Combination with catalyzed Fe(0)-carbon microelectrolysis and activated carbon adsorption for advanced reclaimed water treatment: simultaneous nitrate and biorefractory organics removal

A process combining catalyzed Fe(0)-carbon microelectrolysis (IC-ME) with activated carbon (AC) adsorption was developed for advanced reclaimed water treatment. Simultaneous nitrate reduction and chemical oxygen demand (COD) removal were achieved, and the effects of composite catalyst (CC) addition, AC addition, and initial pH were investigated. The reaction kinetics and reaction mechanisms were calculated and analyzed. The results showed that CC addition could enhance the reduction rate of nitrate and effectively inhibit the production of ammonia. Moreover, AC addition increased the adsorption capacity of biorefractory organic compounds (BROs) and enhanced the degradation of BRO. The reduction of NO₃^?–N at different pH values was consistently greater than 96.9%, and NH₄⁺–N was suppressed by high pH. The presence of CC ensured the reaction rate of IC-ME at high pH. The reaction kinetics orders and constants were calculated. Catalyzed iron scrap (IS)-AC showed much better nitrate reduction and BRO degradation performances than IS-AC and AC. The IC-ME showed great potential for application to nitrate and BRO reduction in reclaimed water.

     

类-Fenton体系对水中17β-雌二醇的光降解

以250W照明金属卤化物灯为光源研究了水中17β雌二醇(E2)在类Fenton体系中的光降解。结果表明,Fe(Ⅲ)/H2O2体系能有效地光降解E2。pH3～6范围内,E2光降解率及反应初始速率随酸度的增大而增大;H2O2初始浓度越大,E2降解率及反应初始速率越大;E2初始浓度越低,E2降解率越高,反应初始速率越低。     

黑龙江省中部漫川漫岗区坡耕地的治理──垄作区田水土保持措施的应用

本文对黑龙江省中部漫川漫岗侵蚀区坡耕地利用现状和采取的水土保持耕作措施进行了总结分析，提出了在黑龙江省坡耕地治理中应用垄作区田技术标准和发展方向。     

钻井环境污染源头控制技术综述

通过对国内外石油行业的钻井环境污染源头控制技术的简单综述,分析了钻井工艺可采用小孔径钻井、连续软管工艺、新型固控设施等的技术特点,对选择合适的钻井液以及应用环保型钻井液来减轻污染方面进行了探讨。并展望了我国石油行业钻井环境污染源头控制技术的发展。     

岷江生态环境问题及其对策研究

本文主要探讨岷江流域的生态环境问题及其对策。全文分为两个部分。(1)研究岷江生态环境问题;(2)解决岷江生态环境问题的主要对策。     

应用模糊聚类方法进行四川国土分区研究

本文介绍采用模糊聚类方法进行四川省国土综合分区研究的情况和主要结果。提出将全省划分为8个国土区的结论,论述了各区的前景,探讨了定性与定量分区方法的先进性。     

新型絮凝剂室内评价试验

通过对比国外的有机絮凝剂和无机絮凝剂复配使用情况,对钻井污水用新型絮凝剂一有机一无机复合絮凝剂ＷＢＹ进行了评价,结果证明该絮凝剂能经济、高效地处理钻井污水。     

一体化-膜生物反应器物理清洗效果的研究

在一体式一膜生物反应器处理生活污水的基础上，考察了运行过程中膜污染情况。试验结果表明，膜外表面沉积污泥是造成膜污染的主要因素，在活性污泥混合液中搓洗膜丝，是一种方便而有效的清洗方式。间歇式运行方式的停抽期间最低剩余抽吸压力可用来表征运行过程中膜过滤性能的变化。     

油气钻井作业对地下水污染治理研究＊

分析了钻井作业对地下水污染的特点、污染途径,针对性地提出了钻井作业对地下水污染的预防措施,以及污染物处理技术,其中氧化还原技术、气体抽取技术、环境生物技术主要用于有机物污染治理,SRB技术、废弃钻井液固化技术、钻井液转换为水泥浆(MTC)的固井技术可用于处理废弃钻井液。钻井引起的污染治理应以"预防为主,防治结合",切实推行清洁生产和HSE管理。     

Electrokinetic removal of chromium and copper from contaminated soils by lactic acid enhancement in the catholyte

The electrokinetic removal of chromium and copper from contaminated soils by adding lactic acid in cathode chamber as an enhancing reagent was evaluated. Two sets of duplicate experiments with chromium contaminated kaolinite and with a silty soil sampled from a supeffund site in Califomia of USA and polluted by Cr and Cu, were carried out in a constant current mode. Changes of soil water content and soil pH before and after the electrokinetic experiments, and variations of voltage drop and electroosmosis flow during the treatments were examined. The results indicated that Cr, spiked as Cr(Ⅵ) in the kaolinite, was accumulated mainly in the anode chamber, and some of Cr and metal hydroxides precipitated in the soil sections in contact with the cathode, which significantly increased electrical energy consumption. Treatment of the soil collected from the site showed accumulation of large amounts of Cr and Cu in the anode chamber while none was detected in the cathode one. The results suggested that the two metals either complexed with the injected lactic acid at the cathode or existed as negatively charged complex, and electromigrated toward the anode under a voltage gradient.