Calcite-seeded crystallization of calcium phosphate for phosphorus recovery

For phosphorus recovery from wastewater, the present paper aims at understanding the crystallization of calcium phosphate by using calcites (Juraperle and Coccolith) as seeds from hard water. Synthetic hard water with 60 mgCl(-1) carbonate and 10 mgPl(-1) phosphate was prepared and used in the batch experiments of calcite-seeded crystallization. The solution composition was measured throughout the batch crystallization process, and the corresponding saturation indices with respect to the minerals were calculated with PHREEQC Program. The surface of the calcite seeds was observed and measured with environmental scanning electron microscopy (ESEM), Fourier transform infrared (FTIR) and BET method. The studies show that both calcites are effective seeds for the crystallization of calcium phosphate from hard water; the used calcites are more efficient than the original ones because newly formed crystals with calcium phosphate have covered their surfaces. The studies show that the calcite seeds can be used for phosphorus recovery from hard waters.     

Characterization of indoor dust from Brazil and evaluation of the cytotoxicity in A549 lung cells

Over the past decade, ambient air particulate matter (PM) has been clearly associated with adverse health effects. In Brazil, small and poor communities are exposed to indoor dust derived from both natural sources, identified as blowing soil dust, and anthropogenic particles from mining activities. This study investigates the physicochemical and mineralogical composition of indoor PM₁₀ dust samples collected in Minas Gerais, Brazil, and evaluates its cytotoxicity and inflammatory potential. The mean PM₁₀ mass concentration was 206 μg/m³. The high dust concentration in the interior of the residences is strongly related to blowing soil dust. The chemical and mineralogical compositions were determined by ICP-OES and XRD, and the most prominent minerals were clays, Fe-oxide, quartz, feldspars, Al(hydr)oxides, zeolites, and anatase, containing the transition metals Fe, Cr, V, Ni, Cu, Zn, Ti, and Mn as well as the metalloid As. The indoor dust samples presented a low water solubility of about 6 %. In vitro experiments were carried out with human lung alveolar carcinoma cells (A549) to study the toxicological effects. The influence of the PM₁₀ dust samples on cell viability, intracellular formation of reactive oxygen species (ROS), and release of the pro-inflammatory cytokine IL-8 was analysed. The indoor dust showed little effects on alamarBlue reduction indicating unaltered mitochondrial activity. However, significant cell membrane damage, ROS production, and IL-8 release were detected in dependence of dose and time. This study will support the implementation of mitigation actions in the investigated area in Brazil.     

Socioeconomic indicators and the survival of the tropical rainforest of cross river state of Nigeria

An internal household survey of socioeconomic indicators in the Cross River State forest communities showed that basic infrastructural facilities such as clean water supply, adequate waste disposal system, good roads and electricity are grossly inadequate. There is a total absence of modern family planning practices in the communities, and population is projected to increase by 44.8% between 2000 and 2015 and 85.4% between 2000 and 2025. The study revealed that about 65% of the population of the rainforest communities consists of subsistence farmers and power chain operators, and besides the 19% of the Cross River State Tropical High Forestry (THF) already reported to have been lost to agriculture and plantation between 1972 and 1991, about 9% was lost between 1991 and 2000. An additional 25% of the THF will be lost by 2025, leaving only 470600 hectares (4706 km²). With 84.1% of community members having an annual income less than $300, the survival potential of the Cross River State rainforest in the next fifty years is very low, unless an effective forest management programme is encouraged by government in partnership with all stakeholders.