Experimental study on drying and moisture re-adsorption kinetics of an Indonesian low rank coal

The drying kinetics of an Indonesian low rank coal and moisture re-adsorption of the dried coal using a thermobalance and a climatic chamber were investigated. Results show that the drying kinetics is best represented by two stages, as a constatnt rate stage followed by a rate decay stage. The water removal rate is dependent mainly on drying temperature and coal sample size. The apparent activation energy (E) of drying was 26.58 kJ/mol. A rate equation for drying of the coal was obtained from the experimental data. The moisture re-adsorption rate was dependent on drying temperature, coal particle size, and relative humidity of the atmosphere.     

Multi-GCM projections of future drought and climate variability indicators for the Mediterranean region

Future climate conditions for the Mediterranean region based on an ensemble of 16 Global Climate Models are expressed and mapped using three approaches, giving special attention to the intermodel uncertainty. (1) The scenarios of mean seasonal temperature and precipitation agree with the projections published previously by other authors. The results show an increase in temperature in all seasons and for all parts of the Mediterranean with good intermodel agreement. Precipitation is projected to decrease in all parts and all seasons (most significantly in summer) except for the northernmost parts in winter. The intermodel agreement for the precipitation changes is lower than for temperature. (2) Changes in drought conditions are represented using the Palmer Drought Severity Index and its intermediate Z-index product. The results indicate a significant decrease in soil moisture in all seasons, with the most significant decrease occurring in summer. The displayed changes exhibit high intermodel agreement. (3) The climate change scenarios are defined in terms of the changes in parameters of the stochastic daily weather generator calibrated with the modeled daily data; the emphasis is put on the parameters, which affect the diurnal and interdiurnal variability in weather series. These scenarios indicate a trend toward more extreme weather in the Mediterranean. Temperature maxima will increase not only because of an overall rise in temperature means, but partly (in some areas) because of increases in temperature variability and daily temperature range. Increased mean daily precipitation sums on wet days occurring in some seasons, and some parts of the Mediterranean may imply higher daily precipitation extremes, and decreased probability of wet day occurrence will imply longer drought spells all across the Mediterranean.     

Drinking water treatment is not associated with an observed increase in neural tube defects in mice

Disinfection by-products (DBPs) arise when natural organic matter in source water reacts with disinfectants used in the water treatment process. Studies have suggested an association between DBPs and birth defects. Neural tube defects (NTDs) in embryos of untreated control mice were first observed in-house in May 2006 and have continued to date. The source of the NTD-inducing agent was previously determined to be a component of drinking water. Tap water samples from a variety of sources were analyzed for trihalomethanes (THMs) to determine if they were causing the malformations. NTDs were observed in CD-1 mice provided with treated and untreated surface water. Occurrence of NTDs varied by water source and treatment regimens. THMs were detected in tap water derived from surface water but not detected in tap water derived from a groundwater source. THMs were absent in untreated river water and laboratory purified waters, yet the percentage of NTDs in untreated river water were similar to the treated water counterpart. These findings indicate that THMs were not the primary cause of NTDs in the mice since the occurrence of NTDs was unrelated to drinking water disinfection.     

Measuring the effectiveness of landscape approaches to conservation and development

Landscape approaches attempt to achieve balance amongst multiple goals over long time periods and to adapt to changing conditions. We review project reports and the literature on integrated landscape approaches, and found a lack of documented studies of their long-term effectiveness. The combination of multiple and potentially changing goals presents problems for the conventional measures of impact. We propose more critical use of theories of change and measures of process and progress to complement the conventional impact assessments. Theories of change make the links between project deliverables, outputs, outcomes, and impacts explicit, and allow a full exploration of the landscape context. Landscape approaches are long-term engagements, but short-term process metrics are needed to confirm that progress is being made in negotiation of goals, meaningful stakeholder engagement, existence of connections to policy processes, and effectiveness of governance. Long-term impact metrics are needed to assess progress on achieving landscapes that deliver multiple societal benefits, including conservation, production, and livelihood benefits. Generic criteria for process are proposed, but impact metrics will be highly situation specific and must be derived from an effective process and a credible theory of change.     

Improving dialogue among researchers,local and indigenous peoples and decision-makers to address issues of climate change in the North

Ambio - The Circumpolar North has been changing rapidly within the last decades, and the socioeconomic systems of the Eurasian Arctic and Siberia in particular have displayed the most dramatic...     

(Dis)connected communities and sustainable place-making

Why, despite a recent surge in the UK in “sustainable communities” policy discourse, do so many community-led sustainability initiatives remain fragmented, marginal and disconnected from local government strategies? How can community- and government-led sustainability initiatives be better integrated such that they add significantly to a denser matrix and cluster of sustainable places? These questions, we argue, lie at the heart of current sustainable place-making debates. With particular reference to two spatial scales of analysis and action, the small town of Stroud, England and the city of Cardiff, Wales, we explore the twin processes of disconnection and connection between community sustainability activists and local state actors. We conclude that whilst there will always remain a need for community groups to protect the freedom which comes from acting independently, for community activists and policy-makers alike, there are nevertheless a series of mutual benefits to be had from co-production. However, in setting out these benefits we also emphasise the dual need for local government to play a much more nuanced, integrative and facilitatory role, in addition to, but separate from, its more traditional regulatory role.     

The electron density distribution in pyridinium and bipyridylium compounds and its relevance to their adsorption by expanding lattice clays

Abstract

Charge distributions in 1, 1'‐ethylene‐2, 2'‐bipyridylium (diquat), 1,1'‐dimethyl‐4,4'‐bipyridylium (paraquat) and 1‐methylpyridinium organocations were calculated by a Complete Neglect of Differential Overlap semi‐empirical quantum mechanical procedure. The data show that the positive charges in the organocations are distributed around the molecules and are greatest in the positions ortho and para to the heterocyclic nitrogen atoms. Earlier interpretations of the mechanisms of adsorption of paraquat and diquat by soils and clays assumed that the charges were located in the heterocyclic nitrogen atoms. Here some consideration is given to the influence of the charge delocalizations on the processes of adsorption by montmorillonite and vermiculite clay preparations.     

Screening Capsicum chinense fruits for heavy metals bioaccumulation

Elevated concentrations of heavy metals in edible plants could expose consumers to excessive levels of potentially hazardous chemicals. Sixty-three accessions (genotypes) of Capsicum chinense Jacq, collected from 8 countries of origin were grown in a silty-loam soil under field conditions. At maturity, fruits were collected and analyzed for seven heavy metals (Cd, Cr, Ni, Pb, Zn, Cu, and Mo) concentrations. The main objectives of this investigation were: 1) to determine the concentrations of seven heavy metals in the soil and monitor their accumulation in mature fruits, 2) to categorize the pepper accessions as low or high heavy metal accumulators, and 3) to determine if heavy metal content of the pepper fruit was lower than the permitted limits. Concentrations and relative proportions of heavy metals in pepper fruits of C. chinense varied among accessions. Fruits of Plant Introduction (PI) 355820 accumulated significant concentrations of Cd (0.47 μ g g^?1dry fruit). PI-260522 accumulated the highest concentration of Pb (2.12 μ g g^?1 dry fruit) among the 63 accessions tested. This accession (PI-260522) contained about twice the Pb limit on a fresh weight basis. Among the 63 accessions analyzed, PI-238051 contained the highest levels of Ni (17.2 μ g g^?1). We concluded that high accumulator genotypes may be useful for phytoremediation, while, low accumulator accessions might be appropriate selections for growing on Cd-, Pb-, or Ni-contaminated soils to prevent potential human exposure to heavy metals and health hazards through the food chain.