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Shah DB Phadke AV Kocher WM 《Journal of the Air & Waste Management Association (1995)》1995,45(3):150-155
Solvent extraction is used to reduce lead concentrations from millpond wastewater solids, a type of foundry process waste. Toluene and toluene mixed with di-(2-ethyl-hexyl) phosphoric acid (HDEHP) have been tried as leaching solvents. Toluene is ineffective as a solvent in extracting lead, but the toluene-HDEHP mixture effectively removes lead from solid foundry waste. The effects of the HDEHP concentration, the contact time, and the amount of solvent used on lead extraction have been investigated. The mass transfer process is rapid: contact time of 1/2 hour has been found to be sufficient to accomplish the leaching process. The concentration of HDEHP significantly impacts lead removal. The optimum concentration of HDEHP is determined to range from 0.05 to 0.1 mol/l. The Toxicity Characteristic Leaching Procedure (TCLP) test of the treated samples gives leachable lead in much lower quantities than those found in the untreated samples. Thus the solvent extraction process appears to be an effective method to significantly reduce the lead content of millpond wastewater solids. 相似文献
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Joshi SD Pandya GH Phadke KM Tajne DS Jain AK Gajrani CP Yennawar PK 《Environmental pollution (Barking, Essex : 1987)》1989,58(2-3):87-96
A chemical analysis of suspended particulate matter (SPM) collected near the world famous Taj Mahal monument at Agra has been carried out. SPM samples collected on glass fibre filters were analysed for water-soluble sulphate, nitrate, chloride and ammonium ions. The data were derived from over 200 samples (each of 24 h), collected continuously during the winter periods (October through to March) of 1984-1985 and 1985-1986. The SO(4)(2-) and NO(3)(-) components are acidic in nature causing corrosion and effects on visibility, and so were studied in more detail. Mean values for SO(4)(2-) and NO(3)(-) derived from two-year data are 7.2 microg m(-3) and 8.2 microg m(-3), respectively. The SO(4)(2-)/SO(2) and NO(3)(-)/NO(2) ratiosobserved indicate faster conversion of SO(2) to SO(4)(2-) than NO(2) to NO(3)(-), the maximum levels being in January. Thus, both SO(4)(2-) and NO(3)(-) results appear to offer more promising indices of air quality than do SPM data alone. 相似文献
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G.C. Tiao M.S. Phadke G. E. P. Box 《Journal of the Air & Waste Management Association (1995)》2013,63(5):485-490
This paper presents (i) an empirico-mechanistic model which describes the dependence of CO, NO, NO2, and O3 on total hydrocarbons, traffic, wind speed, inversion base height, and solar radiation as well as the photochemical reactions associated with these pollutants; (ii) a detailed study of weather conditions when the instantaneous daily maximum O3 exceeds the L.A. County alert level of 50 pphm; and (iii) regression models for the prediction of daily maximum O3 values. 相似文献
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