Quantification of nitrate leaching from German forest ecosystems by use of a process oriented biogeochemical model

Simulations with the process oriented Forest-DNDC model showed reasonable to good agreement with observations of soil water contents of different soil layers, annual amounts of seepage water and approximated rates of nitrate leaching at 79 sites across Germany. Following site evaluation, Forest-DNDC was coupled to a GIS to assess nitrate leaching from German forest ecosystems for the year 2000. At national scale leaching rates varied in a range of 0–>80 kg NO₃–N ha⁻¹ yr⁻¹ (mean 5.5 kg NO₃–N ha⁻¹ yr⁻¹). A comparison of regional simulations with the results of a nitrate inventory study for Bavaria showed that measured and simulated percentages for different nitrate leaching classes (0–5 kg N ha⁻¹ yr⁻¹:66% vs. 74%, 5–15 kg N ha⁻¹ yr⁻¹:20% vs. 20%, >15 kg N ha⁻¹ yr⁻¹:14% vs. 6%) were in good agreement. Mean nitrate concentrations in seepage water ranged between 0 and 23 mg NO₃–N l⁻¹.     

Can coffee certification schemes increase incomes of smallholder farmers? Evidence from Jinotega,Nicaragua

This paper investigates the impact of Fairtrade and organic certification on household income of smallholder coffee farmers in the Jinotega Municipality of Nicaragua. Using a sample of 233 coffee farming households and employing endogenous switching regression model and propensity score matching method, the results found that Fairtrade and organic certification standards have different effects on the certified farmers; while Fairtrade farmers had experienced yield gains, organic farmers had the price advantage. However, the overall impact of these certification standards on the total household income is found to be statistically not significant. While some of the Fairtrade-certified cooperatives have used the social premium in creating community-level infrastructure, there is a need for more investment. The major constraint the organic-certified farmers face is lack of availability of adequate organic inputs such as manures and organic herbicides.     

A longitudinal study of determinants of perceived employability

Employability is highly important to individuals in coping with job insecurity. Although many employability models have been developed, few studies have tested determinants of employability empirically. This longitudinal study aims to analyze core determinants of perceived employability. These were tested using a sample of 465 employees (time 1) taken from four companies in Switzerland and surveyed at three points in time. In order to include data from all participants, we used multilevel analysis (level 1: time, level 2: person). Results showed that education, support for career and skill development, current level of job‐related skills, and willingness to change jobs were significant predictors of perceived employability. Contrary to our hypotheses, willingness to develop new competencies, opportunity awareness, and self‐presentation skill failed to predict perceived employability. Copyright © 2009 John Wiley & Sons, Ltd.     

Model evaluation of different mechanisms driving freeze–thaw N2O emissions

N₂O emissions from soil contribute significantly to global warming. Pulse emissions of N₂O from soils during freeze-thawing were recently recognized as important atmospheric sources. In this modelling study we explore three different hypotheses for explaining freeze–thaw related N₂O emissions: (1) soil frost or snow cover may reduce gas diffusion and create anaerobic conditions that stimulate N₂O production via denitrification, (2) microbes that die of frost deliver easy decomposable organic carbon and nitrogen to the soil, which stimulates microbial growth and vigorous N₂O production during freeze–thaw, and (3) the enzyme nitrous oxide reductase, which is responsible for the reduction of N₂O to N₂ during denitrification, is more sensitive to low temperatures than other enzymes, so that N₂O becomes the dominating end-product of denitrification at low temperatures. These hypotheses were tested with a biogeochemical model that combines hydrology and physics calculations with a newly developed, parameter-poor biochemistry module. The model was first calibrated with field datasets on soil–atmosphere fluxes of N₂O, NO and CO₂ and soil NO₃ and NH₄ concentrations that were measured in a spruce forest in Southeast Germany in the years 1994–1997. Subsequently, additional model mechanisms were implemented that allow the model to describe the outlined mechanisms potentially driving freeze–thaw N₂O fluxes. After each implementation the model was recalibrated. We were able to mimic dimension and timing of high N₂O emissions when either one of the first two hypotheses were assumed, but found no confirmation for the third. The best model fit was achieved by combining hypothesis one and two, indicating that freeze–thaw N₂O emissions are not mono-causal.     

