Characterization and pollution potential assessment of Tunceli, Turkey municipal solid waste open dumping site leachates

Environmental monitoring of leachate quality from an open municipal solid waste dumping site in Tunceli, Turkey was studied in this research. The most commonly examined pollution parameters were determined on a seasonal basis. The annual average 5-day biological oxygen demand (BOD₅) and chemical oxygen demand (COD) values of station points were measured as 70 and 425 mg/L, respectively, and also the average BOD₅/COD ratio (a measure of biodegradability) was calculated as 0.20. The low ratio of biodegradability and slightly alkaline pH values in the leachate samples indicated that the site was characterized by methanogenic conditions. The mean ammonium-nitrogen (NH₄ ⁺-N) and corresponding phosphate (orthophosphate) values were assayed as 70 and 11 mg/L, respectively. The average solids content in the leachates was measured as 4,681 mg/L (total solids) and 144 mg/L (suspended solids). Very low concentrations of iron, manganese, copper, and zinc in the leachate samples were found and the concentration of cadmium was measured below detection limits. Excessive amount of nutrients and high organic and inorganic pollutant content in the leachates pose serious pollution potential to the environment. Since no drainage system or bio treatment exists in this open dumping site, high permeability of natural soil at the site and in the surrounding area and very fractured and crackled rocks under natural soil are indicators of high groundwater pollution potential in this site.     

Wastewater management for Istanbul: basis for treatment and disposal

A number of studies have so far been conducted to assess the magnitude of pollution generated by domestic and industrial sources in the Istanbul Metropolitan Area. They indicate that a management scheme for wastewater treatment and disposal should involve a total discharge of 15.4 m3 s(-1) with a potential pollution load of 330 tons BOD5 day(-1) for 1990. A scheme of this magnitude inevitably requires careful evaluation of receiving water characteristics, both from an oceanographic and a quality standpoint. In this paper significant water quality parameters related to the Black Sea-Bosphorus Strait-Marmara Sea System are reviewed and incorporated in the evaluation of treatment and disposal alternatives. In this context, the pollution exchange between the Mamara Sea and Bosphorus is quantified, pollutant contents of the Mamara Sea and discharges from the Istanbul Metropolitan Area are compared, and a number of scenarios are evaluated to define the optimum treatment and disposal strategy.     

Treatment of E. coli HB101 and the tetM gene by Fenton’s reagent and ozone in cow manure

The destruction of antibiotic-resistant microorganisms at the source of contamination is necessary due to their adverse effects and to their increasingly widespread occurrence in the environment. To address this problem, Fenton and ozone oxidation processes were applied to synthetically contaminated cow manure to remove the tetM gene and its host, Escherichia coli HB101. The efficiency of the processes was evaluated by enumeration of E. coli HB101 and by PCR amplification of the tetM gene. The results of this study show that 56.60% bacterial inactivation (corresponding to a 0.36 log reduction) was achieved by a Fenton reagent dose of 50 mM H₂O₂ and 5 mM Fe²⁺ without acidifying the manure. Despite the high organic content of cow manure, 98.50% bacterial inactivation (corresponding to a 1.83 log reduction) was obtained by the ozonation process with an applied dose of 3.125 mg ozone/g manure slurry. The PCR study revealed that the band intensity of the tetM gene gradually decreased by increasing the Fenton reagent and the applied ozone dose. However, significantly high doses of oxidants would be required to completely eliminate bacterial pollution in manure.     

Do renewable energy and natural gas consumption mitigate CO2 emissions in the USA? New insights from NARDL approach

Environmental Science and Pollution Research - This article attempts to explore the asymmetric impact of renewable energy and natural gas consumptions on CO2 emissions for the selected ten most...     

The fatty acid compositions of several plant seed oils belong to Leguminosae and Umbelliferae families

In samples with 1,009, 7,723, 7,618, 7,618, 1,004 and 1,009 number, oleic acid were found as 62.0, 77.0, 74.84, 71.55, 54.52 and 62.30 %, respectively. In other samples, oleic acid content was determined between 17.43 % (1,589) and 34.86 % (1,298). Linoleic acid content of seed oils ranged from 6.52 % (7,727) to 57.29 % (1,501). In addition, linolenic acid content was found between 0.22 % (7,618) and 46.91 % (1,589). Palmitic acid content of samples changed between 2.03 % (7,727) and 19.81 % (1,298). Capric acid was found at high level in 1,009 (8.53 %), 7,727 (37.31 %) and 1,004 (8.28 %) samples. Caproic acid was found in only 7,727 (3.38 %).     

