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Lysine is widely used in the fields of food, medicine and feed, which generally appears in the form of lysine sulfate or lysine hydrochloride dust because of the high instability of the free L-lysine. The L-lysine Sulfate is in high risk of decomposition, spontaneous ignition and even the dust explosion, because the control temperature in its production process is high up to 90 °C. Thus, the thermal behaviors and its thermal stability of 65% lysine sulfate are experimentally explored in Air and Nitrogen using the simultaneous TG-DSC measurements. Results show: (1) the decomposition of 65% lysine sulfate can be divided into three stages both in the atmospheres of air and nitrogen, and most of the weight loss occurred in the first two stages, which are related with the decarboxylation and deamination process. (2) The effects of atmosphere on the decomposition of 65% lysine sulfate mainly occur at the third stage. In this stage, the weight loss in nitrogen is only 14.2%, which is much lower than that in air (34.3%), which is related to the oxidative degradation at high temperature. Besides, the active energy is slightly increased in nitrogen compared to that in air. (3) The initial temperatures of the decomposition of the 65% lysine sulfate are 145 °C and 155 °C, for the air and nitrogen atmosphere, respectively, which are much lower than that (260 °C) of the pure lysine. 相似文献
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Afshin Shabani Xiaodong Zhang Xuefeng Chu Timothy P. Dodd Haochi Zheng 《Journal of the American Water Resources Association》2020,56(2):297-309
Devils Lake is a terminal lake located in northeast North Dakota. Because of its glacial origin and accumulated salts from evaporation, the lake has a high concentration of sulfate compared to the surrounding water bodies. From 1993 to 2011, Devils Lake water levels rose by ~10 m, which flooded surrounding communities and increased the chance of an overspill to the Sheyenne River. To control the flooding, the State of North Dakota constructed two outlets to pump the lake water to the river. However, the pumped water has raised concerns about of water quality degradation and potential flooding risk of the Sheyenne River. To investigate these perceived impacts, a Soil and Water Assessment Tool (SWAT) model was developed for the Sheyenne River and it was linked to a coupled SWAT and CE‐QUAL‐W2 model that was developed for Devils Lake in a previous study. While the current outlet schedule has attempted to maintain the total river discharge within the confines of a two‐year flood (36 m3/s), our simulation from 2012 to 2018 revealed that the diversion increased the Sheyenne River sulfate concentration from an average of 125 to >750 mg/L. Furthermore, a conceptual optimization model was developed with a goal of better preserving the water quality of the Sheyenne River while effectively mitigating the flooding of Devils Lake. The optimal solution provides a “win–win” outlet management that maintains the efficiency of the outlets while reducing the Sheyenne River sulfate concentration to ≤600 mg/L. 相似文献
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In this study, the relationship between inhalable particulate (PM10), fine particulate (PM2.5), coarse particles (PM2.5 – 10) and meteorological parameters such as temperature, relative humidity, solar radiation, wind speed were statistically analyzed and modelled for urban area of Kolkata during winter months of 2003–2004. Ambient air quality was monitored with a sampling frequency of twenty-four hours at three monitoring sites located near traffic intersections and in an industrial area. The monitoring sites were located 3–5 m above ground near highly trafficked and congested areas. The 24 h average PM10 and PM2.5 samples were collected using Thermo-Andersen high volume samplers and exposed filter papers were extracted and analysed for benzene soluble organic fraction. The ratios between PM2.5 and PM10 were found to be in the range of 0.6 to 0.92 and the highest ratio was found in the most polluted urban site. Statistical analysis has shown a strong positive correlation between PM10 and PM2.5 and inverse correlation was observed between particulate matter (PM10 and PM2.5) and wind speed. Statistical analysis of air quality data shows that PM10 and PM2.5 are showing poor correlation with temperature, relative humidity and solar radiation. Regression equations for PM10 and PM2.5 and meteorological parameters were developed. The organic fraction of particulate matter soluble in benzene is an indication of poly aromatic hydrocarbon (PAH) concentration present in particulate matter. The relationship between the benzene soluble organic fraction (BSOF) of inhalable particulate (PM10) and fine particulate (PM2.5) were analysed for urban area of Kolkata. Significant positive correlation was observed between benzene soluble organic fraction of PM10 (BSM10) and benzene soluble organic fraction of PM2.5 (BSM2.5). Regression equations for BSM10 and BSM2.5 were developed. 相似文献
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联合运用聚铁混凝-臭氧-曝气生物滤池(BAF)对晚期垃圾场的渗滤液进行深度处理。在废水进水COD=601mg/L,色度=400倍时,提出最佳工艺条件:聚铁0.6 mL/L,臭氧用量144 mg/L,BAF停留时间7 h。研究表明,聚铁去除大部分悬浮性有机物,臭氧降解难生物降解有机物并提高废水的可生化性,BAF进一步降解有机物,最终出水COD为75 mg/L,深度处理成本仅为5.5元/t。 相似文献
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通过Fenton法和结合聚合硫酸铁的混凝作用,实现垃圾渗滤液氧化塘出水COD的深度处理;并利用水泥水化产物的凝胶物质,强化COD去除率。30%H2O2投加量为0.75mL/L、七水硫酸亚铁投加量为1.5g/L、n(H2O2):n(Fe^2+)=1.2:1(摩尔比)时,Fenton法对渗滤液COD的去除率可达52%;水灰比为2:1、搅拌24h的水泥水化物将Fenton法的出水pH值从4调至10,该工艺流程总的COD去除率为73.6%,较普通的Ca(OH)2调节法提高9.3%,出水COD可以从进水的1200mg/L降至315mg/L。 相似文献