全文获取类型
收费全文 | 46篇 |
免费 | 1篇 |
国内免费 | 10篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 1篇 |
环保管理 | 5篇 |
综合类 | 16篇 |
基础理论 | 14篇 |
污染及防治 | 10篇 |
评价与监测 | 8篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 1篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2014年 | 4篇 |
2013年 | 12篇 |
2012年 | 3篇 |
2011年 | 3篇 |
2009年 | 1篇 |
2008年 | 1篇 |
2007年 | 8篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有57条查询结果,搜索用时 15 毫秒
1.
土壤样品的传统消解方法是用电热板硝酸-氢氟酸-高氯酸体系,消解时间长,试剂用量大,对操作人员身体危害大,并且测定结果也不准确。本文阐述了微波消解——原子吸收分光光度法测定土壤中的钴、钼。通过硝酸-盐酸-氢氟酸-高氯酸消解体系,选择出微波消解的最佳消解条件,通过对微波消解体系和传统消解体系进行对比试验,微波消解体系具有赶酸时间短,准确度高,对人体危害小,是一种值得推广的土壤消解方法。 相似文献
2.
3.
4.
《环境科学学报(英文版)》2023,35(2):42-49
Growing studies have linked metal exposure to diabetes risk. However, these studies had inconsistent results. We used a multiple linear regression model to investigate the sex-specific and dose-response associations between urinary metals (cobalt (Co) and molybdenum (Mo)) and diabetes-related indicators (fasting plasma glucose (FPG), hemoglobin A1c (HbA1c), homeostasis model assessment for insulin resistance (HOMA-IR), and insulin) in a cross-sectional study based on the United States National Health and Nutrition Examination Survey. The urinary metal concentrations of 1423 eligible individuals were stratified on the basis of the quartile distribution. Our results showed that the urinary Co level in males at the fourth quartile (Q4) was strongly correlated with increased FPG (β = 0.61, 95% CI: 0.17–1.04), HbA1c (β = 0.31, 95% CI: 0.09–0.54), insulin (β = 8.18, 95% CI: 2.84–13.52), and HOMA–IR (β = 3.42, 95% CI: 1.40–5.44) when compared with first quartile (Q1). High urinary Mo levels (Q4 vs. Q1) were associated with elevated FPG (β = 0.46, 95% CI: 0.17–0.75) and HbA1c (β = 0.27, 95% CI: 0.11–0.42) in the overall population. Positive linear dose-response associations were observed between urinary Co and insulin (Pnonlinear = 0.513) and HOMA–IR (Pnonlinear = 0.736) in males, as well as a positive linear dose-response relationship between urinary Mo and FPG (Pnonlinear = 0.826) and HbA1c (Pnonlinear = 0.376) in the overall population. Significant sex-specific and dose-response relationships were observed between urinary metals (Co and Mo) and diabetes-related indicators, and the potential mechanisms should be further investigated. 相似文献
5.
Sheppard PR Speakman RJ Ridenour G Witten ML 《Environmental monitoring and assessment》2007,130(1-3):511-518
This paper describes the use of lichen chemistry to assess airborne tungsten and cobalt in Fallon, Nevada, where a cluster
of childhood leukemia has been on going since 1997. Lichens and their rock substrates were collected from Rattlesnake Hill
within Fallon as well as from four different rock outcrops located north, east, south, and west of Fallon and at least 20 km
away from the town center. In the lichens themselves, W and Co are significantly higher within Fallon than in the combined
control site outside of Fallon. In the rock substrates of the lichens, no differences exist in W and Co. The W and Co differences
in lichens cannot be attributed to substrate geochemistry. Fallon is distinctive in west central Nevada for high airborne
W and Co, and given its cluster of childhood leukemia, it stands to reason that additional biomedical research is in order
to test directly the leukogenicity of combined airborne W and Co. 相似文献
6.
