The effects of the mechanical–chemical stabilization process for municipal solid waste incinerator fly ash on the chemical reactions in cement paste

A water extraction process can remove the soluble salts present in municipal solid waste incinerator (MSWI) fly ash, which will help to increase the stability of the synthetic materials produced from the MSWI fly ash. A milling process can be used to stabilize the heavy metals found in the extracted MSWI fly ash (EA) leading to the formation of a non-hazardous material. This milled extracted MSWI fly ash (MEA) was added to an ordinary Portland cement (OPC) paste to induce pozzolanic reactions. The experimental parameters included the milling time (96 h), water to binder ratios (0.38, 0.45, and 0.55), and curing time (1, 3, 7 and 28 days). The analysis procedures included inductively coupled plasma atomic emission spectroscopy (ICP/AES), BET, mercury intrusion porosimetry (MIP), X-ray diffraction (XRD), and nuclear magnetic resonance (NMR) imaging. The results of the analyses indicate that the milling process helped to stabilize the heavy metals in the MEA, with an increase in the specific surface area of about 50 times over that of OPC. The addition of the MEA to the OPC paste decreased the amount of Ca(OH)₂ and led to the generation of calcium–silicate–hydrates (C–S–H) which in turned increased the amount of gel pores and middle sized pores in the cement. Furthermore, a comparison shows an increase in the early and later strength over that of OPC paste without the addition of the milled extracted ash. In other words, the milling process could stabilize the heavy metals in the MEA and had an activating effect on the MEA, allowing it to partly substitute OPC in OPC paste.     

Using micro deep drawing with ironing stages to form stainless steel 304 micro cups

The needs of stainless steel 304 micro cups have been increasing tremendously due to the trend of miniaturization in medical and electronic devices, etc. For application purpose, it is highly desired to have stainless steel micro cups with high CH/OD (cup height/outer diameter) ratios. Due to the constraints of the limit draw ratio (LDR) of stainless steel 304 sheets in micro deep drawing, forming a micro cup with high CH/OD ratio at room temperature cannot be achieved by using a single stage deep drawing die. A process consisting of one micro deep drawing and two ironing stages was proposed for achieving this goal; three micro dies were designed, fabricated and used for experimental validation. A series of experiments were conducted by using the stainless steel 304 sheets of 200 μm thickness annealed at four different temperatures to understand the influence of size effects on this process for generating knowledge, know-how and technologies to form high quality stainless steel micro cups with large CH/OD ratio. No lubricant was used in this study. It was proven that the proposed process is a robust process as long as the sheets are annealed at the temperature no less than 900 °C for more than 3 min.     

Identification of pollution of Tapeng Lagoon from neighbouring rivers using multivariate statistical method

This work investigated water samples collected from Tapeng Lagoon and three neighbouring rivers (the Kaoping River, Tungkang River and Lingbeng River) in Taiwan, Republic of China. Canonical discriminant analysis was applied to identify the source of pollution in neighbouring rivers outside Tapeng Lagoon. The two constructed discriminant functions showed a marked contribution to all discriminant variables, and the total nitrogen, algae, dissolved oxygen and total phosphate were combined as the nutrient effect factor. The recognition capacities of the two discriminant functions were 95.6% and 4.4%, respectively. The water quality in the Kaoping River most strongly controlled the water quality in Tapeng Lagoon. Disassembling the oyster frames and fishery boxes had improved the water quality markedly. The methodology and results provide useful information concerning watershed management and may be applicable to other basins with similar properties that are experiencing similar coastal environmental issues.     

