Morphology-dependent interfacial interactions of Fe2O3 with Ag nanoparticles for determining the catalytic reduction of p-nitrophenol

In this work,we fabricated three kinds of Ag/Fe_2O_3 model catalysts with different morphologies to study the interfacial interactions between Ag and Fe_2O_3,and how they affected the catalytic activity in hydrogenation of p-nitrophenol was explored.The hydrothermal method was used to synthesize the metal oxide supported silver catalyst,with various morphologies including nanoplates(NPs),nanospheres(NSs),and nanocubes(NCs).The crystal structure,morphology and surface elements of the composite were investigated by various measurements,such as X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS).The catalytic activity was also evaluated by the reduction of p-nitrophenol to p-aminophenol.It was found that the activities of the above catalysts varied with the morphology of the support.Among them,Ag/Fe_2O_3 NPs promoted the highest performance,Ag/Fe_2O_3 NSs were slightly inferior,and Ag/Fe_2O_3 NCs were the worst.At last,we ascribed the remarkable activity of Ag/Fe_2O_3 NPs to the strong metal-support interactions between Ag and Fe_2O_3.     

中国“四化”建设对水足迹强度的影响分析

采用2000—2016年中国30省市（不包括香港、澳门、台湾、西藏四省区）的数据,构建四化指标体系,计算四化发展指数,进行地区四化水平评价,通过OLS和GMM回归模型考察四化发展对水足迹强度的影响,同时设置四化之间的交互项来识别四化指标之间的相互作用。主要结论如下：首先,从四化水平的地域发展差异上来看,中国四化水平总体上呈现出东部优于中部、中部优于西部的格局,水足迹强度的分布与之类似,说明四化水平发展与水足迹强度之间可能存在相关关系;其次,计量模型显示四化水平的提升对于水足迹强度的改善有积极影响,但每一化对于水足迹强度改善的影响大小不一;第三,以交互项衡量的四化相互作用对于水足迹强度的影响作用为正,表明四化发展对水足迹强度的改善效果逐渐趋于收敛。因此,优先提升落后地区的四化水平,以四化水平的提升推动水足迹强度的降低,能够有效降低我国总体水足迹强度水平。     

低温等离子体协同催化降解废气污染物的研究进展

阐述了低温等离子体协同催化工艺流程与反应机理,探讨了反应温度、废气进口组分、废气中水蒸气含量、气体流速、气溶胶等因素对降解效果的影响。分析认为:一段式低温等离子体协同催化可改变低温等离子体特征及催化剂催化特性,但尚未解决尾气臭氧逃逸、副产物产生及放电稳定性等问题;两段式低温等离子体协同催化可提高污染物分子降解效率并减少尾气臭氧逃逸,但未能有效利用等离子体的能量,气体中的水蒸气、粉尘及反应过程中产生的气溶胶均能影响后置催化剂的催化性能;两段式低温等离子体协同催化已具备工程应用条件,还需配套高效预处理单元以降低废气中水蒸气、粉尘等对催化剂的影响。     

爆炸螺栓分离对热防护系统冲击响应分析

目的考察在爆炸螺栓分离过程中,作用在TPS(热防护系统)上的冲击响应是否会导致其破坏,从而影响航天器飞行安全,对过程进行数值仿真分析。方法提出四阶段仿真方案,基于MSC.Dytran软件,采用流固耦合方法对爆炸螺栓分离过程进行动力学仿真;根据单个爆炸螺栓地面分离试验的结构进行建模和分析,获取结构响应曲线;再根据实测的冲击响应数据,对爆炸过程中炸药及JWL方程的参数等设置进行调整,获取准确爆炸螺栓的分析模型;最后应用于对真实结构中TPS(热防护系统)在分离过程里受爆炸螺栓冲击响应的动力学分析与评估。结果通过参数调整,获得的仿真模型与爆炸螺栓地面分离试验实测结果一致,证明了仿真模型的有效性和四阶段仿真方案的可行性。结论提取的真实结构爆炸螺栓分离过程中作用在TPS(热防护结构)上的最大加速度响应曲线,可用于指导TPS(热防护系统)的设计。     

