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1.
为了有效处理低浓度抗生素残留废水,以水热法制备的BiOBr为载体,诺氟沙星(NOR)为模板,通过表面分子印迹法制备了BiOBr分子印迹材料(MIP).同时,采用SEM与XRD对制备的材料进行相分析及显微结构分析,并利用XPS、FTIR、BET和UV-Vis DRS对所合成材料的微观结构进行观察.最后,以诺氟沙星(NOR)为目标污染物,对MIP在暗反应下的吸附性能及300 W Xe灯照射下的光催化性能进行测定,并探讨pH、投加量、初始浓度、是否印迹处理对NOR去除的影响.实验结果表明,在pH为中性,MIP投加量为2.5 g·L-1的条件下,MIP对5 mg·L-1 NOR溶液的去除率达到96.2%,且对低浓度(1 mg·L-1)NOR溶液的去除率达到99%.综合表明,本文所制备的MIP适用于低浓度诺氟沙星废水的处理. 相似文献
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James Redfern Marina Ratov Andrew P. Dean James Pritchett Matthieu Grao Joanna Verran Peter Kelly 《环境科学学报(英文版)》2021,33(6):128-136
Access to safe drinking water free from microbial pollution is an issue of global concern. The use of photocatalytic thin films in water treatment has focused on titanium dioxide, which requires UV-activation, proving a potential barrier to upscaling and implementation in the real world. Visible-light-activated photocatalytic thin films, such as bismuth oxide, have recently been shown to have antimicrobial properties. However, more understanding of the photocatalytic effect on the microbial population in water is required. Glass beads coated with bismuth oxide were incubated with either Microcystis aeruginosa, Anabaena sp. or free-floating genomic DNA. The presence of bismuth oxide-coated glass beads was able to rapidly stop a population of cyanobacteria from increasing. The coated beads were also able to degrade genomic DNA. Leachate from the beads showed no increase in toxicity against human liver cells. This data demonstrates the efficacy of bismuth oxide-coated glass beads for controlling potentially dangerous cyanobacterial populations, whilst potentially reducing the amount of free-floating genomic DNA (an essential issue in the face of antimicrobial resistance) – all of which should be essential considerations in emerging water treatment technologies. 相似文献
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许文静 《环境监测管理与技术》2019,31(5):50-52
采用一步法制备石墨烯(GO)和铋[Bi(Ⅲ)]改性沸石咪唑酯骨架结构(ZIF-8),得到GZIF和Bi@GZIF吸附剂,并用X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)及扫描电镜(SEM)对制备的吸附剂进行表征。结果显示,改性后ZIF-8晶体结构没有被破坏,表面形态及表面基团发生了变化,对碘离子的吸附能力增强,吸附速度加快,尤其是Bi@GZIF在5 min内完成吸附88.3%,最大吸附容量达197.2 mg/g。 相似文献
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采用溴化1-丁基-3-甲基咪唑([Bmim]Br)离子液体辅助水热合成法制备了光催化剂Bi VO4。以高压氙灯作为可见光源,亚甲基蓝为目标污染物,考察反应温度、p H、反应时间和离子用量等制备条件对Bi VO4的可见光催化活性的影响,确定了最佳制备条件。并采用XRD、SEM和UV-Vis漫反射等分析手段对催化剂的晶相、形貌和光学特性进行了表征。结果表明,在离子液体加入量为2 m L、p H=4、反应温度为180℃、反应时间为4 h的条件下,制得的Bi VO4催化剂的可见光光催化活性最高。制得的Bi VO4为单斜相,呈分散的、大小均匀的片状,在200~500 nm范围有一个较宽的强吸收平台,具有良好的可见光催化活性,在可见光照射下对浓度为5 mg/L的亚甲基蓝的光催化脱色率达97%以上。 相似文献
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A highly active visible light-induced BiVO4 photocatalyst was prepared by a simple co-precipitation method using ammonia solution as a pH adjustor and Triton X-100 (TX100) as a structure directing agent. The physical properties of the prepared BiVO4 photocatalyst were investigated by several techniques such as X-ray diffractometer (XRD), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), energy dispersive analysis (EDS), Fourier-transformed infrared spectroscopy (FT-IR), photoluminescence (PL), and UV–Vis diffused reflectance spectroscopy (DRS). XRD results revealed the existence of a