Electrogeneration of H(2) for Pd-catalytic hydrodechlorination of 2,4-dichlorophenol in groundwater

A novel electrolytic groundwater remediation process, which used the H₂ continuously generated at cathode to achieve in situ catalytic hydrodechlorination, was developed for the treatment of 2,4-dichlorophenol (2,4-DCP) in groundwater. Catalytic hydrodechlorination using Pd supported on bamboo charcoal and external H₂ showed that 2,4-DCP was completely dechlorinated to phenol within 30 min at pH ? 5.5. In a divided electrolytic system, the catalytic hydrodechlorination of 2,4-DCP in cathodic compartment by H₂ generated at the cathode under 20 and 50 mA reached 100% at 120 and 60 min, respectively. Two column experiments with influent pHs of 5.5 (unconditioned) and 2 were conducted to evaluate the feasibility of this process. The 2,4-DCP removal efficiencies were about 63% and nearly 100% at influent pHs of 5.5 and 2, respectively. Phenol was solely produced by 2,4-DCP hydrodechlorination, and was subsequently degraded at the anode. A low pH could enhance the hydrodechlorination, but was not necessarily required. This study provides the preliminary results of a novel effective electrolytic process for the remediation of groundwater contaminated by chlorinated aromatics.     

铜的快速电解法测定

为适应用废铜制取电解铜时快速测定铜的需要，试验用快速电解法测定电解铜中的铜的方法，采用水浴控制溶样温度，电炉加热驱氮，加大电解电流，缩短电解时间，对不同电解酸度进行了探讨，样品测定结果重现性好，准确性较好。     

Reclaiming the spent alkaline zinc manganese dioxide batteries collected from the manufacturers to prepare valuable electrolytic zinc and LiNi0.5Mn1.5O4 materials

A process for reclaiming the materials in spent alkaline zinc manganese dioxide (Zn–Mn) batteries collected from the manufacturers to prepare valuable electrolytic zinc and LiNi_0.5Mn_1.5O₄ materials is presented. After dismantling battery cans, the iron cans, covers, electric rods, organic separator, label, sealing materials, and electrolyte are separated through the washing, magnetic separation, filtrating, and sieving operations. Then, the powder residues react with H₂SO₄ (2 mol L^?1) solution to dissolve zinc under a liquid/solid ratio of 3:1 at room temperature, and subsequently, the electrolytic Zn with purity of ?99.8% is recovered in an electrolytic cell with a cathode efficiency of ?85% under the conditions of 37–40 °C and 300 A m^?2. The most of MnO₂ and a small quantity of electrolytic MnO₂ are recovered from the filtration residue and the electrodeposit on the anode of electrolytic cell, respectively. The recovered manganese oxides are used to synthesize LiNi_0.5Mn_1.5O₄ material of lithium-ion battery. The as-synthesized LiNi_0.5Mn_1.5O₄ discharges 118.3 mAh g^?1 capacity and 4.7 V voltage plateau, which is comparable to the sample synthesized using commercial electrolytic MnO₂. This process can recover the substances in the spent Zn–Mn batteries and innocuously treat the wastewaters, indicating that it is environmentally acceptable and applicable.     

吸附胶体浮选法处理电解钴废水的研究

采用吸附胶体浮选法处理电解钴废水。用十二烷基磺酸钠（ＳＬＳ）作浮选剂，用ＦｅＣｌ３和Ａｌ２（ＳＯ４）３作混凝剂，浮选后废水可达到国家工业废水排放标准（３ｍｇ／Ｌ）。为实际废水的处理提供了可靠的依据。     

电解钴废水处理的研究

采用气浮法处理电解钴废水。用十二烷基磺酸纳(SLS)作浮选剂,用FeCl3 和Al2 (SO4)3 作混凝剂,气浮后水可达到国家工业废水排放标准(3mg/L)。为实际废水的处理提供了可靠的依据。     

电解铝工程清洁生产分析与评价

本文以乐山某铝业有限公司新建10万吨电解铝工程为例,简述了电解铝生产工艺,重点对电解铝工程的清洁生产进行分析。从生产工艺的先进性、污染物排放量少、清洁原料、原辅材料消耗低、节能措施和废物回收利用等方面对预焙阳极电解槽技术的清洁生产进行分析。通过清洁生产指标分析结果,乐山某铝业有限公司电解铝工程满足清洁生产标准要求,经预焙槽技术和自焙槽相比,预焙槽技术具有污染物排放量少,物耗能耗低,使用原辅料清洁,电流效率高的特点,以不同预焙槽原辅材料消耗量回归分析结果及其综合分析,大型预焙阳极电解槽技术是铝电解行业的清洁生产工艺。     

染料生产废水的电解工艺处理方法

采用电解工艺处理染料生产废水，一方面降低废水的CODcr浓度，另一方面提高了废水的可生化性。当进水pH为11、CODcr为7000－12000mg／L时，出水可达国家排放标准。该工艺具有投资少，运用费用低，处理效果稳定等特点，适合中、小型染料生产厂的综合废水处理。     

硫化氢制氢电解槽设计的改进及实验研究

硫化氢间接电解制氢过程中,在电解槽内采用湍流网结构可以有效地改善传质,基本消除扩散传质的影响。当槽压为1．1V,阴阳极流速皆为200L／h,电解温度为40℃的情况下,电解槽可以长时间保持良好性能,电流密度约为160mA／cm^2。     

我国电解锰行业循环经济对策研究

分析了目前我国电解锰行业发展中存在的问题,阐述了电解锰循环经济的内涵,提出了构建循环型产业链的整体思路,并从企业、行业、政策层面提出了具体对策,为中国电解锰行业可持续发展提供理论依据。     

废水净化的电化学技术进展

从工程应用的角度，概述了废水净化电化学技术的发展现状，指出了当前存在的问题，展望了今后的发展方向。