A sensitive method for selective determination of vanadium species by dispersive liquid–liquid microextraction (DLLME) with spectrophotometric detection

A simple, fast, and low-cost analytical procedure was developed for trace-level determination of inorganic vanadium species by dispersive liquid–liquid microextraction in combination with spectrophotometry. Vanadium in pentavalent form, V(V), was quantitatively extracted into organic phase as 4-(2-pyridylazo)-recorcinol (PAR) complex in the presence of N-cetyl-N,N,N-trimethyl ammonium bromide (CTAB) as counter-ion. Vanadium (IV) was masked with 1,2-diaminocyclohexanetetraacetic acid to allow speciation analysis. Total vanadium was determined after oxidation of V(IV) to V(V). The main factors affecting preconcentration and spectrophotometric detection of vanadium species such as pH, concentration of PAR and CTAB, the type and volume of the extraction, and disperser solvents were optimized. The limit of detection and enhancement factor obtained under optimum conditions were found to be 0.06 μg L^?1 and 98, respectively. Relative standard deviations for V(IV) and V(V) at 3.0 μg L^?1 were less than 2.4%. The presented procedure was applied to environmental water samples for selective determination of vanadium species. Moreover, the method was applied to determination of vanadium in edible salt samples, due to its applicability in high-NaCl-containing solutions. The validity of proposed method was proven by spike recovery experiments and also independent analysis by inductively coupled plasma mass spectrometry.     

Modeling wastewater discharge at the planning stage of a marine outfall system

The possibility of marine discharge of a negatively buoyant industrial waste was evaluated by a modeling study using Killworth 3-D, which is the first version of the Modular Ocean Model (MOM). The Model was run with the recorded wind direction and speed on the cruise dates and the circulation patterns for surface and subsurface were found to be similar with the current meter measurements. Model scenarios have been set-up in order to estimate the intensity and direction of the currents in the Nemrut Bay under the condition of wind blowing from a definite direction for a long time. MOM model has been run for four major wind directions, each having duration of 10 days and the behavior of the discharge plume in the worst case has been traced. Also, the behavior of the discharge plume in the real case has been estimated by using the wind data of the region. According to the model results, impact of trace elements that compose the discharge effluent is limited both in time and space. It is concluded that trace elements will leave the Bay in a short time due to the short residence times.     

Effects of Starch Sources and Supplementary Materials on Starch Based Foam Trays

Firstly, foam trays were produced from glyoxal cross-linked wheat, potato and corn starches and their mixtures. The most suitable starch type for starch-based foam tray production was selected according to the level of water absorption, density, surface and cross-section micrographs of the foam trays. It was decided that a wheat and potato starch blend was the most suitable starch source for producing the foam trays because they have the lowest water absorption percentage (25.5 ± 0.7%), low density (0.17 ± 0.01 g/cm³) and a smooth surface. Potato–wheat starch foam trays with fibres were produced by adding wheat and wood fibres. Unlike wood fibres addition, wheat fibres significantly decreased the percentage of water absorption (16.63 ± 1.2%) and density (0.115 ± 0.013 g/cm³) of the tray. Also, the trays including wheat fibre had a lighter colour than the wheat–potato starch tray. To further reduce water absorption of the tray, the trays were made by adding two different types of lipids (beeswax or shortening and three different types of filler materials—kaolin, montmorillonite or zinc oxide nanoparticles). According to the level of water absorption of the trays, it was decided that shortening and zinc oxide nanoparticles, in addition to kaolin, were respectively the most suitable lipid and filler materials. The foam trays were produced by adding these supplementary materials. The addition of shortening slightly, zinc oxide nanoparticles moderately and kaolin greatly increased the density of the wheat potato starch tray including fibre. However, the percent of water absorption of the trays containing wheat fibre + shortening or wheat fibre + shortening + zinc oxide nanoparticles decreased 6.4 ± 0.01 and 5.9 ± 0.3%, respectively.     

Trace metal distribution in different chemical fractions of marine sediments along the eastern Aegean shelf

The major objective of this study was to carry out sequential chemical extraction for the partitioning of particulate trace metals in sediment samples, collected along the eastern Aegean shelf during cruises July‐August 1994, in the framework of a National Marine Measurement and Monitoring Programme for the Aegean Sea.

Five metals, Cd, Pb, Cu, Zn and Cr were examined in each of sediment samples. Three chemical fractions of the sediments were separated and concentrations of the trace metals were determined by AAS techniques. The three different leaches used were hydroxylamine hydrochloride‐acetic acid, hydrogen peroxide and nitric‐perchloric acids.

Metals were concentrated mainly in the fraction extracted by nitric‐perchloric acids. Lead in the first fraction were found in the sediments of Northern part of Aegean, where the concentration of organic material was high.

The total concentrations of Cd, Cu, Zn, Cr were higher in Izmir Bay than the other sampling points. The distribution of Pb concentrations was the highest in Edremit Bay and Izmir Bay.