Distribution Of Volatile Organic Compounds In Ambient Air Of Kaohsiung, Taiwan

Automobile emissions have created a major hydrocarbon pollution problem in the ambient air of Taiwan. The aim of this study was to determine the volatile organic compounds (VOCs) in the ambient air of Kaohsiung, Taiwan. The spatial distribution, temporal variation, and correlations of VOCs at three study sites, selected based on traffic densities and distances from a freeway, were discussed. Sixty-four hydrocarbons were identified in the ambient air. Among all of the VOC species, acetone, aromatic and aliphatic compounds constituted the major constituents. Higher concentrations of VOCs existed further away from major arteries as compared to those found near the freeway. Therefore, the distance from the freeway may not be a sufficient index for reflecting actual air quality in the study area. Weather conditions, wind speed and direction did not affect the distribution of VOC concentrations in the three study sites. Other factors, such as the height and density of buildings, traffic conditions or commercial activities, might affect the distribution of VOCs.     

ESTIMATION OF OPTIMAL YIELD IN YUN-LIN AREA OF TAIWAN USING DECISION ANALYSIS1

ABSTRACT: Ground water is a vital resource in the Yun-Lin area of Taiwan. A substantial amount is continuously extracted, creating adverse effects such as land subsidence and seawater intrusion. Minimizing these negative impacts depends on regulating the rate of groundwater withdrawal. An optimal yield must be determined to establish a sound water management policy. A wide range of safe yields for Yun-Lin have already been proposed based on constant hydrological and hydrogeological parameters. By extending the results of those investigations, this study presents a decision analysis model. The optimal yield concept is introduced as well. The proposed model incorporates a probability density function for rainfall recharge and a loss function, derived from fluctuations in the ground water table. Through decision analysis, the optimum yield is obtained by minimizing the expected value of the loss function. The optimal yield varies monthly because the probability density function is time dependent. Analysis results suggest that the cumulative optimum yield of ground water in the area is 1.26 × 10⁸ m³/year. If the probability distribution function for rainfall recharge is modified as new precipitation data become available, the above suggested yield may require revision in the future.     

The Impact of Typhoon Morakot on Heavy Metals of Dapeng Bay and Pollution from Neighboring Rivers

This study demonstrates that prior to Typhoon Morakot, the index of heavy metals such as Cd, Pb, and Cr was above moderate pollution levels in Dapeng Bay and the three neighboring rivers. During January 2007, the content of Zn metal in Dapeng Bay and Tungkang River was also above moderate pollution levels, while after the Typhoon Morakot event, all metals were at levels below the criteria for low pollution. This work has demonstrated that the samples collected from Dapeng Bay and the three neighboring river systems displayed individual crowd–distribution phenomena, indicating variability between the heavy metal content of sediments collected from Dapeng Bay and the three neighboring rivers. Understanding the spatial and temporal variability of heavy metal pollutants in the sediments of Dapeng Bay, along with pollution sources from three neighboring rivers, provides useful information in the fields of disaster management, habitat recovery, operative management, as well as ecotourism specification.     

Effect of the milling solution on lead stabilization in municipal solid waste incinerator fly ash during the milling processes

The wet milling process had been found to effectively stabilize lead in fly ash. This study adopts this method and looks at the effect of different milling solutions to improve the efficiency of lead stabilization. Different milling solutions (water, phosphoric acid and ethanol) and different milling times (1, 24, 48 and 96 h) were selected as parameters. Since lead oxide can be identified by XRD in this experiment’s samples, 5% lead oxide was added to the extracted mixed fly ash to make instrumental analysis easier. The experimental results indicate that the effect of stabilization of lead after milling could exceed 96%. During milling with water, considerable lead leached into the water in the initial stage (1 h) of the process, but a stable level was reached as the milling time increased. After milling with ethanol and 0.2 M phosphoric acids, the efficiency could exceed 93% after 1 h of milling time. The results of the sequential extraction procedure (SEP) results show that the residual fraction could be increased from 8.93% to 56.16% when a 0.2 M phosphoric acid solution was used. Clearly the choice of an appropriate milling solution can enhance lead stabilization in the fly ash.     

Allergy from perspective of environmental pollution effects: from an aspect of atopic dermatitis,immune system,and atmospheric hazards—a narrative review of current evidences

Environmental Science and Pollution Research - Environmental pollution has become more diversified in recent years as technologies for urbanization is increasingly more advanced. Several...