monoclinic scheelite structure in both the unmodified and the modified samples. The TX100 played a crucial role to control the cuboid-like shape morphology of BiVO4. The DRS results showed that the as-prepared cuboid BiVO4 possessed enhanced visible light absorption range compared with that of the unmodified BiVO4. The photocatalytic activity was evaluated via indigo carmine (IC) degradation under visible light irradiation. The modified BiVO4 showed higher photocatalytic efficiency than the unmodified BiVO4 and the commercial P25-TiO2 which could be ascribed to the better charge separation efficiency. 相似文献
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Tianhao Xi Xiaodan Li Qihui Zhang Ning Liu Shu Niu Zhaojun Dong Cong Lyu 《Frontiers of Environmental Science & Engineering》2021,15(4):55
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本文提出了以聚三氟氯乙烯(PTFCE)为卤化剂,悬浮体制样/电热蒸发等离于体原子发射光谱(ETV-ICP-AES)直接测定水系沉积物(固体粉末)中微量铋的新方法。加入5%PTFCE,利用由化反应,改善Bi的蒸发。方法的检出限为24ng·ml ̄(-1),相对标准偏差3.2%,该法用于直接测定固体粉末水系沉积物中的Bi.结果与参考值吻合,回收率99.7-106.8%。 相似文献
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Ravindranadh Koutavarapu Mohan Rao Tamtam Chimpiri Rao Myl Migyung Cho Jaesool Shim 《环境科学学报(英文版)》2021,33(4):326-340
Global environmental problems have been increasing with the growth of the world economy and have become a crucial issue. To replace fossil fuels, sustainable and eco-friendly catalysts are required for the removal of organic pollutants. In this study, nickel ferrite (NiFe2O4) was prepared using a simple wet-chemical synthesis, followed by calcination; bismuth phosphate (BiPO4) was also prepared using a hydrothermal method. Further, NiFe2O4/BiPO4 nanocomposites were prepared using a hydrothermal technique. Numerous characterization studies, such as structural, morphology, surface area, optical, photoluminescence, and photoelectrochemical investigations, were used to analyze NiFe2O4/BiPO4 nanocomposites. The morphology analysis indicated a successful decoration of BiPO4 nanorods on the surface of NiFe2O4 nanoplate. Further, the bandgap of the NiFe2O4/BiPO4 nanocomposites was modified owing to the formation of a heterostructure. The as-prepared NiFe2O4/BiPO4 nanocomposite exhibited promising properties to be used as a novel heterostructure for tetracycline (TC) and Rhodamine B (RhB) removal. The NiFe2O4/BiPO4 nanocomposite degrades TC (98%) and RhB (99%) pollutants upon solar-light irradiation within 100 and 60 min, respectively. Moreover, the trapping experiments confirmed the Z-scheme approach of the prepared nanocomposites. The efficient separation and transfer of photogenerated electron-hole pairs rendered by the heterostructure were confirmed by utilizing electrochemical impedance spectroscopy, photocurrent experiments, and photoluminescence. Mott–Schottky measurements were used determine the positions of the conduction and valence bands of the samples, and the detailed mechanism of photocatalytic degradation of toxic pollutants was projected and discussed. 相似文献
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观察奥美拉唑、枸橼酸铋钾、阿莫西林及呋喃唑酮四联疗法对消化性溃疡的疗效.方法选取96例消化性溃疡、幽门螺杆菌(HP)阳性患者,给予口服奥美拉唑20 mg+枸橼酸铋钾240 mg+阿莫西林1 g+呋喃唑酮200mg2,次/日,共14日,观察症状,并复查胃镜和HP感染情况.结果绝大部分患者症状消失,行胃镜检查和HP检测,显示溃疡面治愈或明显好转,并HP转为阴性.结论四联疗法治疗消化性溃疡的疗效可靠,副作用少,价格便宜,值得临床推广.参10. 相似文献