排序方式: 共有37条查询结果,搜索用时 140 毫秒
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介绍了黄河宁蒙河段近几年突发性水污染事件应急监测基本情况,总结了应急监测的特点、作用,对突发性水污染事件中应急监测中存在的问题进行了重点分析,提出了解决的对策。 相似文献
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用人工驯养的厌氧污泥进行除铀实验,探讨了微生物投加量(VSS)、pH值、U(Ⅵ)初始浓度、外加电子供体和污泥重复利用等对污泥处理U(Ⅵ)的影响,并进行了相关机理分析。实验结果表明,在适当的pH范围内(5.2~6.6),厌氧污泥对铀保持较长时间的高效去除率;当以还原铁粉和无水乙醇作电子供体时,U(Ⅵ)去除率保持在95%以上的时间为未加电子供体时的2倍。U(Ⅵ)去除速度与VSS投加量成正比关系,U(Ⅵ)初始浓度对去除效果的影响不大,厌氧污泥可以长期使用。pH值的影响最关键,其次是外加电子供体。厌氧污泥除U(Ⅵ)机理为氧化还原和吸附的共同作用。 相似文献
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为了在事故发生之前对苯储罐进行风险评价,提出1种基于BP神经网络的泄漏事故风险评价方法,利用该方法构建了苯储罐的风险评价模型,并对模型进行了训练及验证。研究结果表明:BP神经网络成功完成了建模任务,且模型训练结果较好,可利用基于BP神经网络所构建的苯泄漏事故风险评价模型对苯储罐发生泄漏事故的风险进行评价。 相似文献
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Song Qiulai Zhu Jie Gong Zhenping Feng Yanjiang Wang Qi Sun Yu Zeng Xiannan Lai Yongcai 《Environmental science and pollution research international》2021,28(39):54792-54801
Environmental Science and Pollution Research - Inappropriate farm management practices can lead to increased agricultural inputs and changes in atmospheric greenhouse gas (GHG) emissions, impacting... 相似文献
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Rod-like, hexagonal and fiber-like SBA-15 mesoporous silicas were synthesized to support MnO_x for toluene oxidation. This study showed that the morphology of the supports greatly influenced the catalytic activity in toluene oxidation. MnO_x supported on rod-like SBA-15(R-SBA-15) displayed the best catalytic activity and the conversion at 230°C reached more than 90%, which was higher than the other two catalysts. MnO_x species consisted of coexisting MnO_2 and Mn_2O_3 on the three kinds of SBA-15 samples. Large amounts of Mn_2O_3 species were formed on the surface and high oxygen mobility was obtained on MnO_x supported on R-SBA-15, according to the H_2 temperature programmed reduction(H_2-TPR)and X-ray photoelectron spectroscopy(XPS) results. The Mn/R-SBA-15 catalyst with greater amounts of Mn_2O_3 species possessed a large amount of surface lattice oxygen, which accelerated the catalytic reaction rate. Therefore, the surface lattice oxygen and high oxygen mobility were critical factors on the catalytic activity of the Mn/R-SBA-15 catalyst. 相似文献
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Herein, Na+ and Ca2+ are introduced to MnO2 through cation-exchange method. The presence of Na+ and Ca2+ significantly enhance the catalytic activity of MnO2 in toluene oxidation. Among them, the Ca-MnO2 catalyst exhibits the best catalytic activity (T50 = 194°C, T90 = 215°C, Ea = 57.2 kJ/mol, reaction rate 8.40 × 10?10 mol/(sec?m2) at 210°C. T50 and T90: the temperature of 50% and 90% toluene conversion; Ea: apparent activation energy) and possess high tolerance against 2.0 vol.% water vapor. Results reveal that the increased acidic sites of the MnO2 sample can enhance the adsorption of gaseous toluene, and the mobility of oxygen species and the content of reactive oxygen species in the catalyst are significantly improved due to the formed oxygen vacancy. Thus these two factors result in excellent catalytic performance for toluene oxidation combining with the weak CO2 adsorption ability. 相似文献
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SO2在Co—Mo/AC催化剂上的还原 总被引:5,自引:1,他引:4
本文研究了活性焦(AC)担载Co-Mo催化剂对SO2还原的催化性能。考查了催化剂不同的预处理方法,H2/SO2摩尔比和还原温度对还原过程硫产率的影响,并就硫化后的Co-Mo和活性焦在催化床不同的构成对硫产率的影响进行了研究。结果表明,经硫化后的催化剂在SO2+2H2→S+2H2O反应有较高的催化活性,在最佳反应温度300℃,H/SO摩尔比为3,空速6000L;kg^-1.h^-1条件下,生成硫的产 相似文献
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铁催化聚丙烯腈脱氮的研究 总被引:2,自引:0,他引:2
应用热天平研究了载铁聚丙烯腈的脱氮碳化行为,负载铁对PAN的稳定化和脱氮碳化均具有显著的催化作用,并在580-760℃范围内明显增加了N2形成速率。XPS和XRD对碳化过程中铁和氮化学形态变化的研究结果表明,铁催化反应机理可能是负载铁与吡啶氮作用形成中间体铁氮化物,后者进而分解释放出N2。 相似文献
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二种高硫煤中硫氮化学形态的研究 总被引:2,自引:0,他引:2
利用XPS技术研究了贵定煤和西班牙Mequienza煤中硫和氮化学形态的分布,并结合硫K-边XANES和Mossbauer谱着重考察贵定煤中硫化学形态。结果表明,贵定煤中含硫化合物主要以噻吩形态存在,其次为有机硫化物;而Mequienza煤中以有机硫化物含量最大,噻吩硫次之,有关含氮化合物,Mequienza煤以吡咯和吡啶氮为主,但在贵定煤中观察到较大浓度的氧化氮化合物。 相似文献