Screening of halogenated aromatic compounds in some raw material lots for an aluminium recycling plant

Four samples of scrap raw materials for an aluminium recycling plant were screened for the occurrence of persistent halogenated aromatic compounds. The samples contained waste from handling of electric and electronic plastics, filter dust from electronic crusher, cyclone dust from electronic crusher and light fluff from car shredder. In our screening analyses, brominated flame retardants were observed in all samples. Polybrominated diphenyl ethers (PBDE) were identified in all samples in amounts of 245-67450 ng/g. The major PBDE congeners found were decabromo- and pentabromodiphenyl ethers. 1,1-bis(2,4,6-tribromophenoxy)ethane, hexabromobenzene, ethyl-pentabromobenzene, tetrabromobisphenol-A, pentabromotoluene and dimethyl tetrabromobenzene were observed in all scrap samples. The concentrations of PCBs, PCNs (polychlorinated naphthalenes) and nona- to undecachlorinated terphenyls in some of these scrap samples were remarkably high.     

OPTIONS FOR ENVIRONMENTAL SUSTAINABILITY OF THE CRUDE PALM OIL INDUSTRY IN THAILAND THROUGH ENHANCEMENT OF INDUSTRIAL ECOSYSTEMS

The crude palm oil industry plays an important role in the economic development of Thailand and in enhancing the economic welfare of the population. Despite obvious benefits of this industrial development, it also significantly contributes to environmental degradation, both at the input and the output sides of its activities. On the input side, crude palm oil mills use large quantities of water and energy in the production process. On the output side, manufacturing processes generate large quantities of wastewater, solid waste/by-products and air pollution. Current industrial wastes and recoverable materials are empty fruit bunches, fibers, shells and ash. It is estimated that in 2003, a total of 2.1 million ton of solid wastes/by-products and 2.5 million m³ of wastewater were generated. The concept of the industrial ecosystem points at the potential of industrial waste recycling resembling food chains, food webs and nutrient cycles of nature. Following the notion of industrial ecology crude palm oil mills can develop a number of waste recycling and reuse systems. This paper analyzes the nature of these industrial ecosystems, divided in in-plant ecosystems (clean technology options) and external waste exchange between crude palm oil industries and other economic activities in Thailand.     

中国金属矿产的消费强度与回收潜力分析

从中国金属资源安全的角度来看,优化战略性金属矿产的供应结构,降低一次矿产的对外依存度,通过合理的政策导向有效地增加中国城市矿产开发效率,挖掘废旧金属的回收和利用潜力,是实现矿产资源安全保障的重要前提。本文以铁、铜、铝等三种金属矿产为例,采用美国、英国、法国、德国、日本等五个工业化国家及中国1949—2015年的面板数据,通过构建消费强度、回收密度和寿命分布函数分析了工业化五国金属消费和报废金属回收的历史规律,预测了2016—2030年中国三种金属消费和报废回收的变化趋势。结果显示:(1)五个工业化国家铁、铜、铝金属的消费强度经历了快速上升、平台缓降和较快下降的过程,而回收密度则经历了缓慢上升、较快增长和快速增长的三个阶段,在消费强度与回收密度的第三阶段呈现"脱钩"特征;(2)中国铁、铜、铝三种金属的消费强度大幅增加主要是集中在2000年以后,2015年我国铁、铜、铝的消费强度分别为540 kg/人、8 kg/人和23 kg/人,回收密度分别只有100kg/人、0.5 kg/人和3 kg/人,除铁、铝的消费强度进入平台下降期外,铜消费强度和三种金属回收密度仍处于增长的第一阶段;(3)预计2030年,中国铁、铜、铝的消费强度将分别为450 kg/人、9 kg/人和20 kg/人,仍处在平台缓慢下降阶段,回收密度将分别增加到220kg/人、3 kg/人和5 kg/人,回收密度与消费强度比例分别达到49%、33%和25%。通过对比可知,中国未来社会报废金属回收潜力巨大,如果能加以有效政策引导,加快回收利用,可大大缓解中国战略性金属的安全保障压力。     

Ecological and economical assessment of end‐of‐life waste recycling in the electrical and electronic recovery sector

