共查询到20条相似文献,搜索用时 15 毫秒
1.
黄健 《石油化工环境保护》1998,(1):43-45
通过碱渣与废酸溶液的中和反应室内试验和碱渣与中和溶液在75℃和50℃条件下通风12小时的氧化反应的室内试验,碱液的硫化物含量可降至120mg/L以下,pH值降至8.5~9.0,提出工业生产的工艺流程,彻底根治碱渣冲击污水处理系统的现象。 相似文献
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SBR工艺处理城市垃圾渗滤液的可行性分析 总被引:10,自引:0,他引:10
在参考国内外垃圾渗滤液的处理方案后,选择厌氧预处理 SBR工艺作为处理方案,通过实验对该废水处理的情况来看,该工艺较好地适应了垃圾渗滤液的处理特点,能达到比较良好的效果。 相似文献
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废水处理仿真基准模型BSM1简介 总被引:2,自引:0,他引:2
文章比较详细地介绍了欧盟科学技术合作组织所研究的项目中,一个关于水处理的仿真基准模型(BSM1)。该模型建立在活性污泥法处理废水的基础之上,所选择的建模对象是一种简单常见的生物反应器和二次沉淀池组成的活性污泥水处理系统,致力于C、N的去除。应用该模型可以很方便地进行水处理控制方案之间的效果比较,对于世界各地的水处理研究机构之间的沟通有很大的帮助。文章结尾部分还对该模型存在的缺陷和今后的发展方向做了分析。 相似文献
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This study revealed the relationship between the presence of calcium impurities and ammoniacal nitrogen concentration upon crystallization of struvite. The research hypothesis was that the presence of both calcium and high concentrations of ammoniacal nitrogen(328–1000 mg/L) in waste activated sludge may influence the struvite quality and acid stability. Hence, we studied the impact of Ca:Mg ratio upon morphology, particle size, purity and dissolution of struvite, in the presence of varying levels of excess ammoniacal nitrogen. X-ray diffraction revealed that up to 31.4%amorphous material was made which was assigned to hydroxyapatite. Increasing the ammoniacal nitrogen concentration and elevation of the Mg:Ca ratio maximized the presence of struvite. Struvite particle size was also increased by ammoniacal nitrogen as was twinning of the crystals. Tests with dilute solutions of organic acid revealed the sensitivity of struvite dissolution to the physical characteristics of the struvite. Smaller particles(21.2 μm) dissolved at higher rates than larger particles(35.86 μm). However,struvite dissolved rapidly as the p H was further reduced irrespective of the physical characteristics. Therefore, addition of struvite to low p H soils was not viewed as beneficial in terms of controlled nutrient release. Overall, this study revealed that waste activated sludge effluent with high ammoniacal nitrogen was prospective for synthesis of high quality struvite material. 相似文献
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Yu Zhang Jiayi Tang Weijun Zhang Jing Ai Yanyang Liu Qiandi Wang Dongsheng Wang 《环境科学学报(英文版)》2021,33(8):83-96
In this work, we employed waste activated sludge (WAS) as carbon source to prepare ultrahigh specific surface area (SSA) biopolymers-based carbons (BBCs) through alkali (KOH) treatment coupled to pyrolysis strategy. Before the pyrolysis process, the involvement of KOH made a great recovery of soluble biopolymers from WAS, resulting in highly-efficient catalytic pyrolysis. The Brunner-Emmett-Teller and pore volume of BBCs prepared at 800°C (BBC800) reached the maximum at 2633.89 m2·g?1 and 2.919 m3·g?1, respectively. X-ray photoelectron spectroscopy suggested that aromatic carbon in the form of C=C was the dominant fraction of C element in BBCs. The N element in BBCs were composed of pyrrolic nitrogen and pyridinic nitrogen at 700°C, while a new graphitic