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1.
Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25–207 kg CO2-eq t?1 rw. Within all process stages, the emission of fossil CO2 from the combustion of MSW was the main contributor (111–254 kg CO2-eq t?1 rw), while the substitution of electricity reduced the GHG emissions by 150–247 kg CO2-eq t?1 rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.  相似文献   

2.
The municipal solid waste management significantly contributes to the emission in the atmosphere of greenhouse gases (e.g. CO2, CH4, N2O) and therefore the management process from collection to treatment and disposal has to be optimized in order to reduce these emissions. In this paper, starting from the average composition of undifferentiated municipal solid waste in Italy, the effect of separate collection on greenhouse gases emissions from municipal waste management has been assessed. Different combinations of separate collection scenarios and disposal options (i.e. landfilling and incineration) have been considered. The effect of energy recovery from waste both in landfills and incinerators has also been addressed. The results outline how a separate collection approach can have a significant effect on the emission of greenhouse gases and how wise municipal solid waste management, implying the adoption of Best Available Technologies (i.e. biogas recovery and exploitation system in landfills and energy recovery system in Waste to Energy plants), can not only significantly reduce greenhouse gases emissions but, in certain cases, can also make the overall process a carbon sink. Moreover it has been shown that separate collection of plastic is a major issue when dealing with global warming relevant emissions from municipal solid waste management.  相似文献   

3.
This study aimed to identify distribution of metals and the influential factors on metal concentrations in incineration residues. Bottom ash and fly ash were sampled from 19 stoker and seven fluidized bed incinerators, which were selected to have a variety of furnace capacity, furnace temperature, and input waste. In the results, shredded bulky waste in input waste increased the concentration of some metals, such as Cd and Pb, and the effect was confirmed by analysis of shredded bulky waste. During MSW incineration, lithophilic metals such as Fe, Cu, Cr, and Al remained mainly in the bottom ash while Cd volatilized from the furnace and condensed to the fly ash. About two thirds of Pb and Zn was found in the bottom ash despite their high volatility. Finally, based on the results obtained in this study, the amount of metal in incineration residues of MSW was calculated and the loss of metal was estimated in terms of mass and money. A considerable amount of metal was found to be lost as waste material by landfilling of incineration residues.  相似文献   

4.
Nitrous oxide and carbon dioxide were continuously measured and variability of emission factors (EFs) was evaluated in five municipal waste incinerators (MWIs) and four industrial waste incinerators (IWIs) from 24 to 86 days between 2008 and 2011. N2O EFs were calculated by Monte Carlo simulation and mean N2O EFs were 7.1, 107, 127, 219 g N2O/ton waste combusted in MWIs with selective catalytic reduction (SCR) for NOx control, MWIs with selective non-catalytic reduction (SNCR), IWIs with SNCR, and a MWI using fluidized bed with SNCR, respectively. Climate-relevant CO2 EFs ranged from 0.45 to 0.72 ton CO2/ton waste combusted in MWIs. Maximum values of upper limit for 95% confidence intervals (CIs) of N2O EFs estimated in each MWIs with SCR, MWIs with SNCR, IWIs with SNCR were 185, 94, 101% of mean N2O EFs, respectively. Meanwhile, maximum values of upper limit for 95% CIs of CO2 EFs were much lower as between 18 and 36% in those facilities. 84% CIs of mean N2O EFs in MWIs with SNCR and IWIs with SNCR were overlapped indicating those values are not significantly different.  相似文献   

5.
Materials and energy used for the construction of modern waste incineration plants were quantified. The data was collected from five incineration plants (72,000–240,000 tonnes per year) built in Scandinavia (Norway, Finland and Denmark) between 2006 and 2012. Concrete for the buildings was the main material used amounting to 19,000–26,000 tonnes per plant. The quantification further included six main materials, electronic systems, cables and all transportation. The energy used for the actual on-site construction of the incinerators was in the range 4000–5000 MW h. In terms of the environmental burden of producing the materials used in the construction, steel for the building and the machinery contributed the most. The material and energy used for the construction corresponded to the emission of 7–14 kg CO2 per tonne of waste combusted throughout the lifetime of the incineration plant. The assessment showed that, compared to data reported in the literature on direct emissions from the operation of incinerators, the environmental impacts caused by the construction of buildings and machinery (capital goods) could amount to 2–3% with respect to kg CO2 per tonne of waste combusted.  相似文献   

