A review on adsorptive removal of dyes from wastewater by hydroxyapatite nanocomposites

Environmental Science and Pollution Research - Dye removal from wastewater is of prominence due to its hostile effects on human health and the environment. The complex structure of the dye molecule...     

Monitoring and assessing variation of sewage quality and microbial functional groups in a trunk sewer line

In this study, the variation of sewage quality was investigated and the active fraction of different microbial functional groups in biofilm was quantified in a 5.6-km trunk sewer line. The sewage quality including suspended solids, biochemical oxygen demand, total chemical oxygen demand (COD), total nitrogen, total Kjeldahl nitrogen, ammonia nitrogen, nitrite nitrogen, and nitrate nitrogen were measured and compared with the values in literatures. The results indicated that since the wastewater treatment plant was not operated at its full capacity, the concentrations of different compounds were lower compared with the values in literatures. The values of heterotrophic growth rate constant lay between 5.6 and 8.6 day^???1. Its average value was 7.7 day^???1. The values of heterotrophic lysis rate constant lay between 0.2 and 0.4 day^???1. The active heterotrophic biomass in biofilm varied from 240 to 800 mg COD m^???2 and average value was 497 mg COD m^???2. The biofilm mass varied from 880 to 1,080 mg m^???2. The percentage of heterotroph to biofilm mass fall within the range of 24.0–90.9% and average value was 52.9%. In the oxygen uptake rate batch tests, the biomass, growth rate constant, and lysis rate constant of autotroph could not be determined because the fraction of autotroph in biofilm was relatively few. It revealed that the degradation of organic matters, nitrification, and denitrification occurred in the trunk sewer line. But the results indicate that the condition seem favorable for nitrification.     

Motorcyclist injury severity in angle crashes at T-junctions: Identifying significant factors and analysing what made motorists fail to yield to motorcycles

Evidence in literature suggested that motorists’ failure to give way to motorcycles at junctions is the main contributory factor to motorcycle–car accidents that involve gap acceptance (i.e., approach-turn and angle crashes). This paper attempts to examine how motorist’s failure to give way affects motorcyclist injury severity in angle crashes at T-junctions, while controlling for other factors (demographic, vehicle, crash, and environmental factors). Binary logistic models of motorcyclist injury severity were estimated using the data extracted from the Stats19 accident injury database (1991–2004). Angle collisions were classified into several sub-crashes based on the manoeuvres motorcycles and cars were making prior to the accidents. The modelling results showed that injuries were greatest when a travelling-straight motorcycle on the main road crashed into a right-turn car from the minor road, particularly at stop-/yield-controlled junctions. Such crash pattern was assumed to be an accident involving right-of-way violation. Using binary logistic models, factors determining the likelihood of motorist’s failure to yield to motorcycles were also examined. The implications of the research findings of this present study were provided.     

Ozone Formation in California's San Joaquin Valley: A Critical Assessment of Modeling and Data Needs

ABSTRACT

Data from the 1990 San Joaquin Valley Air Quality Study/ Atmospheric Utility Signatures, Predictions, and Experiments (SJVAQS/AUSPEX) field program in California's San Joaquin Valley (SJV) suggest that both urban and rural areas would have difficulty meeting an 8-hr average O₃ standard of 80 ppb. A conceptual model of O₃ formation and accumulation in the SJV is formulated based on the chemical, meteorological, and tracer data from SJVAQS/ AUSPEX. Two major phenomena appear to lead to high O₃ concentrations in the SJV: (1) transport of O₃ and precursors from upwind areas (primarily the San Francisco Bay Area, but also the Sacramento Valley) into the SJV, affecting the northern part of the valley, and (2) emissions of precursors, mixing, transport (including long-range transport), and atmospheric reactions within the SJV responsible for regional and urban-scale (e.g., downwind of Fresno and Bakersfield) distributions of O₃. Using this conceptual model, we then conduct a critical evaluation of the meteorological model and air quality model. Areas of model improvements and data needed to understand and properly simulate O₃ formation in the SJV are highlighted.     

模拟降雨作用桩锚-加筋土组合结构加固边坡研究

桩锚—加筋土组合支挡结构在治理大型复杂滑坡中发挥越来越重要的角色。以某高填方山区机场滑坡为原型,进行降雨作用对桩锚—加筋土组合支挡结构加固边坡稳定性的模型试验研究。结果表明:①桩顶位移随注水时间产生三个阶段的变化:初期平缓发展阶段、突变增加阶段、再次平缓发展阶段。后排悬臂式桩桩顶位移变化量明显大于前排埋入式桩,因此,多排锚索抗滑桩加固边坡设计时,在后排桩悬臂情况下,宜考虑后排桩比前排桩截面尺寸大、锚索间距小来减小其桩顶位移,增强坡体稳定性;②填方边坡位移随注水时间变化,坡顶一级边坡位移量最大,随边坡级数增加,位移量减小,因此多级边坡加固可适当增加边坡锚索框架;③填方坡体沉降量随注水时间表现出后缘大、前缘小的趋势;④加筋土的变形与边坡坡体的变形一致,表明加筋土能够增强填方边坡的整体性;⑤各监测曲线最终均趋于平缓,表明桩、锚和加筋土组合支挡结构体系性能发挥良好。     