Lipids and fatty acids as indicators of egg condition,larval feeding and maternal effects in Cape hakes (<Emphasis Type="Italic">Merluccius paradoxus</Emphasis> and <Emphasis Type="Italic">M. capensis</Emphasis>)

Cape hakes, Merluccius paradoxus and M. capensis, are important gadoid fish that are commercially harvested in the Benguela Current system off Namibia and South Africa. The aim of this study was to elucidate the nutritional condition and feeding preferences of their larvae. Hake eggs and larvae were sampled in austral spring of two consecutive years, 2007 and 2008, off the west coast of South Africa. They were identified to species using genetics, and total lipid content and fatty acid (FA) composition were analysed for each individual egg and larva to compare the condition of different early life stages of both hake species. Higher abundances of M. paradoxus eggs and larvae were consistently found compared to M. capensis. In both species, eggs contained wax esters (WE) and had significantly higher lipid content per dry mass than larvae. Lipid content as well as FA composition changed with the developmental stage of larvae. Quantities of essential fatty acid (EFA) increased with feeding of larvae due to dietary lipid incorporation. In 2007, yolk-sac larvae contained significantly lower total lipids than in 2008. It is argued that this was due to reduced lipid transfer by the spawning females to the eggs. These findings indicate that maternal effects are important in determining condition of hake larvae and that this may have an effect on their survival and subsequent recruitment.     

Are “job hoppers” trapped in hedonic treadmills? Effects of career orientations on newcomers' attitude trajectories

Joining a new organization to change jobs is an influential event in an employee's career. Thus, inter-organizational job changes have sparked growing scholarly interest, especially in the temporal dynamics involved in detaching from organizations and adapting to new ones. While it is widely accepted that employees adapt differently to job changes, the influence of employees' career orientations on changes in job attitudes has not yet been considered. This is surprising given that a key difference between self-centered and organization-centered career orientations is a positive attitude toward job changes. Building on hedonic adaptation, we examined how career orientations influence changes in job satisfaction and turnover intention throughout a job change. We compared self-centered and organization-centered employees using random coefficient modeling on two longitudinal data sets with voluntary job changers. Our results illustrate that self-centered career orientations foster a stronger decline in job satisfaction with the new employer, as well as a larger increase in turnover intention, than organization-centered career orientations. In contrast, employees with organization-centered career orientations experienced an upward trend in job satisfaction toward the end of the first year. Our findings offer important implications for research on the determinants of job attitude trajectories when individuals join a new organization.     

Workplace monitoring for volatile organic compounds using thermal desorption-gas chromatography-mass spectrometry

The interest in the identification of volatile organic compounds in the workplace has been a major focus of many National Institute for Occupational Safety and Health (NIOSH) field studies. A primary technique for sampling and analysis of these compounds is summarized by NIOSH Manual of Analytical Methods (NMAM) 2549. This is a screening method that uses a multi-bed sorbent to trap a wide variety of compounds and compound classes. Thermal desorption techniques are used as a first attempt to characterize potential contaminants in a workplace and to determine what future sampling and analyses must be performed. Field examples are provided to show the versatility of thermal desorption methods and techniques. Due to their sensitivity, thermal desorption tube methods are sometimes required in order to measure the workplace concentrations of unusual compounds. In other situations, the exposures are too high or varied to make thermal desorption tubes practical. In these cases, the identification of contaminants with thermal desorption tubes leads to new method developments for the quantification of specific compounds using more conventional solid sorbent-solvent desorption based methods.     

Diagnosis of safety culture in safety management audits

Based on the sociotechnical systems approach, an understanding of safety culture as deeply rooted assumptions about the interplay of people, technology, and organization in their relation to safety is presented. As a complement to audit methods aimed at assessing formal safety management, a questionnaire was developed which allows some indications of these assumptions to be captured by providing data on perceptions regarding operational safety, safety and design strategies, and personal job needs. Analyzing response patterns of different occupational, hierarchical, and organizational groups within a company in combination with formal audit results and the communicative validation of both in a feedback meeting can help the auditors as well as the members of the company to gain a deeper understanding of safety management and safety culture in that company. Results from seven audits in petrochemical plants are presented and discussed with respect to the validity and practicability of the chosen approach.