6.
In the European Union (EU), waste management is almost totally regulated by EU directives, which supply a framework for national regulations. The main target in view of sustainability is the prevention of direct disposal of reactive waste in landfills. The tools to comply with these principles are recycling and material recovery as well as waste incineration with energy recovery for final inertization. The adaptation of the principles laid down in EU directives is an ongoing process. A number of countries have already enacted respective national regulations and their realization shows that recycling and incineration are not in competition but are both essential parts of integrated waste management systems. In the EU, the amount of residual waste available for energy recovery can supply approximately 1% of the primary energy demand. About 50% of the energy inventory of municipal solid waste (MSW) in most EU countries is of biogenic origin, and MSW is to the same extent to be looked upon as regenerative fuel. Hence part of the CO2 released from waste incineration is climate neutral. In the EU, this share could produce savings of the order of 1% of annual CO2 emissions if energy from MSW replaced that derived from fossil fuel.  相似文献   

7.
The identification of significant pollutants emitted from the contamination source is the first step in evaluating the impact associated with anthropic activity. Municipal solid waste (MSW) incinerators are still generally perceived as great pollutant sources, in particular due to their gaseous emissions from the stack, which constitute the major effluent from the plant. In this work a life cycle assessment and an integrated environmental monitoring system were applied together, in order to obtain complete information about the incineration process and its environmental impact. The former is a proven methodology, but its application to waste management systems constitutes a relatively new field of application with a great developmental potential. The contribution of the incineration process to the different environmental impact categories was investigated, finding many avoided impacts due to energy recovery. The latter is an innovative approach that allows a remarkable understanding of impact due to a contamination source; interesting correlations were found between heavy metals both in gas emissions and in natural matrices in the surroundings.  相似文献   

8.
The management of greenhouse gases (GHGs) emissions is currently a very important environmental issue. Mega-event organizers and host cities have attached great importance to GHGs emissions associated with event-related activities. However, GHGs emissions from event solid waste have never been thoroughly discussed. This study investigated GHGs emissions of major event’s solid waste using life cycle assessment, based on Shanghai Expo case. The results showed that GHGs from collecting and sorting, transportation and landfill treatment amount to 9790 t CO2e. And the emission intensity is estimated to be 134 g CO2e per event service. GHGs reduction from recycling amounts to 48 kt CO2e, with 78 % of these the result of construction waste recycle. It illustrates that waste recycle plays a vital role in GHGs mitigation. Finally, the study suggests that the concept of waste avoidance, waste reuse and waste recycle is an effective waste management to mitigate climate change and should be implemented in major event to achieve the goal of green event.  相似文献   

9.
CO2-loads from combustible waste are important inputs for national CO2 inventories and life-cycle assessments (LCA). CO2 emissions from waste incinerators are often expressed by emission factors in kg fossil CO2 emitted per GJ energy content of the waste. Various studies have shown considerable variations between emission factors for different incinerators, but the background for these variations has not been thoroughly examined. One important reason may be variations in collection of recyclable materials as source separation alters the composition of the residual waste incinerated. The objective of this study was to quantify the importance of source separation for determination of emission factors for incineration of residual household waste. This was done by mimicking various source separation scenarios and based on waste composition data calculating resulting emission factors for residual waste routed to incineration. Emission factors ranged from 27 to 40 kg CO2/GJ. The results appeared most sensitive towards variations in waste composition and water content. Recycling rates and lower heating values could not be used as simple indicators of the resulting emission factors for residual household waste; however the fossil carbon ratio of the waste after source separation was found to be appropriately correlated with the emission factor. Based on the results, it is recommended to carefully evaluate the source separation and collection systems behind reported literature values when comparing different studies and when using the values for environmental assessment purposes.  相似文献   

