生物柴油产业链分析

生物柴油是指由植物油、动物油脂等制备得到的单烷烃酯类。它是一种环境友好、清洁排放的燃料,因此是非常理想的石油柴油替代燃料。本文从生物柴油产业链中的原料来源、生产工艺、产品应用以及其效益等方面对这种新型的清洁燃料进行了简单介绍。总之,生物柴油是一种很有发展前景的生物质燃料。     

Environmental pollution,hydropower and nuclear energy generation before and after catastrophe: Bathtub-Weibull curve and MS-VECM methods

In this paper, the life span of hydro and nuclear energy generations and the relationship between hydro and nuclear energy generations, environmental pollution, and economic growth were investigated for Japan covering the period of 1960–2018 by employing the Bathtub-Weibull curve and Markov switching-vector error correcting (MSVEC) method, respectively. According to the Bathtub-Weibull curve analysis, a rising failure rate for nuclear energy was found, indicating that the life of nuclear energy has expired, but a decreasing failure rate for hydroelectric energy has been detected. Then two different MSVEC models were used. The MSVEC method, unlike traditional approaches, determines the relationship between variables under different regimes. The results of MSVEC methods indicate three important points. First, regime-dependent asymmetry and regime changes are crucial for policy recommendations. Second, the shocks to hydropower and nuclear energy generations cause temporary deviations from the long-run growth path in both regimes. Lastly, the increase in hydropower generation leads to a decrease in environmental pollution and an increase in GDP, and an increase in nuclear power generation increases pollution and growth in both regimes.     

"十三五"国家自然科学基金对能源环境管理领域的资助状况和趋势

能源环境管理是各界关注的热点话题,也是科学研究的重要方向.以国家自然科学基金资助能源环境管理领域的科研项目为基础数据信息,本文重点分析了"十三五"期间国家自然科学基金在该领域资助项目的总体特征、研究主题和热点变化,并结合新时代科学基金资助导向提出了可能的发展趋势.主要结论包括:①能源环境管理领域面上、青年、地区等自由探索类项目的立项绝对数和学科占比均呈上升趋势,并更多向青年学者倾斜,资助强度保持稳定;②碳、能源和环境是自由探索项目中出现频率最高的热词,与之相关的研究主题随着政策等调整具有动态变化特征;③能源环境管理领域重点、重大等引导类项目和优青、杰青、创新研究群体等人才类项目不断实现突破,增速明显,学科占比优势突出;④问题导向与本土情景、理论体系和一般规律、学科交叉融合,以及市场和微观主体作用是研究选题确立与项目申请时可能需要重点关注的方向.     

Effect of pyrolysis and oxidation characteristics on lauric acid and stearic acid dust explosion hazards

The effect of pyrolysis and oxidation characteristics on the explosion sensitivity and severity parameters, including the minimum ignition energy MIE, minimum ignition temperature MIT, minimum explosion concentration MEC, maximum explosion pressure P_max, maximum rate of pressure rise (dP/dt)_max and deflagration index K_st, of lauric acid and stearic acid dust clouds was experimentally investigated. A synchronous thermal analyser was used to test the particle thermal characteristics. The functional test apparatuses including the 1.2 L Hartmann-tube apparatus, modified Godbert-Greenwald furnace, and 20 L explosion apparatus were used to test the explosion parameters. The results indicated that the rapid and slow weight loss processes of lauric acid dust followed a one-dimensional diffusion model (D1 model) and a 1.5 order chemical reaction model (F1.5 model), respectively. In addition, the rapid and slow weight loss processes of stearic acid followed a 1.5 order chemical reaction model (F1.5 model) and a three-dimensional diffusion model (D3 model), respectively, and the corresponding average apparent activation energy E and pre-exponential factor A were larger than those of lauric acid. The stearic acid dust explosion had higher values of MIE and MIT, which were mainly dependent on the higher pyrolysis and oxidation temperatures and the larger apparent activation energy E determining the slower rate of chemical bond breakage during pyrolysis and oxidation. In contrast, the lauric acid dust explosion had a higher MEC related to a smaller pre-exponential factor A with a lower amount of released reaction heat and a lower heat release rate during pyrolysis and oxidation. Additionally, due to the competition regime of the higher oxidation reaction heat release and greater consumption of oxygen during explosion, the explosion pressure P_m of the stearic acid dust was larger in low concentration ranges and decayed to an even smaller pressure than with lauric acid when the concentration exceeded 500 g/m³. The rate of explosion pressure rise (dP/dt)_m of the stearic acid dust was always larger in the experimental concentration range. The stearic acid dust explosion possessed a higher P_max, (dP/dt)_max and K_st mainly because of a larger pre-exponential factor A related to more active sites participating in the pyrolysis and oxidation reaction. Consequently, the active chemical reaction occurred more violently, and the temperature and overpressure rose faster, indicating a higher explosion hazard class for stearic acid dust.     

