glycogen transformations: Key aspects to biologic nitrogen and phosphorus removal in low dissolved oxygen systems

In this paper, a study was conducted on the effect of polyhydroxyalkanoates (PHA) and glycogen transformations on biologic nitrogen and phosphorus removal in low dissolved oxygen (DO) systems. Two laboratory-scale sequencing batch reactors (SBR1 and SBR2) were operating with anaerobic/aerobic (low DO, 0.15–0.45 mg·L^-1) configurations, which cultured a propionic to acetic acid ratio (molar carbon ratio) of 1.0 and 2.0, respectively. Fewer poly-3-hydroxybutyrate (PHB), total PHA, and glycogen transformations were observed with the increase of propionic/acetic acid, along with more poly-3-hydroxyvalerate (PHV) and poly-3-hydroxy-2-methyvalerate (PH2MV) shifts. The total nitrogen (TN) removal efficiency was 68% and 82% in SBR1 and SBR2, respectively. In the two SBRs, the soluble ortho-phosphate (SOP) removal efficiency was 94% and 99%, and the average sludge polyphosphate (poly-P) content (g·g-MLVSS^-1) was 8.3% and 10.2%, respectively. Thus, the propionic to acetic acid ratio of the influent greatly influenced the PHA form and quantity, glycogen transformation, and poly-P contained in activated sludge and further determined TN and SOP removal efficiency. Moreover, significant correlations between the SOP removal rate and the (PHV+ PH2MV)/PHA ratio were observed (R²>0.99). Accordingly, PHA and glycogen transformations should be taken into account as key components for optimizing anaerobic/aerobic (low DO) biologic nitrogen and phosphorus removal systems.     

乐清湾海域生物体内多氯联苯的分布特征

以台州(乐清湾)为例,研究了乐清湾海域生物体内多氯联苯(PCBs)的分布,其中以鱼、贝类和虾为主要实验对象,分析了多氯联苯的来源、浓度及各种影响因素。结果表明,鱼肉中∑PCBs 的残留含量为8.61~23.06ng/g,贝类中∑PCBs 的残留含量为11.77~38.04ng/g,对虾中∑PCBs的残留含量为0.38~11.19ng/g。近海生物体内多氯联苯的来源与当地工业排污、航运、PCBs废旧设施非法处置或封存不当等一系列因素有关。     

近断层地震作用下考虑P-Δ效应的混凝土结构响应分析*

近断层地震动具有更大的水平地震和竖向地震作用,从而改变结构的p-Δ效应。首先,利用537组近断层地震动,统计分析了近断层地震动的反应谱特性和竖向与水平向加速度峰值比,考察了近断层地震动的特性。其次,分别对近断层脉冲地震动、近断层非脉冲地震动和远断层地震动作用下混凝土结构的弹塑性反应进行了计算,分析了p-Δ效应的影响规律。最后,同时输入竖向和水平向地震动,考虑竖向地震动对结构p-Δ效应的影响。结果表明:近断层地震动有较大的水平向和竖向反应谱值,在近断层区域,将竖向地震动作用简单的按照现行规范中的取水平地震作用的2/3进行考虑是偏于不安全的;加速度峰值一致的前提下,结构在近断层脉冲地震作用下具有较大的响应,但p-Δ效应对结构的响应影响不明显,幅度大多未超过10%;由于地震动的随机性及复杂性,竖向地震动引起的惯性力不一定会增大结构的反应,也有可能会减小结构的反应。     

进口废物管理目录调整原则和方法及对策建议研究

简要介绍了我国固体废物进口情况,以及进口废物管理目录在进口固体废物管理方面的重要作用。详细阐述了进口废物管理目录动态调整的发展过程,分析了现行进口废物管理目录中存在的问题,提出了进口废物管理目录动态调整的原则、方法和对策建议,为今后我国动态调整进口废物管理目录提供参考。