Voltammetric trace determination of mercury using plant refuse modified carbon paste electrodes

Citrus limon peel (kitchen waste) and Leucaena leucocephala seeds (agricultural waste) were used as a modifier for fabrication of modified carbon paste electrode for determination of mercury in aqueous sample using differential pulse anodic stripping voltammetry. Mercury was adsorbed on electrode surface at open circuit and anodic stripping voltammetric scan was run from ?0.5 to 0.5 V. Various electrochemical parameters including amount of modifier, supporting electrolyte, accumulating solvent, pH of the accumulating solvent, and accumulation time were investigated. The effect of presence of other metal ions and surfactants was also studied. In comparison C. limon peel proved to be a better modifier than L. leucocephala seed biomass. This was justified by electrode characterization using cyclic voltammetry that indicated decrease in resistance of electrode when C. limon peel was used as modifier and increase when modifier was L. leucocephala seeds. Maximum current response was obtained using 5 % C. limon peel biomass, hydrochloric acid as supporting electrolyte, acetate buffer of pH 6 as an accumulating solvent, 10-min accumulation time, and scan rate of 50 mV/s. Linear calibration curves were obtained in the concentration range 100 to 1,000 μg L^?1 of mercury for accumulation time of 10 min with limit of detection of 57.75 μg L^?1 and limit of quantification of 192.48 μg L^?1. This technique does not use mercury as electrode material and, therefore, has a positive environmental benefit.     

Potential benefits of drought and heat tolerance in groundnut for adaptation to climate change in India and West Africa

Climate change is projected to intensify drought and heat stress in groundnut (Arachis hypogaea L.) crop in rainfed regions. This will require developing high yielding groundnut cultivars that are both drought and heat tolerant. The crop growth simulation model for groundnut (CROPGRO-Groundnut model) was used to quantify the potential benefits of incorporating drought and heat tolerance and yield-enhancing traits into the commonly grown cultivar types at two sites each in India (Anantapur and Junagadh) and West Africa (Samanko, Mali and Sadore, Niger). Increasing crop maturity by 10 % increased yields up to 14 % at Anantapur, 19 % at Samanko and sustained the yields at Sadore. However at Junagadh, the current maturity of the cultivar holds well under future climate. Increasing yield potential of the crop by increasing leaf photosynthesis rate, partitioning to pods and seed-filling duration each by 10 % increased pod yield by 9 to 14 % over the baseline yields across the four sites. Under current climates of Anantapur, Junagadh and Sadore, the yield gains were larger by incorporating drought tolerance than heat tolerance. Under climate change the yield gains from incorporating both drought and heat tolerance increased to 13 % at Anantapur, 12 % at Junagadh and 31 % at Sadore. At the Samanko site, the yield gains from drought or heat tolerance were negligible. It is concluded that different combination of traits will be needed to increase and sustain the productivity of groundnut under climate change at the target sites and the CROPGRO-Groundnut model can be used for evaluating such traits.     

Nanocellulosic fiber-modified carbon paste electrode for ultra trace determination of Cd (II) and Pb (II) in aqueous solution

In recent years, increasing awareness of the environmental impact of heavy metals has prompted a demand for monitoring and decontaminating industrial wastes prior to discharging into natural water bodies. This paper describes the preparation and electrochemical application of carbon paste electrode modified with nanocellulosic fibers for the determination of cadmium and lead in water samples using anodic stripping voltammetry. First, cadmium and lead were adsorbed on the carbon paste electrode surface at open circuit potential, followed by anodic stripping voltammetric scan from -1 to 0 V. Different factors affecting sensitivity and precision of the electrode, including accumulating solvent, pH of the accumulating solvent, accumulation time, supporting electrolyte, and scan rate were investigated. The proposed method was also applied to the determination of Cd (II) and Pb (II) in the presence of other interfering metal ions and cetyl trimethyl ammonium bromide, sodium dodecyl sulfate, and Triton X-100 as a representative of cationic, anionic, and neutral surfactants. Linear calibration curves were obtained in the concentration ranges of 150–650 μg?L^?1 and 80–300 μg?L^?1, respectively, for cadmium and lead at an accumulated time of 10 min with limits of detection 88 and 33 μg?L^?1. Optimized working conditions are defined as acetate buffer of pH?5 as accumulating solvent, hydrochloric acid as supporting electrolyte, and scan rate 50 mV/s. This technique does not use mercury and therefore has a positive environmental benefit. The method is reasonably sensitive and selective and has been successfully applied to the determination of trace amounts of Cd (II) and Pb (II) in water samples.