Technological innovation and shorter product life cycles of electrical and electronic equipment coupled with their rapidly growing applications have resulted in the generation of an enormous amount of waste from electrical and electronic equipment (WEEE). To address the potential environmental problems that could stem from improper end‐of‐life management of WEEE, many countries have drafted national legislation to improve the reuse, remanufacture and material recycling from WEEE, and to reduce the amount of such waste going to landfills. With the introduction of such legislation comes an increased need for the recovery operators to evaluate the recycling costs and environmental benefits of reclaimed products and materials in order to select the most appropriate end‐of‐life options for individual products in WEEE. This paper presents a systematic methodology for ecological and economical assessment to provide a holistic understanding of the impacts associated with different end‐of‐life options for such waste. This assessment, in addition to providing decision‐support for the selection of the best possible end‐of‐life option for a particular product in WEEE, could also generate vital information to support the design and material selection processes during the initial product development activities. The assertion made is that the detailed considerations of the ecological and economical impacts associated with different end‐of‐life options will significantly improve the recovery and recycling of WEEE.     

Environmental and economic benefit of recycling model of packaging waste:a case study on aluminum

In order to achieve sustainable utilization of natural resources, save energy and protect environment and ecosystem, it is important for a region or a nation to develop and implement a viable waste recycling model from both theoretical and practical point of view. Some packaging recycling models operated in developed countries are introduced in this article. Aluminium can recovery and recycling is emphasized. Cost effective, economic and environmental benefit of different models are compared and analyzed. The result shows that all recycling models have their characteristics due to the initial purpose of recovery and the situation of the implementing country. However, all the models contribute to the reduction of municipal solid waste disposal and resources conservation.     

The application of system dynamics in different practices of a waste management system

The continuous increase in waste generation warrants global management of waste to reduce the adverse economic, social, and environmental impact of waste while achieving goals for sustainability. The complexity of waste management systems due to different waste management practices renders such systems difficult to analyze. System dynamics (SD) approach aids in conceptualizing and analyzing the structure, interactions, and mode of behavior of the complex systems. The impact of the underlying components can therefore be assessed in an integrated way while the impact of possible policies on the system can be studied to implement appropriate decisions. This review summarizes various applications of SD pertinent to the waste management practices in different countries. Practices may include waste generation, reduction, reuse/recovery, recycling, and disposal. Each study supports regional-demanding targets in environmental, social, and economic scopes such as expanding landfill life span, implementing proper disposal fee, global warming mitigation, energy generation/saving, etc. The interacting variables in the WMS are specifically determined based on the defined problem, ultimate goal, and the type of waste. Generally, population and gross domestic product can increase the waste generation. An increase in waste reduction, source separation, and recycling rate could decrease the environmental impact, but it is not necessarily profitable from an economic perspective. Incentives to separate waste and knowledge about waste management are variables that always have a positive impact on the entire system.

     

Environmental and economic benefit of recycling model of packaging waste: a case study on aluminum

Abstract

In order to achieve sustainable utilization of natural resources, save energy and protect environment and ecosystem, it is important for a region or a nation to develop and implement a viable waste recycling model from both theoretical and practical point of view. Some packaging recycling models operated in developed countries are introduced in this article. Aluminium can recovery and recycling is emphasized. Cost effective, economic and environmental benefit of different models are compared and analyzed. The result shows that all recycling models have their characteristics due to the initial purpose of recovery and the situation of the implementing country. However, all the models contribute to the reduction of municipal solid waste disposal and resources conservation.     

Solid waste management in Bogotá: the role of recycling associations as investigated through SWOT analysis

In emerging economies, recycling provides an opportunity for cities to increase the lifespan of sanitary landfills, to reduce the costs of solid waste management, to decrease environmental problems from waste treatment by reincorporating waste into the productive cycle and to protect and develop the livelihoods of citizens who work as informal waste pickers. However, few studies have analysed the possibilities of and strategies for integrating the formal and informal sectors in solid waste management for the benefit of both. This integration is the key, especially in developing countries, to understanding how the recycling population can develop a business despite their social and economic limitations. The aim of this study was to perform a strength, weakness, opportunity and threat (SWOT) analysis of three recycling associations in Bogotá with the aim of examining and understanding the recycling situation from the perspective of members of the informal sector in their transition to becoming authorised waste providers. This issue has rarely been studied in the context of developing countries. The data used in the analysis are derived from multiple sources, including a literature review, Bogota’s recycling database, focus group meetings, governmental reports, national laws and regulations and interviews with key stakeholders. The results of this study show that as the primary stakeholders, the formal and informal waste management sectors can identify the internal and external conditions of recycling in Bogotá. Several strategies were designed based on the SWOT analysis. The participation of recycling associations is important in the design and application of waste policy, the consolidation of recycling through an effective business model, promotional programmes for social inclusion and the development of new transformation processes and technologies to valorise recycling materials. In conclusion, recycling associations can become authorised waste providers through a profitable business that increases recycling rates to create a productive process from waste during the generation of new materials and to decrease environmental problems while improving the welfare and living conditions of recyclers. These findings are important for Bogotá to advance and promote recycling as a key strategy for integrated sustainable waste management in the city.     