10.
This paper analyzes the amount and characteristics of municipal solid waste (MSW) according to the inhabitant density of population and the business concentration in 25 districts in Seoul. Further, the heat energy recovery and avoided CO2 emissions of four incineration plants located in residential and commercial areas in Seoul are examined. The amount of residential waste per capita tended to increase as the density of inhabitants decreased. The amount of commercial waste per capita tended to increase as the business concentration increased. The examination of the heat energy recovery characteristics indicated that the four incineration plants produced heat energy that depended on residential or commercial areas based on population and business. The most important result regarding avoided CO2 emissions was that commercial areas with many office-type businesses had the most effective CO2 emission savings by combusting 1 kg of waste. Assuming the full-scale operation of the four incineration plants, the amount of saved CO2 emissions per year was 444 Gg CO2 and 57,006 households in Seoul can be provided with heat energy equivalent to 542,711 Nm3 of LNG.  相似文献   

11.
Previous reports have focused on the emission of coplanar polychlorinated biphenyls (Co-PCBs) which have a toxic mechanism similar to that of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/DFs) released from municipal solid waste (MSW) incineration. Such emissions accounted for a small percentage of all the dioxins (PCDDs/DFs and Co-PCBs) recorded at the toxicity equivalent (TEQ) level. There is, however, very little information about Co-PCBs, such as the quantities being released and their effect on overall environmental pollution. The aim of this research has been to clarify the substance flow of Co-PCBs from MSW incineration processes. The results reveal that whereas the input of Co-PCBs into the MSW incineration facilities in Kyoto City was 0.13–0.29 μg-TEQ per ton waste, the total output of Co-PCBs (the sum of Co-PCBs released from emission gas, fly ash, and bottom ash) was 4.9 μg-TEQ per ton waste. The total output was therefore found to be higher than the total input. Over 90% of the total PCBs were decomposed in the incineration process. In comparing the profiles of congeners and homologues, those in the MSW were found to be similar to those detected in the atmosphere and products containing PCBs, but different from those in the MSW incineration gas. Received: August 26, 1998 / Accepted: March 2, 1999  相似文献   

12.
Finding environmentally benign methods related to sound municipal solid waste (MSW) management is of highest priority in Southeast Asia. It is very important to study new approaches which can reduce waste generation and simultaneously enhance energy recovery. One concrete example of particular significance is the concept of hybrid dual-fuel power plants featuring MSW and another high-quality fuel like natural gas. The hybrid dual-fuel cycles provide significantly higher electrical efficiencies than a composite of separate single-fuel power plant (standalone gas turbine combined cycle and MSW incineration). Although hybrid versions are of great importance for energy conversion from MSW, an economic assessment of these systems must be addressed for a realistic appraisal of these technologies. This paper aims to further examine an economic assessment and energy model analysis of different conversion technologies. Energy models are developed to further refine the expected potential of MSW incineration with regards to energy recovery and environmental issues. Results show that MSW incineration can play role for greenhouse gas reduction, energy recovery and waste management. In Bangkok, the electric power production via conventional incineration and hybrid power plants can cover 2.5% and 8% of total electricity consumption, respectively. The hybrid power plants have a relative short payback period (5 years) and can further reduce the CO2 levels by 3% in comparison with current thermal power plants.  相似文献   

13.
Nitrogen evolution was studied during the co-combustion of hydrothermally treated municipal solid wastes (HT MSW) and coal in a bubbling fluidized bed (BFB). HT MSW blending ratios as 10%, 20% and 30% (wt.%) were selected and tested at 700, 800, 900 °C. Emissions of NO and N2O from blends were measured and compared with the results of mono-combustion trials. Moreover, concentrations of precursors like NH3 and HCN were also quantified. The results are summarized as follows: NO emissions were predominant in all the cases, which rose with increasing temperature. The blending of HT MSW contributed to the NO reduction. N2O emissions decreased with temperature rising and the blending of HT MSW also presented positive effects. At 30% HT MSW addition, both NO and N2O emissions showed the lowest values (391.85 ppm and 55.33 ppm, respectively at 900 °C). For the precursors, more HCN was detected than NH3 and both played important roles on the gas side nitrogen evolution.  相似文献   