Prenatal diagnosis of Apert syndrome: report of two cases

Two de novo cases with Apert Syndrome detected prenatally are presented herein. In the first, fetal ultrasound findings of syndactyly of the hands, craniosynostosis and proptosis resulted in a prenatal diagnosis in the nineteenth week of gestation. This is the earliest prenatal diagnosis of this syndrome in a not-at-risk case. Following counseling, this pregnancy was terminated and subsequent pathological examination and DNA analysis confirmed the diagnosis of Apert Syndrome and coarctation of the aorta. In the second case, fetal ultrasound at 21 weeks' gestation revealed a hypoplastic left heart and clover-leaf skull. Following counseling, this pregnancy was also terminated. Further examination of the fetus and DNA analysis led to a diagnosis of Apert Syndrome. These cases emphasize the need to complete a thorough fetal ultrasound in cases with potentially lethal cardiac abnormality and the importance of incorporating a fetal pathologist, as well as a medical geneticist, in the investigations performed after delivery or pregnancy termination when a fetal abnormality is detected on ultrasound. Copyright © 2003 John Wiley & Sons, Ltd.     

我国矿产资源的现状及保护对策

本文着重讲述了我国矿产资源的特点,全面分析了我国矿产资源的现状,并 提出缓解矿产资源危机的一些对策。     

Microbial degradation of mefenoxam in rhizosphere of Zinnia angustifolia

The fate of the fungicide mefenoxam was studied in a containerized rhizosphere system. The rhizosphere system used Zinnia angustifolia (Tropic Snow) in a bark/sand potting mix and was compared to bulk potting mix (no plants). Rhizosphere microbial populations were allowed to establish for 3 weeks prior to fungicide addition (20 microg per g mix). Mefenoxam and degradation product concentrations were determined by High HPLC or capillary electrophoresis after extraction. Seventy eight percent of the fungicide originally applied to the rhizosphere was degraded after 21 days compared to 44% in bulk system (no plant). The primary degradation product was the free acid N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-DL-alanine, which accounted for 71% of the applied parent chemical after 30 days. N-(2,6-dimethylphenyl)-acetamide was also detected, but in lesser amounts. Bacterial populations in the rhizosphere increased during the 30-day period, which correlated with an increase in degradation of the parent compound. Pure cultures of Pseudomonas fluorescens and Chrysobacterium indologenes isolated from the rhizosphere system could degrade the applied fungicide (10 microg/ml) almost completely to the free acid within 54 h.     

The development and application of a simplified ozone modeling system (SOMS)

This paper describes the development and evaluation of a computationally efficient semi-empirical photochemical model that can be used as a screening tool to obtain quick estimates of the effect of a large number of VOC and NO_x emission control strategies on ozone concentrations. Selected control strategies can subsequently be examined with a more complex model. The model is one component of an ozone management system, the regional ozone decision model (RODM), designed to examine the costs and environmental consequences of alternate ozone abatement strategies.The model was developed by systematic simplification of a detailed photochemical model. At each step of the simplification, the simplified model was tested against observations and against results from the detailed model. The first major simplification was the introduction of a highly parameterized chemistry mechanism, originally developed by Azzi et al. (1992 Proc. 11th Int. Clean Air Conf., 4th Regional IUAPPA Conf.). This modification resulted in a factor of 5 improvement in the computational efficiency of the model. The model with the simplified chemistry was then tested by applying it to a photochemical oxidant episode in the San Joaquin Valley of California. Further improvements in computational speed and efficiency were obtained by uncoupling the chemistry from the transport of VOC and NO_x.     

Adaptive flood hazard management strategy and its effect on settlements in the lower Yellow River area in Ming–Qing China: a case study of Kaifeng Prefecture

This paper examines the settlements and embankments of the Yellow River in central China in late imperial China (late fourteenth century to the early twentieth century) through the approach of historical geographical information system. The Yellow River frequently flooded and changed paths in the lower Yellow River area, creating a disaster-prone environment in the populous capital city, Kaifeng in Henan Province. The official policies of constructing embankments in the alluvial fan for the sake of both preventing flood and ensuring canal transportation for grains were important factors in shaping the settlements of the region. Historical data from some counties in Kaifeng Prefecture indicate that people took shelter along the embankments during floods and, as a consequence, villages steadily developed along the embankments. This is in despite official restrictions on the use of the bottomlands along the Yellow River. This historical case not only illustrates the operating modes of official flood prevention strategies in dynastic China, but also shows how archaic settlement patterns and landscapes have shaped the geography of contemporary China.