基于农户兼业视角的农业废弃物资源循环利用意愿及其影响因素比较

基于农户兼业视角,利用湖北省农村地区的微观调查数据,运用Logistic回归模型比较了不同兼业类型农户农业废弃物资源循环利用意愿及其影响因素。研究结果显示：（1）大部分农户具有农业废弃物资源循环利用意愿,其中纯农户和一兼农户的利用意愿相当,且高出二兼农户;（2）农户对农业废弃物资源价值的感知是影响不同兼业类型农户利用意愿的共同因素,农户感知农业废弃物资源的价值越高,其利用意愿也越强;（3）影响不同兼业类型农户利用意愿的因素有明显差异,性别对农户尤其是二兼农户的利用意愿有显著的正向作用;年龄对纯农户和二兼农户利用意愿的影响均为负,尤其是对纯农户影响更大;土地经营规模对农户尤其是一兼农户的利用意愿有显著的正向影响;对获取经济收益的感知正向作用于一兼农户和二兼农户的利用意愿,尤其是对一兼农户有更大程度影响;对纯农户而言,对自身经济条件的感知也显著影响其利用意愿     

Introduction of a recycling system for sustainable municipal solid waste management: a case study on the greater Banjul area of the Gambia

This research proposes for the introduction of a recycling system in the Gambia to enhance sustainable municipal solid waste management. Poor infrastructures, coupled with inadequate resources and lack of funding, work against the optimization of a MSW disposal service. In the authors’ view, authorities in charge of waste management need to change not only behaviors, but modernize their processes. Recycling technology is a key part of the solution. A model has been developed which suggest the involvement of stakeholders to achieve meaningful sustainable MSWM. This can be achieved by recognizing the role of the informal sector through community-based organizations, Non-Governmental Organizations (NGOs), and the private sector. The open dump approach is leading to severe environmental consequences as the groundwater and soil within the dump is been contaminated. In this study, an integrated municipal solid waste management approach was developed with a model to help achieve sustainable municipal solid waste management. Resource recovery, not waste disposal, must be the ultimate goal with clearly defined end user markets so that the recovery loop is complete. Mandatory sorting of waste at household level would help greatly in making recycling activity successful.     

Life cycle sustainability assessments (LCSA) of four disposal scenarios for used polyethylene terephthalate (PET) bottles in Mauritius

Improper disposal of post-consumer Polythylene Terephthalate (PET) bottles constitutes an eyesore to the environmental landscape and gives rise to numerous environmental and health-related nuisances. These problems impact negatively on the flourishing tourism industry in Mauritius. The present study was therefore undertaken to determine a sustainable disposal method among four selected disposal alternatives of post-consumer PET bottles in Mauritius. The disposal scenarios investigated were: 100 % landfilling (scenario 1); 75 % incineration with energy recovery and 25 % landfilling (scenario 2); 40 % flake production (partial recycling) and 60 % landfilling (scenario 3); and 75 % flake production and 25 % landfilling (scenario 4). Environmental impacts of the disposal alternatives were determined using ISO standardized life cycle assessment (LCA) and the SimaPro 7.1 software. Cost-effectiveness was determined using Life cycle costing (LCC) as described by the recent Code of Practice on LCC. An excel-based model was constructed to calculate the various costs. Social impacts were evaluated using Social Life Cycle Assessment (S-LCA) based on the UNEP/SETAC Guidelines for Social Life Cycle Assessment. For this purpose, a new and simple social life cycle impact assessment method was developed for aggregating inventory results. Finally, Life Cycle Sustainability Assessment (LCSA) was conducted to conclude the sustainable disposal route of post-consumer PET bottles in Mauritius. The methodology proposed to work out LCSA was to combine the three assessment tools: LCA, LCC and S-LCA using the Analytical Hierarchy Process. The results indicated that scenario 4 was the sustainable disposal method of post-consumer PET bottles. Scenario 1 was found to be the worst scenario.     