《环境科学学报(英文版)》2023,35(4):263-274
The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H2-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOFCo) being 245°C, 1.23 × 10−3 moltoluene/(gcat·sec), and 11.58 × 10−3 sec−1 for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO2, SO2 or NH3, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O2 and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H2O and CO2. 相似文献
7.
Cobalt is an essential element, but at high concentrations it is toxic. In addition to its well-known function as an integral part of cobalamin (vitamin B12), cobalt has recently been shown to be a mimetic of hypoxia and a stimulator of the production of reactive oxygen species. The present study investigated the responses of goldfish, Carassius auratus, to 96 h exposure to 50, 100 or 150 mg L−1 Co2+ in aquarium water (administered as CoCl2). The concentrations of cobalt in aquaria did not change during fish exposure. Exposure to cobalt resulted in increased levels of lipid peroxides in brain (a 111% increase after exposure to 150 mg L−1 Co2+) and liver (30-66% increases after exposure to 50-150 mg L−1 Co2+), whereas the content of protein carbonyls rose only in kidney (by 112%) after exposure to 150 mg L−1 cobalt. Low molecular mass thiols were depleted by 24-41% in brain in response to cobalt treatment. The activities of primary antioxidant enzymes, superoxide dismutase (SOD) and catalase, were substantially suppressed in brain and liver as a result of Co2+ exposure, whereas in kidney catalase activity was unchanged and SOD activity increased. The activities of glutathione-related enzymes, glutathione peroxidase and glutathione-S-transferase, did not change as a result of cobalt exposure, but glutathione reductase activity increased by ∼40% and ∼70% in brain and kidney, respectively. Taken together, these data show that exposure of fish to Co2+ ions results in the development of oxidative stress and the activation of defense systems in different goldfish tissues. 相似文献
8.
This article analyses the world demand for cobalt. It estimates short- and long-run elasticities with respect to price, activity and in some cases with respect to substitute-complement variables. For the USA these estimates have been obtained for all the important end-use categories. Aggregate elasticities are estimated for Japan, West Germany, France and for the non-communist world (excluding the USA). The appendix to the paper models price setting in the cobalt market and presents two simple simulations conducted on the world cobalt market. 相似文献
9.
AbstractA rapid and selective technique for extraction, preconcentration and determination of trace amounts of cobalt in water and pharmaceutical samples by air-assisted liquid–liquid microextraction combined with flame atomic absorption spectrometry is proposed. 1-Nitroso-2-naphthol is used as a complexing agent and 1-octanol as an extraction solvent. Parameters relevant for analytical effectivity, i.e. pH of sample solution, concentration of complexing agent, volume of extraction solvent, and number of extraction cycles are optimized using a Box–Behnken design. At optimum conditions, a dynamic linear range of 5–600?µg L?1 is obtained, with a limit of detection of 1.2?µg L?1. The method is used for determination of Co(II) in environmental water and pharmaceutical samples. 相似文献
10.
Andrea Hartwig Ursula Kasten Kwabena Boakye‐Dankwa Regina Schlepegrell Detmar Beyersmann 《毒物与环境化学》2013,95(4):205-215
Literature data concerning the genotoxicity of cobalt salts have been conflicting. To establish appropriate incubation conditions, we conducted a series of uptake studies, before genotoxicity was determined by DNA strand break induction in HeLa cells and mutagenicity in V79 Chinese hamster cells. Co(II) is taken up by HeLa cells in a concentration‐dependent manner and is accumulated inside the cell. The uptake is preceded by a fast association step to the outer membrane, with no saturation up to 24 h. DNA strand breaks as determined by nucleoid sedimentation are induced at concentrations as low as 50μMCoCl2. The induction is time‐dependent, showing the highest number of breaks after 4h incubation with no further increase up to 24h. CoCl2 is mutagenic at the HPRT‐locus, enhancing the spontaneous mutation frequency 4.2‐fold at 100μ?. Besides direct interactions with DNA, the mutagenicity of CoCl2 could also be due to a decrease in the Fidelity of DNA polymerisation. 相似文献