14.
The uptake in Europe of Energy from Waste (EfW) incinerator plants has increased rapidly in recent years. In the UK, 25 municipal waste incinerators with energy recovery are now in operation; however, their waste supply chains and business practices vary significantly. With over a hundred more plant developments being considered it is important to establish best business practices for ensuring efficient environmental and operational performance. By reviewing the 25 plants we identify four suitable case study plants to compare technologies (moving grate, fluidised bed and rotary kiln), plant economics and operations. Using data collected from annual reports and through interviews and site visits we provide recommendations for improving the supply chain for waste incinerators and highlight the current issues and challenges faced by the industry. We find that plants using moving grate have a high availability of 87–92%. However, compared to the fluidised bed and rotary kiln, quantities of bottom ash and emissions of hydrogen chloride and carbon monoxide are high. The uptake of integrated recycling practices, combined heat and power, and post incineration non-ferrous metal collections needs to be increased among EfW incinerators in the UK. We conclude that one of the major difficulties encountered by waste facilities is the appropriate selection of technology, capacity, site, waste suppliers and heat consumers. This study will be of particular value to EfW plant developers, government authorities and researchers working within the sector of waste management.  相似文献   

15.
Waste-to-energy is one effective waste management approach for a sustainable society. The purpose of this study was to clarify the potential for energy recovery and greenhouse gas (GHG) reduction that could be achieved by introducing anaerobic digestion (AD) facilities in the process of reconstructing aging incineration facilities in Japan. Using statistical data from 1068 incineration facilities, four future scenarios were considered and compared with the current situation. As results, compared with the current situation the amount of electricity generated could increase by 60 % in 2030, by combining AD facilities for food waste with new, high-efficiency incineration facilities for remaining municipal solid waste (MSW). From a life cycle perspective, net energy recovery in 2030 was approximately three times greater than in 2011, and GHG emission could be reduced by 27 %. The introduction of AD facilities is attractive for small authorities, which currently treat <100 t/day of MSW through incineration facilities without energy recovery. An AD facility is also beneficial for large authorities. On the contrary, in middle-scale authorities that treat 100–299 t/day of MSW, the reconstruction of incineration facilities to include electricity production capabilities requires careful consideration, because it will significantly influence energy recovery and GHG reduction effects.  相似文献   

16.
Mechanical biological treatment (MBT) is an effective technique, which removes organic carbon from municipal solid waste (MSW) prior to deposition. Thereby, methane (CH4) production in the landfill is strongly mitigated. However, direct measurements of greenhouse gas emissions from full-scale MBT landfills have not been conducted so far. Thus, CH4 and nitrous oxide (N2O) emissions from a German MBT landfill in operation as well as their concentrations in the landfill gas (LFG) were measured. High N2O emissions of 20–200 g CO2 eq. m?2 h?1 magnitude (up to 428 mg N m?2 h?1) were observed within 20 m of the working face. CH4 emissions were highest at the landfill zone located at a distance of 30–40 m from the working face, where they reached about 10 g CO2 eq. m?2 h?1. The MBT material in this area has been deposited several weeks earlier. Maximum LFG concentration for N2O was 24.000 ppmv in material below the emission hotspot. At a depth of 50 cm from the landfill surface a strong negative correlation between N2O and CH4 concentrations was observed. From this and from the distribution pattern of extractable ammonium, nitrite, and nitrate it has been concluded that strong N2O production is associated with nitrification activity and the occurrence of nitrite and nitrate, which is initiated by oxygen input during waste deposition. Therefore, CH4 mitigation measures, which often employ aeration, could result in a net increase of GHG emissions due to increased N2O emissions, especially at MBT landfills.  相似文献   