Factors affecting incentive dependency of residents to participate in e-waste recycling: a case study on adoption of e-waste reverse supply chain in Iran

Modern societies face a dilemma called electronic waste (e-waste). This waste, which may contaminate the soil or cause unwanted impacts on human health when treated improperly, is one of the fastest growing waste streams in developed as well as developing countries and has brought great environmental impacts. Developing countries like Iran also face this modern waste management challenge. In order for more appropriate disposal or, if possible, recycling of this waste, more attention has been paid to reverse logistics as the most appropriate way to manage them. The first and most important action to address e-waste and implementation of reverse logistics is to persuade residents to bring back their obsolete electronic products. This paper attempts to understand significant factors affecting residents’ incentive dependency to participate in e-waste recycling program. Socioeconomic and demographic information of different residents is discussed by means of logistic regression for the first time in Iran. The results show that about 58.7 % of residents will participate even if no incentive is given. Household income, household size, education, e-waste concern level, and marital status are the significant factors affecting the incentive dependency of respondents.     

Reverse logistics network design: a conceptual framework for decision making

Reverse logistics play a significantly increased role in supply chains. Producers are incorporating reverse logistics into their supply chain design because of governmental legislation, economic benefits from product recovery, and customers' demands for better environmental practices. Motivated producers face two main challenges in reverse logistics network design: (1) how do you build product recovery activities into traditional forward logistics networks? and (2) how do you manage the impact of uncertainty in the reverse logistics supply chain? Moreover, producers need to consider many tradeoffs leading to efficient network design. Published case studies have discussed these tradeoffs, and we describe a framework to evaluate these tradeoff considerations. We then apply the framework to three new case studies: medical device refurbishing, municipal e‐waste recycling, and carpet fibre recycling.     

我国废钢铁资源的可持续利用政策

本文概述了我国废钢铁资源回收利用的现状以及钢铁工业对废钢铁资源的需求现状，用三种不同的模型预测了未来钢铁工业的发展对废钢铁资源的需求，提出了废钢铁资源可持续利用存在的问题和政策建议。     

Mercury risk from fluorescent lamps in China: Current status and future perspective

Energy-efficient lighting is one of the key measures for addressing electric power shortages and climate change mitigation, and fluorescent lamps are expected to dominate the lighting market in China over the next several years. This review presents an overview on the emissions and risk of mercury from fluorescent lamps during production and disposal, and discusses measures for reducing the mercury risk through solid waste management and source reduction. Fluorescent lamps produced in China used to contain relatively large amounts of mercury (up to 40 mg per lamp) due to the prevalence of liquid mercury dosing, which also released significant amounts of mercury to the environment. Upgrade of the mercury dosing technologies and manufacturing facilities had significantly reduced the mercury contents in fluorescent lamps, with most of them containing less than 10 or 5 mg per lamp now. Occupational hygiene studies showed that mercury emissions occurred during fluorescent lamp production, particularly in the facilities using liquid mercury dosing, which polluted the environmental media at and surrounding the production sites and posed chronic health risk to the workers by causing neuropsychological and motor impairments. It is estimated that spent fluorescent lamps account for approximately 20% of mercury input in the MSW in China. Even though recycling of fluorescent lamps presents an important opportunity to capture the mercury they contain, it is difficult and not cost-effective at reducing the mercury risk under the broader context of mercury pollution control in China. In light of the significant mercury emissions associated with electricity generation in China, we propose that reduction of mercury emissions and risk associated with fluorescent lamps should be achieved primarily through lowering their mercury contents by the manufacturers while recycling programs should focus on elemental mercury-containing waste products instead of fluorescent lamps to recapture mercury from the waste stream cost-effectively.     

Fuel from waste tyres and particulate matter emitted from the process

The interest in obtaining alternative fuels from waste sources and at the same time diminishing the impact of waste disposal has drawn attention to scrap tyres' carbon recovery. In order to thermally degrade used tyre rubber, a laboratory pyrolysis system was developed in this work. The installation devised focused on the production of liquid pyrolysates, where shredded rubber was supplied as the feedstock and nitrogen used as the carrier gas to provide an oxygen-free atmosphere. The variables affecting the performance of the process were investigated, including target temperature, heating rate and total residence time. Characterization of the volatile matter released was conducted by means of mass spectrometry to determine the composition of products, and particulate matter analysis to ascertain the aerosol content in the gas stream. The reproducibility of experiments, the influence of the temperature and time, and differences between the vapours before condensation and the exhaust gases are discussed. This work identified that the larger hydrocarbon fragments condense to constitute the oils, whereas the lighter molecules remain as non-condensable gases. This work also identified that the total number of nano-scale particles carried by the exhaust stream varies with temperature; significant changes in the composition of products and particle content were reported at approximately 400°C. The high number of nano-scale solid particulate matter present in the exhaust gases suggests that a thorough treatment for that stream would be required to avoid human health hazards.     