nitrogen appeared over 800°C. As a refractory pollutant of wastewater treatment plants, tetracycline (TC) was selected to evaluate adsorption performance of BBCs. The adsorption behavior of BBCs towards TC was conformed to the pseudo-second-order kinetic and the Langmuir models, signifying that chemisorption of monolayers was dominant in TC adsorption. The adsorption capacity of BBC800 reached the maximum at 877.19 mg·g?1 for 90 min at 298 K. Thermodynamic analysis indicated that the adsorption process was endothermic and spontaneous. Hydrogen bonding and π-π stacking interaction were mainly responsible for TC adsorption, and interfacial diffusion was the main rate-control step in adsorption process. The presence of soluble microbial products (SMPs) enhanced TC removal. This work provided a novel strategy to prepare bio-carbon with ultrahigh SSA using WAS for highly-efficient removal of organic pollutants. 相似文献
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湿式氧化处理剩余污泥反应动力学研究 总被引:1,自引:0,他引:1
针对剩余污泥湿式氧化处理过程。以污泥中挥发分的去除为目标污染物,进行了化工废水剩余污泥.炼油废水剩余污泥湿式氧化过程动力学研究,并对湿式氧化两阶段一级动力学模型和广义动力学模型的动力学进行求解。两阶段一级动力学模型说明化工污泥.炼油污泥湿式氧化过程均属于快速反应期接慢速反应期。但不同污泥其活化能和指前因子相差较大:而用广义动力学模型可以建立通用的剩余污泥湿式氧化反应速率方程,该模型应用于城市废水剩余污泥湿式氧化过程,计算值与试验值有很好的相关性(P^2≥0.98)。 相似文献
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因污水量增加,汾酒厂污水处理站于 2 0 0 1年扩建。建成后污水站处理能力达 80 0 0m3 d。扩建部分不仅工艺流程与原系统相同,而且充分挖掘原有构、建筑物的潜力。该处理工艺技术成熟,运行稳定,出水水质优于设计要求 相似文献
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李健光 《石油化工环境保护》2006,29(3):4-7
荆门石化污水处理场采用氧化沟处理工艺。针对在处理炼油污水过程中发生的污泥膨胀现象,根据运行数据,对活性污泥膨胀的原因进行分析和讨论,并提出建议。 相似文献
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城市污水处理厂污泥制活性炭的研究 总被引:29,自引:0,他引:29
经对天津东郊污水处理厂的污泥性质和组成测试 ,研究了以城市污水厂污泥为基本原料、氯化锌为活化剂采用传统活性炭制备工艺的污泥活性炭制备技术 .选取活化剂浓度、固液比、活化温度及活化时间等因素 ,通过正交试验确定了最佳工艺条件 .结合比表面积、孔径分布和扫描电镜表征分析 ,对制备的污泥活性炭进行性能评价 ,并初步探讨了污泥活性炭作为水处理吸附剂的去除效果 .结果表明 :在最佳工艺条件 4 0 %氯化锌溶液为活化剂、活化时间 2 0min、活化温度 6 0 0℃、固液比为 1∶2~ 1∶3的条件下 ,制备的污泥活性炭碘吸附值为 5 14~ 5 4 2mg/ g ,大孔、中孔、微孔容积分别为 0 39~ 0 5 3mL/g、0 10~ 0 15mL/ g、0 15~ 0 2 3mL/ g ,比表面积为 193~ 2 5 6m2 / g .将污泥活性炭处理COD为 2 4 0 0mg/L、色度 2 5 0的制药废水 ,COD去除率 >87%、色度去除率 >80 % . 相似文献
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采用中试规模(10t/d)的厌氧-好氧膜生物反应器(A/O MBR)处理毛纺印染废水.当HRT为7h,进水COD、BOD5分别为179~358mg/L和44.8~206mg/L,试验系统对COD、BODs、色度、浊度的平均去除率分别为92.1%、98.4%、60.7%、98.9%,出水水质浓度或指标值分别为20.2mg/L、1.6mg/L、25倍、0.51 NTU.出水水质指标达到建设部生活杂用水水质标准(CJ25.1-89).A/O MBR工艺处理毛纺印染废水技术可行、操作简单、易于管理,可为工业规模应用提供技术参考. 相似文献
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驯化活性污泥处理高含盐量有机废水研究 总被引:9,自引:0,他引:9
工业废水的高含盐量对生物处理有强抑制作用,该文利用驯化活性污泥对此类废水进行有 机物降解试验,试验表明,含盐量和有机负荷在一定范围内,对化活性污泥并明显抑制作用,COD去除率稳定在90%以上,BOD去除率稳定在93%以上,半速率常数Ks=340mg/L,最大比降解速度K=1.96/d。驯化活性污泥以菌胶团为主,菌落形态相对较少。同时有少量原生动物,主要以纤毛虫中的裂口虫和漫游虫为主。 相似文献