17.
In this study, mercury (Hg) leaching characteristics of the waste treatment residues (fly ash, bottom ash, sludge, and phosphor powder) generated from various sources (municipal, industrial, medical waste incinerators, sewage sludge incinerator, oil refinery, coal-fired power plant, steel manufacturing plant, fluorescent lamp recycler, and cement kiln) in Korea were investigated. First, both Hg content analysis and toxicity characteristic leaching procedure (TCLP) testing was conducted for 31 collected residue samples. The Hg content analysis showed that fly ash from waste incinerators contained more Hg than the other residue samples. However, the TCLP values of fly ash samples with similar Hg content varied widely based on the residue type. Fly ash samples with low and high Hg leaching ratios (RL) were further analyzed to identify the major factors that influence the Hg leaching potential. Buffering capacity of the low-RL fly ash was higher than that of the high-RL fly ash. The Hg speciation results suggest that the low-RL fly ashes consisted primarily of low-solubility Hg compounds (Hg2Cl2, Hg0 or HgS), whereas the high-RL fly ashes contain more than 20% high-solubility Hg compounds (HgCl2 or HgSO4).  相似文献   

18.
We discuss the current status of waste to power generation (WPG) in Japan and various scenarios involving indirect reduction of carbon dioxide emissions by WPG. The number of WPG facilities domestically as of 2005 was 286. Power generation capacity attained 1,515 MW and power generation 7,050 GWh/year. This amount substitutes energy otherwise acquired from natural resources such as fossil fuels in thermal power plants. If the basic unit of carbon dioxide is 0.555 kg-CO2/kWh, then the corresponding carbon dioxide emission reduction is calculated to be 3.9 million tons, equivalent to 26.7% of the 14.6 million tons emitted by municipal solid waste incinerators (MSWI) in 2005. Using various existing technological options, the power generation efficiency could reach more than 20% in MSWI facilities with capacity of 300 tons/day, although present efficiency is only 12.0%. If about 85% of MSW were incinerated in MSWI with power generation efficiency of 20% as a feasible assumption, the total power generation and the corresponding carbon dioxide reduction would be 16,540 GWh/year and 9.18 million tons, respectively, equivalent to 62.7% of the carbon dioxide emitted by MSWI. Also, the ratio of the additional reduction of carbon dioxide emissions by WPG to the total additional reduction (20,000 ktons/year) in Japan during the first commitment period would be 26.3%, suggesting that promotion of WPG in MSWI is an effective option for prevention of global warming.  相似文献   

19.
Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are emitted in trace amounts from municipal solid waste (MSW) incinerators. The exposure to PCDD/Fs experienced by an individual is dominated by the food chain pathway, which accounts for over 98% of the total uptake. Defining a target daily intake (the World Health Organization TDI of 10 pg I-TEQ kg.bw−1day−1) exposure assessment algorithms were then applied to arrive at the corresponding PCDD/F levels in air, soil, plants, food products, etc., which would allow the target intake to be met while retaining the balance of intake between the various exposure pathways. These concentrations were converted to an ambient air concentration of PCDD/Fs and ultimately, by defining criteria for acceptability, to a guide value for PCDD/F concentration in emissions from the MSW incinerator. This strategy was applied to PCDD/F emissions from MSW incinerators of various sizes against two illustrative criteria for acceptability: an “insignificant” release and a threshold above which the release may require further assessment for environmental effects and for control. Using the criteria developed in this paper, the current PCDD/F emission limit of 0.1 ng I-TEQ m−3results in an emission that is classed as “insignificant” for all plant sizes. However, higher emission concentrations can also be accommodated below the threshold for further assessment and control.  相似文献   

20.
Following the Kyoto protocol with respect to reducing emissions of greenhouse gases emissions, and EU energy policy and sustainability in waste management, there has been an increased interest in the reduction of emissions from waste disposal operations. From the point of view of nitrous oxide (N2O) emissions, waste incineration and waste co-combustion are very acceptable methods for waste disposal. In order to achieve very low N2O emissions from waste incineration, particularly for waste with higher nitrogen content (e.g. sewage sludge), two factors are important: temperature of incineration over 900 degrees C and avoiding the selective non-catalytic reduction (SNCR) de-NO(X) method based on urea or ammonia treatments. The more modern selective catalytic reduction (SCR) systems for de-NO(X) give rise to negligible sources of N2O.  相似文献   

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