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改性TiO2的制备、表征及光解水制氢性能研究
引用本文:尚世通,张雷,郝慧聪,徐爱琴,王丽,王德英.改性TiO2的制备、表征及光解水制氢性能研究[J].环境科学与管理,2010,35(4):102-106.
作者姓名:尚世通  张雷  郝慧聪  徐爱琴  王丽  王德英
作者单位:[1]东北电力大学,吉林吉林132012 [2]烟台大学,山东烟台264005
摘    要:以陶粒为载体,采用改进的溶胶-凝胶法制备B、Ni共掺杂陶粒负载纳米TiO2光催化剂。利用XRD,TG-DTA,FT-IR等手段对其组成、结构等进行分析和表征。以250 W紫外灯为光源,三乙胺为目标污染物和电子给体,考察了B-Ni2O3-TiO2/陶粒合成体降解污染物耦合光解水制氢的光催化性能;结果表明:所制得的B-Ni2O3-TiO2/陶粒催化剂具有较高的产氢效率,并探讨了焙烧温度、三乙胺溶液初始浓度等对催化剂光催化活性的影响。

关 键 词:B-Ni2O3-TiO2/陶粒  有机污染物  光催化降解  制氢

Preparation and Characterization of Modified TiO2 and the Performance of Photocatalytic Decomposition of Water into Hydrogen
Shang Shitong,Zhang Lei,Hao Huicong,Xu Aiqin,Wang Li,Wang Deying.Preparation and Characterization of Modified TiO2 and the Performance of Photocatalytic Decomposition of Water into Hydrogen[J].Environmental Science and Management,2010,35(4):102-106.
Authors:Shang Shitong  Zhang Lei  Hao Huicong  Xu Aiqin  Wang Li  Wang Deying
Institution:1.Electric Power University,Jilin 132012,China;2.Yantai University,Yantai 264005,China)
Abstract:B-Ni2O3-TiO2/haydite composite photocatalysts were prepared via modified sol-gel method by a carrier of haydite.The as-prepared composites were analysed and characterized with regard to their components,structure etc.by XRD,TG-DTA and FT-IR.Using triethylamine as the pollutants and electron donors,photocatalytic hydrogen generation and decomposition of the pollutants over B-Ni2O3-TiO2/haydite were studied by 250W UV lamp.It is showed that this preparation leads to a highly photocatalytic hydrogen generation activity.Meanwhile the effects of calcination temperature and concentration of the pollutants on photocatalytic hydrogen generation were also investigated.
Keywords:B-Ni2O3-TiO2/haydite  organic pollutant  photocatalysis  hydrogen generation
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