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Millions of tons of waste activated sludge (WAS) produced from biological wastewater treatment processes cause severe adverse environmental consequences. A better understanding of WAS composition is thus very critical for sustainable sludge management. In this work, the occurrence and distribution of several fundamental sludge constituents were explored in WAS samples from nine full-scale wastewater treatment plants (WWTPs) of Beijing, China. Among all the components investigated, active heterotrophic biomass was dominant in the samples (up to 9478 mg/L), followed by endogenous residues (6736 mg/L), extracellular polymeric substances (2088 mg/L), and intracellular storage products (464 mg/L) among others. Moreover, significant differences (p < 0.05) were observed in composition profiles of sludge samples among the studied WWTPs. To identify the potential parameters affecting the variable fractions of sludge components, wastewater source as well as design and operational parameters of WWTPs were studied using statistical methods. The findings indicated that the component fraction of sewage sludge depends more on wastewater treatment alternatives than on wastewater characteristics among other parameters. A principal component analysis was conducted, which further indicated that there was a greater proportion of residual inert biomass in the sludge produced by the combined system of the conventional anaerobic/anoxic/oxic process and a membrane bioreactor. Additionally, a much longer solids retention time was also found to influence the sludge composition and induce an increase in both endogenous inert residues and extracellular polymeric substances in the sludge. 相似文献
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治理橡胶废水的活性污泥模型研究 总被引:3,自引:1,他引:3
采用模拟曝气工艺研究了活性污泥对橡胶厌氧废水的CODcr,NH3-N的降解条件,确定了最佳的曝气时间,污泥浓度及溶解氧浓度与处理效果的关系。 相似文献
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用Matlab/Simulink建立废水处理仿真模型 总被引:1,自引:0,他引:1
国际水质协会(IWA)和欧盟科学技术合作组织(COST)合作开发的活性污泥废水处理基准仿真模型BSM1(benchmark sim-ulation model NO.1),主要目的是为了建立一个活性污泥过程控制方案的开发平台。文章比较详细的介绍了如何用Matlab和Simulink建立BSM1,对于如何得到正确的开环仿真结果给出了详细的说明,并将两种建模方式在仿真结果、仿真速度、建模的难易程度等方面进行了比较。 相似文献
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同步测定了超声处理过程中污泥破解程度、微生物活性、颗粒大小等参数的变化,并分析了不同参数之间的内在联系及超声参数对污泥微生物活性的影响.结果表明,污泥颗粒的超声处理过程可以分为2个阶段:首先絮体破碎为直径十几μm的小凝集体,胞外有机质溶出,微生物游离出来,活性增强;随后小凝集体被进一步破坏,污泥颗粒直径降至10μm以下,微生物胞内有机质溶出,活性明显下降.由于污泥的不均匀性,2个阶段并非截然分开,短时间内,污泥破解程度低于20%时,以絮体破碎为主,污泥活性提高20%以上;当污泥破解程度在20%~40%之间时,部分微生物开始受到损伤,污泥活性提高不到20%;当污泥破解程度高于40%时,大部分微生物受到损伤,污泥活性迅速下降.低强超声可以在较长处理时间内使大部分污泥颗粒停留在絮体破碎阶段,有效避免微生物的破坏,因此适用于增强污泥微生物活性. 相似文献
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循环式活性污泥法在城市废水处理中的应用 总被引:1,自引:0,他引:1
某县城采用循环活性污泥法处理城市废水,工艺简洁易行,反应时间短,出水SS、BOD5、COD和氨氮去除率分别达90%、90%、85%和70%以上,TP<1.5mg/L,均达到GB18918-2002一级排放标准。 相似文献
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As an important intermediate product, short-chain fatty acids(SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane,most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60 min can achieve the maximal hydrolyzation. Further, effects of different initial p Hs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial p H 9.0with fermentation time of 6 d, the production of which was 348.63 mg COD/g VSS(6.8 times higher than the blank test) and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally,the effect of this low energy consumption pretreatment on methane generation was investigated. 相似文献