The curve of ion exchange ratio(%)-pH of the interaction between suspended particles with Cd(II) in the Yellow River

The curve of ion exchange ratio(%)-pH of the interactionbetween suspended particles with Cd(II) in the Yellow River wasstudied. The effects of lysine on this curve have been alsoinvestigated. The results showed that (1) Cadmium in Cd(OH)+ formin the suspended particles exchanges with the cations.The exchangeratio of Cd2+ is nearly at its greatest value in the range of pH(8.0-8.5) in natural aquatic system; (2) Ion exchange ratiodecreases as the concentration of Cd2+ raises from 8.9×10-6 mol/L to 2x8.9 x 10-6mol/L; (3) At the lysine concentration of 6.8x10-6 mol/L, it can promote the ion exchange ratio; (4) Adsorption of thesuspended particles to cadmium is weaker in seawater and Jin ShaRiver than in the Yellow River.     

Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

金堆城超大型钼矿床水-岩δD-δ~(18)O同位素交换体系理论模型及成矿流体来源

基于水-岩δD-δ18O同位素交换体系理论模型的建立和计算，对金堆城超大型斑岩钼矿四个不同成矿期中成矿流体的演化和来源进行了研究，发现在成矿前期和早期，成矿流体为岩浆水与围岩在较低水／岩比值（0．1W／R＞0．001）和中、高温（t=250～500℃）条件下反应后的残余流体，而主成矿期和成矿晚期的成矿流作为大气降水在相对较高水／岩比值（0．5＞W／R0．1）和中、低温（t＝150～310℃）条件下与围岩反应后的残留流体。大气降水在金堆城钼矿成矿过程中起了重要作用。在主成矿期水／岩比值达到最高。     

改革开放以来我国粮食生产转型分析及展望

粮食生产转型是乡村生产体系演变的核心内容,以粮食生产转型研究为突破口能够清晰反映区域乡村人地关系的演化过程,为深化城乡融合发展和乡村转型发展研究提供新的视角。本文聚焦我国改革开放以来粮食生产转型历程,并尝试构建我国粮食生产转型的分析框架。研究发现,改革开放以来我国粮食生产转型呈现出“以粮为纲—农业结构调整—综合转型—城乡互动”四个差异化阶段特征。利用GL-RL模型,构建了我国粮食生产转型的分析框架。研究发现,改革开放以来我国粮食生产由Green Loop阶段演化到Red Loop阶段,粮食生产逐渐由本地生产融入到城乡生产网络,驱动粮食生产转型的扰动因素具有多时空尺度特征和跨尺度效应。城乡融合发展、乡村振兴战略、乡村人地关系协调和全球化等因素将会对未来粮食生产转型产生重要影响。此外,优化粮食生产转型与乡村转型发展的关系,将为保障粮食生产有序转型,完善乡村生产体系创造条件。     

铜山口铜(钼)矿床成矿流体水-岩反应数值模拟

铜山口铜(钼)矿床位于湖北省大冶市境内,是一典型的矽卡岩-斑岩复合型矿床。通过对其流体包裹体的系统研究,确定了成矿阶段成矿流体的成分及温压条件,并结合矿床学研究,将成矿过程分解为两个平行的成矿阶段,即矽卡岩型矿化阶段和斑岩型矿化阶段。根据Johson和Reed等人建立的水 岩反应模型,对本矿床成矿流体与围岩反应并析出金属沉淀的过程进行了数值模拟计算,其结果与实际地质情况吻合较好。     

广告理论课教学若干问题的探讨

本文讨论了在广告教学中广告理论课程在广告学知识体系中的重要位置，分析了忽视广告理论课教学产生的后果，文中最后提出了广告理论课教学的改革措施。