肥煤自燃全过程热动力学特征参数研究

实验测定了林西矿肥煤样品30~900℃煤自燃全过程热动力学特征参数,得出:TG/DTG曲线显示煤样DTG初始临界温度45℃,干裂温度122℃,活性温度195℃,增速温度265℃,质量极大值温度342℃,着火温度465℃,最大热失重速率温度515℃和燃尽温度690℃;DSC曲线显示,煤样初始放热温度60℃、最大热释放速率温度511℃。结合TG-DTG-DSC曲线综合分析可知,煤温达到510℃左右时煤样反应最剧烈。由煤自燃标志气体测定实验系统得出:煤温130℃后CO,CO 2释放量迅速增加,210℃增加速度下降;CH 4,C 2 H 6含量变化具有规律性且两者变化相近;C 2 H 4出现温度为130℃;C 2 H 4/C 2 H 6比值在190~350℃有较强的规律性,呈上升趋势且上升速度较快;350℃之后,CH 4,C 2 H 6,C 2 H 4体积分数均开始急剧增大;C 2 H 4/CO与C 2 H 4/CO 2变化趋势大致相同,在130~350℃时缓慢增长,达到350℃后比值呈指数形式上升。经拟合曲线,得到活化能的3个突变点温度:70,180,220℃,其中180℃与交叉点温度相吻合。通过以上研究,得到了肥煤自燃全过程的热力学特征参数,为实际生产中防治煤自燃提供了理论依据。     

水稻和玉米的热氧化分解特性及几种动力学方法结果的比较

利用热重分析仪在空气气氛、不同的升温速率下对带壳稻谷粉和玉米粒粉进行了热重测试,依据热重实验数据,采用多种热解动力学分析方法计算了水稻和玉米的活化能数值并进行比较,结果表明水稻和玉米的热氧化反应活化能随着转化率出现先增加后降低的趋势,并在转化率为70%左右达到了极大值。     

Effect of pipes in heat pump system on electric vehicle energy saving

ABSTRACT

Refrigerant pressure drop and temperature change in pipes are normally ignored in the thermodynamic analysis of traditional vehicle air conditioning system, this will result in serious errors. In this Paper, pressure drop and temperature difference are simulated in different pipes of electric vehicle (EV) heat pump system to analysis the effects of pipes in the actual EV heat pump system. The results indicate that the greater the mass flow, the faster pressure drop increases, the temperature difference decreases. Pressure drop of saturated liquid refrigerant is smaller than that of saturated gas refrigerant at the same saturation pressure and mass flow rate. The higher the refrigerant pressure (no phase change), the slower pressure drop decreases, the faster the temperature difference decreases. Pressure drop decreases with the increment of bending angle of the pipe. For EV heat pump system, suitable valves and less branches are helpful for energy saving of the system. Shortening the pipe between compressor and condenser can reduce temperature change obviously. Pressure drop per unit length in the pipe between evaporator and compressor is large especially in heating mode because of lower refrigerant density. It even reaches to over 100 times of that in the pipe between condenser and throttle valve in heating mode and has negative effects on the performance of the system. If the evaporator is closer to the compressor and the number of branches is less, then pressure drop will decrease a lot, which will be advantageous for energy saving of the heat pump system.     

Effects of falling weight impact on industrial safety helmets used in conjunction with eye and face protection devices

Industrial workplaces pose concurrent hazards to the upper part of the head and the eyes. Under the circumstances, workers may use protective helmets in conjunction with protective goggles or spectacles. In order to assess the compatibility of this equipment, a method and a test stand for evaluating the behavior of safety helmets and protective goggles/spectacles upon the impact of a falling weight were designed. The results of tests concerning the displacement and deformation of helmets and spectacles/goggles, the forces acting on the helmets, as well as the forces exerted by the spectacles/goggles on the headform upon falling weight impact are presented. The results revealed the ways in which the tested equipment interacted with each other. The influence of equipment construction on the test results was analyzed and inferences concerning the safety of the studied protective devices were made. Some general construction guidelines were formulated for the compatibility of the equipment.     

单轴应力对煤自燃特性参数和导热系数的影响研究

为探究单轴应力作用下煤氧化和传热特性,利用自制荷载加压煤自燃特性参数测定装置对炉体内长焰煤煤样进行程序升温。结合程序升温过程中煤临界温度Tc和Tg,对其进行阶段划分:阶段1为30℃~Tc;阶段2为Tc~Tg。计算了不同单轴应力下2个阶段煤表观活化能和平均耗氧速率。根据能量守恒得出程序升温过程煤导热系数随温度的变化,进一步分析煤导热系数与单轴应力的关系。结果表明:阶段1单轴应力为4 MPa时为临界轴压,煤表观活化能最大,平均耗氧速率最小;阶段2煤表观活化能和平均耗氧速率随单轴应力增大均呈抛物线变化,单轴应力为2.7 MPa时为临界轴压,煤表观活化能最大,平均耗氧速率最小;阶段1和2煤导热系数随温度升高均先减小后增大,并且煤导热系数随单轴应力增大呈三次函数变化。     

加轴压卸围压下含瓦斯煤岩损伤变形的能量演化机制

采动影响下含瓦斯煤岩的损伤变形是一个极其复杂的非线性过程,单纯依靠传统经典弹塑性力学无法准确分析其破坏机理。针对此情况,通过试验研究了不同初始围压条件下含瓦斯煤岩的损伤变形特征,并分析了损伤变形与能量演化规律之间的内在联系。研究表明:初始围压越高,煤样破坏时强度越大,脆性破坏特征越明显,瓦斯流量急剧增加幅度越大,煤样破坏时积累的总能量和弹性应变能越多,且初始围压与弹性能之间满足对数函数关系。采用累积耗散能定义了煤岩损伤变量,并分析了不同阶段损伤与渗透率之间的演化关系。