Double Green Process: a low environmental impact method for recycling of CdTe,a-Si and CIS/CIGS thin-film photovoltaic modules

On the basis of the method for managing the end of life of CdTe photovoltaic panels previously proposed by the authors, a new method for the recycling of all types of thin-film panels (CdTe, a-Si and CIS/CIGS) has been developed and optimised under a research project founded by Enel Foundation and CRUI Foundation. The DGP process has been developed through a feasibility study carried out from three points of view: technical, environmental and economic. The process is composed by two sub-processes matched to each other, one suitable for CdTe panels (named DGPa) and the other one for a-Si and CIS/CIGS panels (DGPb). The Double Green Panel process is based mainly on mechanical treatments with a minimum use of chemicals and it is characterised by a greater level of automation and a high flexibility in production capacity. The potential environmental impacts of various configurations of the DGP process have been extensively analysed with LCA tool in order to develop an environmentally friendly process. The economic feasibility has been assessed through the Discounted Cash Flow Analysis (DCFA) method. The revenues associated to the recovery of valuable and common materials and the recycling costs have been taken into account.     

Study of fluxing in Al refining process by rotary and crucible furnaces

The process used to obtain recycled Al alloys depends on the scrap quality. Rotary furnaces are normally used in Europe as they allow a great productivity and they can process low quality scrap using a salt flux to protect the molten metal from oxidation. In this article, the effect of the quantity of salt on the metal recovery has been experimentally investigated by melting several types of scrap under a mixture of NaCl–KCl–Na₃AlF₆ salts. The quantity of salt has been related to the salt factor (SF), which is the ratio between the non-metallic content in the scrap and the quantity of salt required. The same levels of salt factor have been tested by melting the scrap in rotary and crucible furnaces. The metal recovery increases with the salt content for both furnaces. The results obtained with the different melting processes are comparable because the yield difference is similar considering different salt factors. Crucible furnace gives greater metal recovery but it cannot replace rotary furnace in Al refining industry due to lower melting capacity. However, the results highlight that the optimisation of the Al refining process can be supported by preliminary tests through crucible furnaces reducing the time and material consumptions.     

Evaluating the sustainability potential of a white goods refurbishment program

A sustainable national policy on waste electronic and electrical equipment reuse has to ensure an integrated environmental economic and social approach. In this paper, a quantitative model is developed that permits a comparative analysis of re-use and non-re-use scenarios from an environmental and economic perspective. The model demonstrates the importance of considering user consumption profiles and the changing national electricity generation portfolio in determining the best end-of-life strategy, whether it should be reuse or recycling. A case study of Ireland is used to demonstrate the model. From a social perspective, qualitative aspects of reuse, such as the job creation potential and the impact on prosperity for low income families, are also considered. Reuse of white goods, if conducted through social enterprises, will create more employment than an equivalent amount of recycling for those most vulnerable to unemployment. Any environmental and social dividends from re-use can be realized only in the context of an economically sustainable system. This would include such factors as a secure supply of suitable equipment, a competitive cost base and sufficient revenues from sales and other sources in order for the business to survive. In an attempt to examine whether a white goods re-use program could possibly operate in a competitive manner with new appliances, this study has examined examples of comparable businesses operating in the EU as well as interpreting data on consumer demand.     

循环经济园区发展的技术经济分析

建设资源节约型、环境友好型社会,必须大力发展循环经济。通过剖析江西星火工业园发展循环经济案例,对循环经济园区的发展进行了技术经济分析。循环经济园区是一种先进的生产组织形式,在园区内,上游企业的废弃物或副产品成为下游企业的原料,新的产业链得到延伸,逐步形成产业网,节省了自然资源,减少环境污染;基础设施、公共服务和知识信息得到共享,交易费用减少,提高了企业综合效益。园区以物质与能量循环利用为目标、以产业集群为载体,通过专业化分工和全面合作,经济、社会和生态环境效益显著。